Method for manufacturing a metallization structure comprising aluminum and silicon
View Patent ↗In various embodiments, a solar cell screen-printing composition is provided, comprising aluminum; and silicon; the percentage by mass of silicon lying in a range from 5% to 95% of the sum of the percentages by mass of silicon and aluminum.
1. A method for metallizing a solar cell, the method comprising:
coating a first region of the solar cell with a first solar cell screen-printing composition, the first solar cell screen-printing composition comprising at least aluminum and silicon, a percentage by mass of the silicon lying in a range from approximately 5% to approximately 30% of a sum of percentages by mass of silicon and aluminum;
coating a second region of the solar cell, which adjoins the coated first region, with a second solar cell screen-printing composition which is substantially free of silicon, wherein the first and second solar cell screen-printing compositions on the first region and the second region are connected to one another in an electrically conductive manner;
heating the solar cell coated with the first and second solar cell screen-printing compositions; and
after the heating of the solar cell, an additional layer, which contains a solderable material, being applied directly on or directly over at least the first solar cell screen-printing composition.
2. The method as claimed in claim 1 ,
wherein the first region of the solar cell is coated with the first solar cell screen-printing composition by means of a screen-printing process.
3. The method as claimed in claim 1 ,
wherein the solderable material is applied by vapor deposition, sputtering, electrodeposition, CVD or thermal spraying.
4. The method as claimed in claim 1 ,
wherein the solar cell is heated during the heating to a temperature in a range from approximately 700° C. to approximately 900° C.
5. The method as claimed in claim 1 ,
wherein the solar cell has an n-type emitter and the first solar cell screen-printing composition is applied to a back side of the solar cell.
6. The method as claimed in claim 1 ,
wherein the solar cell has a p-type emitter and the first solar cell screen-printing composition is applied to a front side of the solar cell.
7. The method as claimed in claim 1 ,
wherein in the first solar cell screen-printing composition the percentage by mass of silicon lies in a range from approximately 5% to approximately 15% of the sum of percentages by mass of silicon and aluminum.
8. The method as claimed in claim 1 ,
wherein the first solar cell screen-printing composition is a paste with a viscosity in a range from approximately 10 Pa·s to approximately 500 Pa·s.
9. The method as claimed in claim 1 ,
wherein the first solar cell screen-printing composition comprises etchants and solvents with a maximum percentage by mass of 25%.
10. The method as claimed in claim 1 ,
wherein the silicon and the aluminum of the first solar cell screen-printing composition are in elemental particle form with an average size in a range from approximately 0.5 μm to approximately 20 μm.
11. The method as claimed in claim 1 ,
wherein the first solar cell screen-printing composition only partially covers a back side of the solar cell.
12. The method as claimed in claim 1 ,
wherein the heating forms an electrical back surface field over the first region and the second region.
13. The method as claimed in claim 1 ,
wherein the first solar cell screen-printing composition and the second solar cell screen-printing composition substantially do not include silver.