Organic EL element and method for producing same
View Patent ↗The present invention is to provide a method of favorably forming an organic EL device with the inverted structure by the wet process. On that account, an organic EL device includes a cathode, an electron injection layer, a light emitting layer, a hole transport layer, a hole injection layer, an anode are formed in this order on a substrate. The electron injection layer is formed by applying ink between banks and drying the ink. The ink is formed by dissolving a polymer compound having an organic phosphine oxide skeleton in an alcohol solvent. The light emitting layer is formed by applying ink between components of the bank and the drying the ink. The ink is formed by dissolving material for light emitting layer such as polyphenylene vinylene (PPV) derivative or polyfluorene derivative in a nonpolar solvent.
1. A method of manufacturing an organic EL device having a substrate, and a cathode, a plurality of organic layers and an anode layered on the substrate in an order as stated, the method comprising:
a first step of forming, by a wet process, a first organic layer including a polymer compound having an organic phosphine oxide skeleton; and
a second step of forming, on the first organic layer, a second organic layer by a wet process using a solution including organic material and a solvent, the solvent being at least one selected from the group consisting of an aromatic solvent including a benzene ring and an aliphatic solvent including alkyl or alkene, wherein
the polymer compound is soluble in an alcohol solvent and insoluble in the solvent used in the second step, and is represented by the following structural formula:
where each of Ar 1 and Ar 2 is a monovalent aromatic chromophore, each of R 1 and R 2 is an aliphatic substituent, and n is an integer of 2 or more.
2. The method according to claim 1 , wherein
in the first step, the first organic layer is formed by using a solution including an alcohol solvent.
3. The method according to claim 1 , wherein
in the first step, the first organic layer is formed by using a solution including at least one of alkali metal, alkali earth metal and rare earth metal.
4. The method according to claim 1 , wherein
the polymer compound has a weighted average molecular weight that is equal to or more than 2000.
5. The method according to claim 1 , wherein
the wet process used in the second step is an ink jet method.
6. An organic EL device comprising a substrate, and a cathode, a plurality of organic layers and an anode layered on the substrate in an order as stated, wherein
the plurality of organic layers include:
a first organic layer including a polymer compound having an organic phosphine oxide skeleton; and
a second organic layer made of organic material layered on the first organic layer, and
the polymer compound is soluble in an alcohol solvent and insoluble in an aromatic solvent including a benzene ring or an aliphatic solvent including alkyl or alkene, and is represented by the following structural formula:
where each of Ar 1 and Ar 2 is a monovalent aromatic chromophore, each of R 1 and R 2 is an aliphatic substituent, and n is an integer of 2 or more.
7. The organic EL device according to claim 6 , wherein
the polymer compound has a weighted average molecular weight that is equal to or more than 2000.
8. The organic EL device according to claim 6 , wherein
the first organic layer further includes at least one of alkali metal, alkali earth metal and rare earth metal.
9. The organic EL device according to claim 8 , wherein
the alkali metal, the alkali earth metal or the rare earth metal is mixed in the first organic layer as an organometallic complex.
10. The organic EL device according to claim 6 , wherein
the second organic layer is one of a light emitting layer, an electron transport layer and a hole blocking layer.
11. A polymer compound for forming an organic layer of an organic EL device, the polymer compound being represented by the following structural formula:
where each of Ar 1 and Ar 2 is an aromatic chromophore, each of R 1 and R 2 is an aliphatic substituent, and n is an integer of 2 or more.
12. The polymer compound according to claim 11 represented by the following structural formula:
where n is an integer of 2 or more.
13. The polymer compound according to claim 11 , wherein
the polymer compound has a weighted average molecular weight that is equal to or more than 2000.
14. The polymer compound according to claim 12 , wherein
the polymer compound has a weighted average molecular weight that is equal to or more than 2000.