Method for forming synthesis gas using a plasma-catalyzed fuel reformer
View Patent ↗A method of forming a synthesis gas utilizing a reformer is disclosed. The method utilizes a reformer that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding apparatus and system are also disclosed herein.
1. A method of forming synthesis gas comprising:
receiving a pre-heated mixture of reactants, comprising a feedstock fuel and an oxidant, into a plasma zone;
ionizing the reactants in the plasma zone by applying an electrical potential thereto;
transferring heat to the ionized reactants through a first thermally conductive surface surrounding the plasma zone;
receiving the ionized reactants into a reaction zone;
chemically transforming the ionized reactants in the reaction zone into synthesis gas comprising a mixture of hydrogen and carbon monoxide; and
transferring heat to the reaction zone through a second thermally conductive surface surrounding the reaction zone, wherein the second thermally conductive surface and the first thermally conductive surface are both directly exposed to a heat source.
2. The method of claim 1 , wherein the first thermally conductive surface and the second thermally conductive surface are designed with a surface area sufficient to transfer between about two and thirty percent of the heating value of the feedstock fuel, presently in the plasma and reaction zones, into the plasma and reaction zones to provide the heat of reformation.
3. The method of claim 1 , wherein the plasma zone and the reaction zone are incorporated into a housing having a length and width, and wherein the aspect ratio of the length to the width is at least 1:1.
4. The method of claim 3 , wherein the aspect ratio of the length to the width is at least 1.5:1.
5. The method of claim 1 , wherein the first thermally conductive surface and the second thermally conductive surface are incorporated into one of a U-shaped, M-shaped, and serpentine-shaped housing.
6. The method of claim 1 , wherein the feedstock fuel comprises at least one of a hydrocarbon and carbon.
7. The method of claim 1 , wherein the oxidant comprises at least one of steam, oxygen, and an oxygen-containing compound.
8. The method of claim 1 , wherein the oxidant is provided in sub-stoichiometric amounts to partially oxidize the feedstock fuel.
9. The method of claim 1 , wherein the pre-heated mixture of reactants is provided as a vapor.
10. The method of claim 1 , wherein the plasma zone uses a gliding electric arc to ionize the reactants.
11. The method of claim 1 , wherein the reaction zone comprises a reaction bed to at least one of homogenize the reactants by mixing, and homogenize the reactants by chemical buffering.
12. The method of claim 1 , wherein the reaction zone comprises a reaction bed containing catalysts to promote equilibration of reactive species at temperatures lower than the temperature of reformation.
13. The method of claim 1 , wherein the external heat source is one of a solid-oxide fuel cell, a molten-carbonate fuel cell, a phosphoric acid fuel cell, and a Fischer-Tropsch process.
14. The method of claim 13 , wherein at least one reactant comprises CO 2 obtained as a product of the fuel cell reaction.
15. The method of claim 13 , wherein at least one reactant comprises steam obtained as a product of the fuel cell reaction.
16. The method of claim 1 , wherein the reformer and external heat source are disposed within an insulated enclosure.
17. The method of claim 1 , further comprising a heating zone to heat the preheated mixture.
18. A method of forming synthesis gas comprising:
receiving a pre-heated mixture of reactants, comprising a feedstock fuel and an oxidant, into a plasma zone, wherein the feedstock fuel comprises at least one of a hydrocarbon and carbon, and wherein the oxidant comprises at least one of steam, oxygen, and an oxygen-containing compound, and wherein the plasma zone uses a gliding electric arc to ionize the reactants;
ionizing the reactants in the plasma zone by applying an electrical potential thereto;
transferring heat to the ionized reactants through a first thermally conductive surface surrounding the plasma zone;
receiving the ionized reactants into a reaction zone, wherein the reaction zone comprises a reaction bed to at least one of homogenize the reactants by mixing, and homogenize the reactants by chemical buffering;
chemically transforming the ionized reactants in the reaction zone into synthesis gas comprising a mixture of hydrogen and carbon monoxide; and
transferring heat to the reaction zone through a second thermally conductive surface surrounding the reaction zone, wherein the second thermally conductive surface and the first thermally conductive surface are both directly exposed to a heat source.
19. A method of forming synthesis gas comprising:
receiving a pre-heated mixture of reactants, comprising a feedstock fuel and an oxidant, into a plasma zone, wherein the feedstock fuel comprises at least one of a hydrocarbon and carbon, and wherein the oxidant comprises at least one of steam, oxygen, and an oxygen-containing compound, and wherein the plasma zone uses a gliding electric arc to ionize the reactants;
ionizing the reactants in the plasma zone by applying an electrical potential thereto;
transferring heat to the ionized reactants through a first thermally conductive surface surrounding the plasma zone;
receiving the ionized reactants into a reaction zone;
chemically transforming the ionized reactants in the reaction zone into synthesis gas comprising a mixture of hydrogen and carbon monoxide; and
transferring heat to the reaction zone through a second thermally conductive surface surrounding the reaction zone, wherein the second thermally conductive surface and the first thermally conductive surface are both directly exposed to a heat source.