Flame retardant polyalkylene terphthalate/polycarbonate compositions
View Patent ↗The present invention relates to polyalkylene terephthalate/polycarbonate compositions, containing A) 49 to 70 parts by weight aromatic polycarbonate, B) 21 to 40 parts by weight polyalkylene terephthalate with more than 2 carbons in the diol component, C) 6 to 25 parts by weight of a salt of a phosphinic acid, D) 0 to 24 parts by weight conventional additives, all parts by weight in the present application being standardized such that the sum of the parts by weight of components A+B+C+D in the composition adds up to 100, and which are distinguished by an optimum combination of low molding shrinkage, high chemical resistance and good heat resistance together with good fire behavior, the use of the polycarbonate compositions for the production of moldings and the moldings themselves.
1. A composition comprising
A) 49 to 70 parts by weight aromatic polycarbonate,
B) 21 to 40 parts by weight polyalkylene terephthalate with more than 2 carbons in a diol component thereof,
C) 6 to 25 parts by weight of a salt of a phosphinic acid,
D) 0 to 50 parts by weight one or more additives,
all parts by weight being standardised such that a sum of the parts by weight of components A+B+C+D in the composition adds up to 100,
wherein the composition is free from rubber-based graft polymers.
2. The composition according to claim 1 , wherein a ratio of component A) to B) is in a range of from 1.4 to 3.5.
3. The composition according to claim 1 , wherein a ratio of component A) to B) is in a range of from 1.6 to 2.7.
4. The composition according to claim 1 , comprising 53 to 61 parts by weight aromatic polycarbonate component A).
5. The composition according to claim 1 , comprising 25 to 33 parts by weight polyalkylene terephthalate with more than 2 carbons in the diol component according to component B).
6. The composition according to claim 1 , comprising 7 to 22 parts by weight of a salt of a phosphinic acid according to component C).
7. The composition according to claim 1 , comprising 10 to 20 parts by weight of a salt of a phosphinic acid according to component C).
8. The composition according to claim 1 , comprising 0 to 24 parts by weight additives according to component D).
9. The composition according to claim 1 , wherein component B is polybutylene terephthalate.
10. The composition according to claim 1 , comprising as component C) a salt and/or a mixture of salts of a phosphinic acid of formula (IV)
where
M m+ is a metal cation of main group 1 (alkali metals; m=1), main group 2 (alkaline earth metals; m=2) or main group 3 (m=3) or subgroups 2, 7 or 8 (wherein m signifies an integer from 1 to 6) of the periodic table.
11. The composition according to claim 10 , wherein the metal cation is Li + , Na + , K + , Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ , Al 3+ , Zn 2+ , Mn 2+ , Fe 2+ and/or Fe 3+ .
12. The composition according to claim 11 , wherein M m+ =Ca 2+ and m=2.
13. The composition according to claim 1 , wherein an average particle size d 50 of the phosphinic acid salt (component C) is not more than 80 μm.
14. The composition according to claim 1 , wherein the composition is free from rubber-free vinyl (co)polymers.
15. A moulding that has been produced from a composition of claim 1 .
16. A method for making a moulding comprising forming a composition according to claim 1 into said moulding.
17. A composition according to claim 1 , comprising a combination of chemical resistance expressed as ESC behaviour that is greater than 100 hours and a moulding shrinkage that is less than 0.6%.
18. The composition according to claim 1 , wherein the composition is free from phosphorus-containing flame retardants selected from the group consisting of monomeric and oligomeric phosphoric and phosphonic acid esters, phosphonate amines, and phosphazenes.
19. The composition of claim 1 , wherein component D) comprises flame retardant synergist, anti-dripping agent, lubricant and mould release agent, nucleating agent, stabiliser, antistatic agent, acid, filler and reinforcing material, dye, or pigment.
20. A composition consisting of
A) 49 to 70 parts by weight aromatic polycarbonate,
B) 21 to 40 parts by weight polyalkylene terephthalate with more than 2 carbons in a diol component thereof,
C) 6 to 25 parts by weight of a salt of a phosphinic acid,
D) 0 to 50 parts by weight one or more additives,
all parts by weight being standardised such that a sum of the parts by weight of components A+B+C+D in the composition adds up to 100,
wherein the composition is free from rubber-based graft polymers.