Decarboxylation of levulinic acid to ketone solvents

1. A method of forming a ketone comprising:

obtaining a quantity of a six carbon sugar;

reacting the sugar to form an alkali metal levulinate;

preparing an anolyte comprising the alkali metal levulinate;

decarboxylating the alkali metal levulinate within the anolyte in an electrolytic cell to form at least a methyl ethyl ketone (“MEK”) radical, wherein the electrolytic cell comprises an anolyte compartment that houses the anolyte, a catholyte compartment that houses a catholyte, and an alkali ion conducting membrane that separates the anolyte compartment from the catholyte compartment, wherein the MEK radicals in the anolyte further react to form a ketone.

2. A method as claimed in claim 1 , wherein the ketone is a MEK.

3. A method as claimed in claim 1 , wherein the ketone is an octanedione.

4. A method as claimed in claim 2 , wherein the anolyte further comprises a quantity of a hydrogen supplier that is used to form MEK.

5. A method as claimed in claim 2 , wherein the hydrogen supplier comprises alkali metal formate, further comprising the steps of:

decarboxylating the alkali metal formate to form H radicals, wherein the H radicals react with the MEK radicals to form MEK.

6. A method as claimed in claim 5 , wherein the alkali metal formate is formed from the six carbon sugar.

7. A method as claimed in claim 4 , wherein the hydrogen supplier comprises a quantity of hydrogen gas.

8. A method as claimed in claim 7 , wherein the MEK radicals react with the hydrogen gas to form MEK via a hydrogen abstraction process.

9. A method as claimed in claim 4 , wherein the hydrogen supplier comprises an alkane, an alcohol or water.

10. A method as m claim 2 , wherein the alkali ion conducting membrane is a NaSICON membrane.

11. A method as claimed in claim 2 , wherein the electrolytic cell further comprises a photolysis device.

12. A method as claimed in claim 11 , wherein the photolysis device decarboxylates the alkali metal salt of levulinate.

13. A method as claimed in claim 12 , wherein the photolysis device creates hydrogen radicals that react with the MEK radicals to form MEK.

14. A method for producing methyl ethyl ketone (“MEK”) comprising:

preparing an anolyte for use in an electrolytic cell, the electrolytic cell comprising an alkali ion conducting membrane, wherein the anolyte comprises a solvent and a quantity of an alkali metal levulinate; and

decarboxylating the alkali metal levulinate within the electrolytic cell, wherein the decarboxylating converts the alkali metal levulinate into MEK radicals that react to form MEK.

15. A method as in claim 14 , wherein the decarboxylating the alkali metal levulinate occurs by electrolyzing the anolyte.

16. A method as in claim 14 , wherein the alkali metal levulinate comprises a sodium levulinate and the alkali ion conducting membrane comprises a NaSICON membrane, wherein the membrane divides the cell into an anolyte compartment and a catholyte compartment, the anolyte being housed within the anolyte compartment and a catholyte being housed within the catholyte compartment.

17. A method as in claim 14 , wherein the MEK radicals couple to hydrogen radicals.

18. A method as in claim 17 , wherein the hydrogen radicals are formed by decarboxylating an alkali metal formate during either the decarboxylating of the alkali metal levulinate or photolysis of hydrogen gas or both.

19. A method for producing methyl ethyl ketone (“MEK”) comprising:

obtaining sodium levulinate, the sodium levulinate derived from a six carbon sugar;

preparing an anolyte for use in an electrolytic cell, the electrolytic cell comprising an anolyte compartment, a catholyte compartment, and a NaSICON membrane that separates the anolyte compartment from the catholyte compartment, wherein the anolyte is housed within the anolyte compartment and a catholyte is housed within the catholyte compartment, wherein the anolyte comprises a solvent and a quantity of the sodium levulinate; and

electrolyzing the anolyte within the cell, wherein the electrolyzing decarboxylates the sodium levulinate and converts the sodium levulinate into one or more MEK radicals that react with a hydrogen supplier to form MEK.

20. An electrolytic cell comprising:

an anolyte compartment;

a catholyte compartment;

NaSICON membrane that separates the anolyte compartment from the catholyte compartment;

an anolyte is housed within the anolyte compartment, wherein the anolyte comprises a solvent, a hydrogen supplier and a quantity of sodium levulinate;

a catholyte is housed within the catholyte compartment; and

a voltage supplier or photolysis device that decarboxylates the sodium levulinate and converts the sodium levulinate into one or more methyl ethyl ketone radicals that react with the hydrogen supplier to form methyl ethyl ketone.

21. An electrolytic cell as claimed in claim 20 , wherein the cell comprising both a voltage supplier and a photolysis device.

22. An electrolytic cell as claimed in claim 21 , wherein the photolysis device creates hydrogen radicals from the hydrogen supplier.

23. An electrolytic cell as claimed in claim 20 , wherein the cell comprises a voltage supplier and does not include a photolysis device, wherein the hydrogen supplier comprises sodium formate, wherein the sodium formate is decarboxylated by the voltage supplier to form hydrogen radicals that react with the methyl ethyl ketone radicals to form methyl ethyl ketone.