Solar cell with silicon oxynitride dielectric layer
View Patent ↗Solar cells with silicon oxynitride dielectric layers and methods of forming silicon oxynitride dielectric layers for solar cell fabrication are described. For example, an emitter region of a solar cell includes a portion of a substrate having a back surface opposite a light receiving surface. A silicon oxynitride (SiO x N y , 0<x, y) dielectric layer is disposed on the back surface of the portion of the substrate. A semiconductor layer is disposed on the silicon oxynitride dielectric layer.
1. An emitter region of a solar cell, the emitter region comprising:
a portion of a substrate having a back surface opposite a front surface;
a silicon oxynitride (SiO x N y , 0<x, y) dielectric layer disposed on the back surface of the portion of the substrate, wherein the silicon oxynitride dielectric layer has a non-homogeneous distribution of nitrogen, wherein the silicon oxynitride dielectric layer has a thickness approximately in the range of 10-20 Angstroms, and wherein the silicon oxynitride dielectric layer has a first nitrogen-rich region having a thickness approximately in the range of 4-5 Angstroms, a nitrogen-poor region disposed above the first nitrogen-rich region and having a thickness approximately in the range of 5-6 Angstroms, and a second nitrogen-rich region disposed above the nitrogen-poor region and having a thickness approximately in the range of 4-5 Angstroms; and
a semiconductor layer disposed on the silicon oxynitride dielectric layer.
2. The emitter region of claim 1 , wherein the front surface is a light receiving surface of the solar cell.
3. The emitter region of claim 1 , wherein the semiconductor layer disposed on the silicon oxynitride dielectric layer is a boron-doped silicon layer.
4. The emitter region of claim 3 , wherein the silicon oxynitride dielectric layer comprises boron atoms.
5. The emitter region of claim 1 , wherein the silicon oxynitride dielectric layer is for inhibiting dopant penetration from the semiconductor layer to the portion of the substrate.
6. The emitter region of claim 1 , wherein the silicon oxynitride dielectric layer is a silicon oxynitride tunnel dielectric layer for the emitter region.
7. The emitter region of claim 1 , further comprising:
a metal contact disposed on the semiconductor layer.
8. A solar cell, comprising:
a first emitter region, comprising:
a first portion of a substrate having a back surface opposite a light receiving surface;
a silicon oxynitride (SiO x N y , 0<x, y) dielectric layer disposed on the back surface of the first portion of the substrate, wherein the silicon oxynitride dielectric layer has a non-homogeneous distribution of nitrogen, wherein the silicon oxynitride dielectric layer has a thickness approximately in the range of 10-20 Angstroms, and wherein the silicon oxynitride dielectric layer has a first nitrogen-rich region having a thickness approximately in the range of 4-5 Angstroms, a nitrogen-poor region disposed above the first nitrogen-rich region and having a thickness approximately in the range of 5-6 Angstroms, and a second nitrogen-rich region disposed above the nitrogen-poor region and having a thickness approximately in the range of 4-5 Angstroms; and
a P-type semiconductor layer disposed on the silicon oxynitride dielectric layer; and
a second emitter region, comprising:
a second portion of the substrate;
the silicon oxynitride dielectric layer disposed on the back surface of the second portion of the substrate; and
an N-type semiconductor layer disposed on the silicon oxynitride dielectric layer.
9. The solar cell of claim 8 , wherein the silicon oxynitride dielectric layer is for inhibiting dopant penetration from the P-type semiconductor layer to the first portion of the substrate, and wherein the silicon oxynitride dielectric layer is a silicon oxynitride tunnel dielectric layer for the first and second emitter regions.
10. The solar cell of claim 8 , wherein the first and second emitter regions are separated by a trench formed in the substrate, between the first and second portions of the substrate.
11. An emitter region of a solar cell, the emitter region comprising:
a portion of an N-type bulk silicon substrate having a back surface opposite a light receiving surface;
a silicon oxynitride (SiO x N y , 0<x, y) dielectric layer disposed on the back surface of the portion of the N-type bulk silicon substrate, wherein the silicon oxynitride dielectric layer has a non-homogeneous distribution of nitrogen, wherein the silicon oxynitride dielectric layer has a thickness approximately in the range of 10-20 Angstroms, and wherein the silicon oxynitride dielectric layer has a first nitrogen-rich region having a thickness approximately in the range of 4-5 Angstroms, a nitrogen-poor region disposed above the first nitrogen-rich region and having a thickness approximately in the range of 5-6 Angstroms, and a second nitrogen-rich region disposed above the nitrogen-poor region and having a thickness approximately in the range of 4-5 Angstroms;
a boron-doped polycrystalline silicon layer disposed on the silicon oxynitride dielectric layer; and
a metal contact disposed on the boron-doped polycrystalline silicon layer.
12. The emitter region of claim 11 , wherein the silicon oxynitride dielectric layer is for inhibiting dopant penetration from the boron-doped polycrystalline silicon layer to the portion of the N-type bulk silicon substrate, and wherein the silicon oxynitride dielectric layer is a silicon oxynitride tunnel dielectric layer for the emitter region.