IP Library Granted Patent US 9,567,558
Granted Patent B2
US 9,567,558 · App. 13/722,385 · Granted Feb 14, 2017

Biomass hydrothermal decomposition system and saccharide-solution production method using biomass material

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Quick Facts
Patent No.
US 9,567,558
App. No.
13/722,385
Granted
Feb 14, 2017
Kind
B2
Abstract

A saccharide-solution production method using a biomass material, including feeding a biomass material containing cellulose, hemicellulose, and lignin under a normal pressure to put it under an increased pressure; hydrothermally decomposing the biomass material using pressurized hot water by a hydrothermal decomposition unit; and dissolving a lignin component and a hemicellulose component in the pressurized hot water; thereafter, adding a biomass solid discharged from the hydrothermal decomposition unit to a slurrying vessel containing water injected therein and communicating with the hydrothermal decomposition unit so as to obtain a slurried biomass solid; then, removing water from the slurried biomass solid; and thereafter, performing enzymatic saccharification of the water-removed biomass solid to produce a saccharide solution.

Claims (48)

1. A saccharide-solution production method using a biomass material, comprising:

putting a biomass material under an increased pressure, the biomass material containing cellulose, hemicellulose, and lignin under a normal pressure, and feeding the biomass material under the increased pressure to a biomass material inlet provided at a lower end side of a vertical hydrothermal decomposition unit;

feeding pressurized hot water to a pressurized hot water inlet provided at an upper end side of the hydrothermal decomposition unit, so as to provide a first gas-liquid interface between the biomass material inlet and the pressurized hot water inlet of the hydrothermal decomposition unit;

supplying a pressurizing gas to a pressurizing gas inlet provided at the upper end side of the hydrothermal decomposition unit;

conveying the biomass material from the biomass material inlet to a biomass material outlet provided at the upper end side of the hydrothermal decomposition unit to hydrothermally decompose the biomass material using the pressurized hot water in the hydrothermal decomposition unit; and

dissolving a lignin component and a hemicellulose component in the pressurized hot water, so as to discharge hot-water effluent containing the lignin component and the hemicellulose component from a hot water outlet provided at the lower end side of the hydrothermal decomposition unit;

extracting the hydrothermally decomposed biomass material as a biomass solid from the biomass material outlet of the hydrothermal decomposition unit;

injecting water in a slurrying vessel that communicates with the hydrothermal decomposition unit and has a water inlet at an upper side thereof and an outlet at a lower side thereof, so as to provide a second gas-liquid interface between the water inlet and the outlet of the slurrying vessel;

adding the biomass solid discharged from the hydrothermal decomposition unit to the slurrying vessel so as to obtain a slurried biomass solid;

measuring pH of the slurried biomass solid;

removing water from the slurried biomass solid;

performing enzymatic saccharification of the water-removed biomass solid to produce a first saccharide solution; and

performing enzymatic saccharification of the hot-water effluent, so as to produce a second saccharide solution,

wherein a liquid seal that prevents leakage of the pressurized gas is provided by the first gas-liquid interface and the second gas-liquid interface, and

wherein the saccharide-solution production method further comprises:

on the basis of the measured pH, controlling at least one of the following:

(i) a feed amount of the pressurized hot water;

(ii) a feed amount of the biomass material;

(iii) a conveying rate of the biomass material by a screw means;

(iv) a liquid level of the first gas-liquid interface of the hydrothermal decomposition unit; and

(v) a discharge amount of the hot-water effluent.

2. The saccharide-solution production method using a biomass material according to claim 1 , wherein

on an upstream of the enzymatic saccharification of the water-removed biomass solid, enzyme liquefaction of the biomass solid is performed.

3. A saccharide-solution production method using a biomass material, comprising:

putting a biomass material under an increased pressure, the biomass material containing cellulose, hemicellulose, and lignin under a normal pressure, and feeding the biomass material under the increased pressure to a biomass material inlet provided at a lower end side of a vertical hydrothermal decomposition unit;

feeding pressurized hot water to a pressurized hot water inlet provided at an upper end side of the hydrothermal decomposition unit, so as to provide a first gas-liquid interface between the biomass material inlet and the pressurized hot water inlet of the hydrothermal decomposition unit;

supplying a pressurizing gas to a pressurizing gas inlet provided at the upper end side of the hydrothermal decomposition unit;

conveying the biomass material from the biomass material inlet to a biomass material outlet provided at the upper end side of the hydrothermal decomposition unit to hydrothermally decompose the biomass material using the pressurized hot water in the hydrothermal decomposition unit; and

dissolving a lignin component and a hemicellulose component in the pressurized hot water, so as to discharge hot-water effluent containing the lignin component and the hemicellulose component from a hot water outlet provided at the lower end side of the hydrothermal decomposition unit;

injecting water in a slurrying vessel that communicates with the hydrothermal decomposition unit and has a water inlet at an upper side thereof and an outlet at a lower side thereof, so as to provide a second gas-liquid interface between the water inlet and the outlet of the slurrying vessel;

adding the biomass solid discharged from the hydrothermal decomposition unit to the slurrying vessel so as to obtain a slurried biomass solid;

measuring pH of the slurried biomass solid;

performing enzymatic saccharification of the slurried biomass solid to obtain a first saccharide solution;

separating a solid content from the first saccharide solution;

removing water from the first saccharide solution; and

performing enzymatic saccharification of the hot-water effluent, so as to produce a second saccharide solution,

wherein a liquid seal that prevents leakage of the pressurizing gas is provided by the first gas-liquid interface and the second gas-liquid interface, and

wherein the saccharide-solution production method further comprises:

on the basis of the measured pH, controlling at least one of the following:

(i) a feed amount of the pressurized hot water;

(ii) a feed amount of the biomass material;

(iii) a conveying rate of the biomass material by a screw means;

(iv) a liquid level of the first gas-liquid interface of the hydrothermal decomposition unit; and

(v) a discharge amount of the hot-water effluent.

4. The saccharide-solution production method according to claim 3 , further comprising:

removing water as first water from the first saccharide solution to obtain a first condensed saccharide solution;

removing water as second water from the second saccharide solution to obtain a second condensed saccharide solution; and

performing a biological treatment on a reaction inhibiting substance contained in the first water and the second water.

Assignments (5)
CHANGE OF NAME Recorded Jan 21, 2021
From: MITSUBISHI HITACHI POWER SYSTEMS ENVIRONMENTAL SOLUTIONS, LTD.
To: MITSUBISHI POWER ENVIRONMENTAL SOLUTIONS, LTD.
Reel/Frame 055055/0721 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME PREVIOUSLY RECORDED AT REEL: 039785 FRAME: 0648. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 30, 2016
From: MITSUBISHI HEAVY INDUSTRIES MECHATRONICS SYSTEMS, LTD.
To: MITSUBISHI HITACHI POWER SYSTEMS ENVIRONMENTAL SOLUTIONS, LTD
Reel/Frame 040191/0918 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2016
From: MITSUBISHI HEAVY INDUSTRIES MECHATRONICS SYSTEMS, LTD.
To: MITSBISHI HITACHI POWER SYSTEMS ENVIRONMENTAL SOLUTIONS, LTD
Reel/Frame 039785/0648 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2012
From: MITSUBISHI HEAVY INDUSTRIES, LTD.
To: MITSUBISHI HEAVY INDUSTRIES MECHATRONICS SYSTEMS, LTD.
Reel/Frame 029542/0259 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 27, 2012
From: SUZUKI, HIDEO; KUROMI, YOSHIO; KIMURA, YOSHITAKA
To: MITSUBISHI HEAVY INDUSTRIES, LTD.
Reel/Frame 029533/0168 →