Electrochemical co-production of products with carbon-based reactant feed to anode

1. A method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode, the method comprising the steps of:

contacting the first region with a catholyte comprising carbon dioxide;

contacting the second region with an anolyte comprising a recycled reactant and at least one of an alkane, haloalkane, alkene, haloalkene, aromatic compound, haloaromatic compound, heteroaromatic compound or halo-heteroaromatic compound, the recycled reactant includes a halide salt; and

applying an electrical potential between the anode and the cathode sufficient to produce the first product recoverable from the first region and the second product recoverable from the second region.

2. The method according to claim 1 , wherein the halide salt is AX where A is selected from the group consisting of Li, Na, K and Cs and X is selected from the group consisting of F, Cl, Br and I.

3. The method according to claim 1 , wherein the second product includes a halogenated compound.

4. The method according to claim 3 , further comprising:

removing the halogenated compound from the second region; and

converting the halogenated compound to a different compound.

5. The method according to claim 1 , wherein the catholyte further comprises a solvent selected from the group consisting of propylene carbonate, water, methanol, ethanol, acetonitrile, dimethylformamide, dimethylsulfoxide, and pyrrolidinone.

6. The method according to claim 1 , wherein the catholyte and the anolyte are separated by an ion permeable barrier that operates at a temperature less than 600 degrees C.

7. The method according to claim 6 , wherein the ion permeable barrier includes one of a polymeric or inorganic ceramic-based ion permeable barrier.

8. The method according to claim 1 , wherein the catholyte is liquid phase and the anolyte is gas phase.

9. A method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode, the method comprising the steps of:

contacting the first region with a catholyte comprising carbon dioxide;

contacting the second region with an anolyte comprising a recycled reactant and at least one of an alkane, haloalkane, alkene, haloalkene, aromatic compound, haloaromatic compound, heteroaromatic compound or halo-heteroaromatic compound, the recycled reactant includes a halide salt;

applying an electrical potential between the anode and the cathode sufficient to produce the first product recoverable from the first region and the second product recoverable from the second region, wherein the second product includes a halogenated compound;

removing the halogenated compound from the second region; and

converting the halogenated compound to a different compound.

10. The method according to claim 9 , wherein the catholyte further comprises a solvent selected from the group consisting of propylene carbonate, water, methanol, ethanol, acetonitrile, dimethylformamide, dimethylsulfoxide, and pyrrolidinone.

11. The method according to claim 9 , wherein the catholyte and the anolyte are separated by an ion permeable barrier that operates at a temperature less than 600 degrees C.

12. The method according to claim 11 , wherein the ion permeable barrier includes one of a polymeric or inorganic ceramic-based ion permeable barrier.

13. The method according to claim 9 , wherein the catholyte is liquid phase and the anolyte is gas phase.

14. The method according to claim 9 , wherein the halide salt is AX where A is selected from the group consisting of Li, Na, K and Cs and X is selected from the group consisting of F, Cl, Br and I.

15. A method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode, the method comprising the steps of:

contacting the first region with a catholyte comprising carbon dioxide;

contacting the second region with an anolyte comprising a recycled reactant and at least one of an alkane, haloalkane, alkene, haloalkene, aromatic compound, haloaromatic compound, heteroaromatic compound or halo-heteroaromatic compound; and

applying an electrical potential between the anode and the cathode sufficient to produce the first product recoverable from the first region and the second product recoverable from the second region, wherein the catholyte is liquid phase and the anolyte is gas phase.

16. The method of claim 15 , wherein the recycled reactant includes a halide salt.

17. The method according to claim 16 , wherein the halide salt is AX where A is selected from a group consisting of Li, Na, K and Cs and X is selected from the group consisting of F, Cl, Br and I.

18. The method according to claim 16 , wherein the second product includes a halogenated compound.

19. The method according to claim 18 , further comprising:

removing the halogenated compound from the second region; and

converting the halogenated compound to a different compound.

20. The method according to claim 15 , wherein the catholyte further comprises a solvent selected from the group consisting of propylene carbonate, water, methanol, ethanol, acetonitrile, dimethylformamide, dimethylsulfoxide, and pyrrolidinone.

21. The method according to claim 15 , wherein the catholyte and the anolyte are separated by an ion permeable barrier that operates at a temperature less than 600 degrees C.

22. The method according to claim 21 , wherein the ion permeable barrier includes one of a polymeric or inorganic ceramic-based ion permeable barrier.