Arthropodicidal anthranilamides
View Patent ↗This invention provides a composition comprising a first compound selected from Formula 1, an N-oxide or an agriculturally suitable salt thereof; and a second compound selected from neonicotinoids, wherein R 1 , R 2 , R 3 , R 4a , R 4b and R 5 are as defined in the disclosure.
1. A composition, comprising: a first compound selected from Formula 1, an N-oxide thereof, and an agriculturally suitable salt thereof; and a second compound selected from neonicotinoids,
wherein Formula 1 is
R 1 is CH 3 , F, Cl or Br;
R 2 is F, Cl, Br, I or CF 3 ;
R 3 is CF 3 , Cl, Br or OCH 2 CF 3 ;
R 4a is C 1 -C 4 alkyl;
R 4b is H or CH 3 ; and
R 5 is Cl or Br.
2. The composition of claim 1 further comprising at least one of a surfactant, a solid diluent or a liquid diluent.
3. The composition of claim 1 containing 5 to 90 wt percent of the first and second compounds, wherein the first compound is
4. The composition of claim 3 wherein the second compound is selected from the group consisting of
5. The composition of claim 3 wherein the second compound is imidacloprid.
6. The composition of claim 3 wherein the second compound is thiacloprid.
7. The composition of claim 3 wherein the second compound is clothianidin.
8. The composition of claim 3 wherein the second compound is acetamiprid
9. The composition of claim 3 wherein the second compound is thiamethoxam
10. A method for controlling an invertebrate pest, comprising: contacting the invertebrate pest or its environment with the composition of claim 1 .
11. The method of claim 10 wherein the application rate for the first compound in an agronomic ecosystem ranges from about 0.0001 to 8 kg/ha and in a nonagronomic application ranges from about 0.1 to 150 mg/square meter.
12. The method of claim 10 wherein the application rate for the first compound in an agronomic ecosystem ranges from about 0.01 to 2 kg/ha.
13. The method of claim 10 wherein the application rate for the first compound in a nonagronomic application ranges from about 1.0 to 50 mg/square meter.
14. A composition, comprising of: a first compound selected from Formula 1, an N-oxide thereof, and an agriculturally suitable salt thereof; a second compound selected from neonicotinoids; and at least one of a surfactant, a solid diluent or a liquid diluent, wherein the first compound and neonicotinoid is about 5 to 90 wt percent of the composition and,
wherein Formula 1 is
R 1 is CH 3 , F, Cl or Br;
R 2 is F, Cl, Br, I or CF 3 ;
R 3 is CF 3 , Cl, Br or OCH 2 CF 3 ;
R 4a is C 1 -C 4 alkyl;
R 4b is H or CH 3 ; and
R 5 is Cl or Br.
15. The composition of claim 14 wherein the first compound is
16. The composition of claim 14 wherein the second compound is selected from the group consisting of
17. The composition of claim 14 wherein the second compound is imidacloprid.
18. The composition of claim 14 wherein the second compound is thiacloprid.
19. The composition of claim 14 wherein the second compound is clothianidin.
20. The composition of claim 14 wherein the second compound is acetamiprid
21. The composition of claim 14 wherein the second compound is thiamethoxam
22. A process for preparing pesticides, comprising: mixing a first compound of Formula 1, an N-oxide thereof, or an agriculturally suitable salt thereof, as set forth in claim 1 , and a second compound selected from neonicotinoids with diluents, surfactants, or combinations thereof.