Leadless brass alloy excellent in stress corrosion cracking resistance
By enhancing a stress corrosion cracking resistance in a leadless brass alloy, specifically by suppressing a velocity of propagation of corrosion cracks in the brass alloy, a straight line crack peculiar to the leadless brass alloy is suppressed, a probability of cracks coming into contact with γ phases is heightened and local corrosion on the brass surface is prevented to suppress induction of cracks by the local corrosion, thereby providing a leadless brass alloy contributable to enhancement of the stress corrosion cracking resistance. The present invention is directed to an Sn-containing Bi-based, Sn-containing Bi+Sb-based or Sn-containing Bi+Se+Sb-based leadless brass alloy excellent in stress corrosion cracking resistance, having an α+γ structure or α+β+γ structure and having γ phases distributed uniformly therein at a predetermined proportion to suppress local corrosion and induction of stress corrosion cracks.
1. A leadless brass alloy excellent in stress corrosion cracking resistance,
wherein the alloy contains 59.5 to 66.0 mass% of Cu, 0.7 to 2.0 mass% of Sn, 0.5 to 2.0 mass% of Bi, 0.06 to 0.6 mass% of Sb and a balance of Zn and unavoidable impurities,
wherein the unavoidable impurities contain 0.25 mass% or less of Pb,
wherein the alloy has an α+γ structure and having γ phases distributed therein at a proportion to suppress a velocity of corrosion cracks propagating therein and enhance stress corrosion cracking resistance,
wherein the γ phases contain Sb as a solute, and
wherein a ratio of each of the γ phases to grains when the γ phases surround the grains is a grain-surrounding γ phase ratio, and a grain-surrounding average γ phase ratio that is an average value of grain-surrounding γ phase ratios is 28% or more to secure the proportion,
wherein the grain-surrounding average γ phase ratio is calculated by the following
grain-surrounding average γ phase ratio [%]=(γ phase length/grain boundary circumferential length)×100, Formula 1:
wherein the grain boundary circumferential length is a circumferential length of a grain boundary of the grains, and the γ phase length is a length of the γ phase existing on a circumference of the alloy.
2. The leadless brass alloy according to claim 1 , wherein a number of the γ phases existing in unit length in a vertical direction of a stress load when the load is exerted onto the alloy is the number of contacting γ phases, and the number of contacting γ phases calculated from an average value and a root-mean-square deviation of the number of contacting γ phases is two or more to secure the proportion.
3. The leadless brass alloy according to claim 1 , wherein the γ phases are uniformly distributed as anodes and maintain a balance relative to α phases that become cathodes.
4. The leadless brass alloy according to claim 1 , wherein the alloy is in a corrosion state in which a ratio of a maximum corrosion depth from a range of an alloy surface after corrosion to an average corrosion depth in the range is 1 to 8.6.
5. The leadless brass alloy according to claim 1 , wherein when a value obtained by dividing a root-mean-square deviation of a range of corrosion depth by an average corrosion depth in the range is a variation coefficient, the alloy assumes a corrosion configuration in which the variation coefficient is 1.18 or less.