Coating composition and articles made therefrom
View Patent ↗The present disclosure includes a waterborne polyolefin based coating layer that has improved features as compared to epoxy coatings. The coating composition of the present disclosure include 40 to 80 weight percent (wt. %) of a base polymer; 10 to 30 wt. % of a polymeric stabilizing agent; 5 to 15 wt. % of a polymeric coupling agent; 0 to 35 wt. % of a polymeric performance improving agent; a neutralizing agent that partially or fully neutralize the polymeric stabilizing agent; and a fluid medium, where the wt. % values are based on the total weight of the base polymer, the polymeric coupling agent, the polymeric stabilizing agent and, when present, the polymeric performance improving agent (as used herein, this total weight of the base polymer, the polymeric coupling agent, the polymeric stabilizing agent and, when present, the polymeric performance improving agent may be referred to as the “solid content” of the coating composition).
1. A coating composition, comprising:
40 to 80 weight percent (wt. %) of a base polymer;
5 to 15 wt. % of a polymeric coupling agent;
10 to 30 wt. % of a polymeric stabilizing agent;
0 to 35 wt. % of a polymeric performance improving agent;
a neutralizing agent that partially or fully neutralizes the polymeric stabilizing agent; and
a fluid medium, where the percent values are based on the total weight of the base polymer, the polymeric coupling agent, the polymeric stabilizing agent and, when present, the polymeric performance improving agent of the coating composition and sum to a value of 100 wt. %, wherein the base polymer is selected from the group consisting of a non-functionalized ethylene polymer, a non-functionalized propylene polymer, a non-functionalized propylene/ethylene copolymer, and a combination thereof.
2. The coating composition of claim 1 , where the non-functionalized ethylene polymer is selected from the group consisting of polyethylene, a polyethylene-copolymer and a combination thereof.
3. The coating composition of claim 1 , where the non-functionalized ethylene polymer, non-functionalized propylene polymer, or non-functionalized ethylene/propylene copolymer has a crystalline melting point of 100° C. to 230° C.
4. The coating composition of claim 1 , where the base polymer is a non-functionalized propylene polymer.
5. The coating composition of claim 1 , where the polymeric stabilizing agent is an ethylene-acrylic acid and ethylene-methacrylic acid copolymer having a functionality in a range of 10 wt. % to 25 wt. %.
6. The coating composition of claim 1 , where the polymeric coupling agent is selected from the group consisting of a functionalized polypropylene, a functionalized polyethylene homopolymer, a copolymer that has been modified with carboxylic acid groups, a copolymer that has been modified with anhydride groups and a combination thereof.
7. The coating composition of claim 1 , where the polymeric performance improving agent is selected from the group consisting of functionalized polyethylene, functionalized polypropylene, non-functionalized copolymer of ethylene and propylene and a combination thereof.
8. The coating composition of claim 1 , where acid groups of the polymeric stabilizing agent are neutralized with the neutralizing agent.
9. The coating composition of claim 1 , where the neutralizing agent is a volatile base.
10. The coating composition of claim 9 , where the volatile base is N,N-dimethylethanolamine.
11. The coating composition of claim 1 , where the fluid medium is water.
12. A coating layer formed with the coating composition of claim 1 .
13. The coating layer of claim 12 , where the coating layer is on a substrate.
14. The coating layer of claim 13 , where the substrate is selected from the group consisting of a metal, a polyurethane, a cured epoxy, a cement or a combination thereof.