Adhesive, polarizing plate including an adhesive layer prepared from the adhesive, and optical member including the polarizing plate
An adhesive for adhering a protective film, the protective film having a water vapor transmission rate of about 100 g/m 2 ·day or less at 40° C. and about 90% RH during manufacture of an optical member including a polarizing plate, a polarizing plate including an adhesive layer prepared from the adhesive, and an optical member including the polarizing plate, the adhesive including a (meth)acrylic copolymer, the (meth)acrylic copolymer having a weight average molecular weight of about 800,000 g/mol or more; a curing agent; and a silane coupling agent, wherein an adhesive layer prepared from the adhesive has a storage modulus, after curing, of about 8×10 3 Pa or more at about 85° C. and a frequency of about 10 −3 rad/s to about 10 2 rad/s.
1. An adhesive for adhering a protective film, the protective film having a water vapor transmission rate of about 100 g/m 2 ·day or less at 40° C. and about 90% RH during manufacture of an optical member including a polarizing plate, the adhesive comprising:
a (meth)acrylic copolymer, the (meth)acrylic copolymer having a weight average molecular weight of about 800,000 g/mol or more;
a curing agent; and
a silane coupling agent,
wherein an adhesive layer prepared by curing the adhesive has a storage modulus of about 8×10 3 Pa or more, when measured at about 85° C. and at a frequency of about 10 −3 rad/s to about 10 2 rad/s.
2. The adhesive as claimed in claim 1 , wherein the adhesive layer prepared by curing the adhesive has a storage modulus of about 27×10 3 Pa to about 2×10 5 Pa, when measured at about 85° C. and at a frequency of about 10 −3 rad/s to about 10 2 rad/s.
3. The adhesive as claimed in claim 1 , wherein the (meth)acrylic copolymer has a weight average molecular weight of about 800,000 g/mol to about 1,800,000 g/mol.
4. The adhesive as claimed in claim 1 , wherein the (meth)acrylic copolymer has a glass transition temperature of less than about −29° C.
5. The adhesive as claimed in claim 1 , wherein the (meth)acrylic copolymer is a copolymer of a hydroxyl group-containing (meth)acrylic monomer, an alkyl group-containing (meth)acrylic monomer, and a carboxylic acid group-containing (meth)acrylic monomer.
6. The adhesive as claimed in claim 1 , wherein the curing agent includes an isocyanate curing agent, a carbodiimide curing agent, an epoxy curing agent, an aziridine curing agent, a melamine curing agent, an amine curing agent, an imide curing agent, an amide curing agent, or mixtures thereof.
7. The adhesive as claimed in claim 1 , wherein the curing agent includes a mixture of an isocyanate curing agent and a carbodiimide curing agent in a weight ratio of about 2:1 to 30:1.
8. The adhesive as claimed in claim 1 , wherein the curing agent is present in the adhesive in an amount of about 0.5 parts by weight to about 5 parts by weight, based on 100 parts by weight of the (meth)acrylic copolymer.
9. The adhesive as claimed in claim 1 , wherein the silane coupling agent includes an epoxy group.
10. The adhesive as claimed in claim 1 , wherein the silane coupling agent is present in the adhesive in an amount of about 0.01 parts by weight to about 5 parts by weight, based on 100 parts by weight of the (meth)acrylic copolymer.
11. A polarizing plate comprising an adhesive layer prepared by curing the adhesive as claimed in claim 1 .
12. The polarizing plate as claimed in claim 11 , further comprising a protective film on the adhesive layer, the protective film having a water vapor transmission rate of about 100 g/m 2 ·day or less at 40° C. and about 90% RH.
13. The polarizing plate as claimed in claim 12 , wherein the protective film includes a cyclic polyolefin, polycarbonate, polyester, polyethersulfone, polysulfone, polyamide, polyimide, polyolefin, polyarylate, polyvinyl alcohol, polyvinyl chloride, polyvinylidene chloride films, or mixtures thereof.
14. The polarizing plate as claimed in claim 11 , wherein the polarizing plate includes:
a polarizer;
a first protective film stacked on an upper side of the polarizer; and
a second protective film stacked on a lower side of the polarizer, the second protective film:
having a water vapor transmission rate of about 100 g/m 2 ·day or less at about 40° C. and about 90% RH, and
being between the adhesive layer and the polarizer.
15. The polarizing plate as claimed in claim 11 , wherein the polarizing plate includes:
a polarizer;
a first protective film stacked on an upper side of the polarizer;
a second protective film stacked on a lower side of the polarizer; and
a third protective film stacked on a lower side of the second protective film,
wherein:
at least one of the second protective film and the third protective film has a water vapor transmission rate of about 100 g/m 2 ·day or less at about 40° C. and about 90% RH, and
the adhesive layer includes a first adhesive layer and a second adhesive layer, the first adhesive layer being between the second protective film and the third protective film and the third protective film being between the second adhesive layer and the first adhesive layer.
16. An optical member comprising the polarizing plate as claimed in claim 11 .