Method of increasing paper strength by using natural gums and dry strength agent in the wet end
View Patent ↗The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process. The method improves the efficiency of drainage aids or wet web strength aids or wet strength aid by coating at least some of the filler particles with a natural gum and with a material that prevents the filler materials form adhering to those additives. The drainage additive or wet web strength additive or wet strength aid holds the cellulose fibers together tightly and is not wasted on the filler particles.
1. A method of papermaking comprising:
combining a filler containing composition, glyoxylated acrylamide/DADMAC copolymer, and cellulose fiber stock comprising a plurality of cellulose fibers and water, thereby forming a combination; and
forming a paper mat from the combination;
wherein the filler containing composition comprises mineral particles and a natural gum coating at least a portion of the mineral particles, the natural gum selected from the group consisting of: xanthan gum, guar gum, derivatives thereof, and combinations thereof, wherein the filler containing composition has a viscosity of from 10% to 100% greater than a filler containing composition absent the natural gum.
2. The method of claim 1 , wherein the combination further comprises a drainage aid.
3. The method of claim 1 , wherein the mineral particles comprise calcium carbonate.
4. The method of claim 3 , wherein the calcium carbonate is selected from the group consisting of: undispersed calcium carbonate, dispersed slurry calcium carbonate, chalk, PCC, GCC, and combinations thereof.
5. The method of claim 3 , wherein at least a portion of the calcium carbonate is dispersed slurry calcium carbonate.
6. The method of claim 5 , wherein the calcium carbonate dispersed slurry further comprises at least one item selected from the group consisting of: a polyacrylic acid polymer dispersant, a sodium polyphosphate dispersant, Kaolin clay, and combinations thereof.
7. The method of claim 1 , wherein the combination further comprises a coagulant.
8. The method of claim 7 , wherein the coagulant is selected from the group consisting of: an inorganic coagulant, an organic coagulant, a condensation polymerization coagulant, and combinations thereof.
9. The method of claim 7 , wherein the coagulant is selected from the group consisting of: alum, sodium aluminate, a polyaluminum chloride, aluminum chlorohydroxide, aluminum hydroxide chloride, polyaluminum hydroxychloride, a sulfated polyaluminum chloride, polyaluminum silica sulfate, ferric sulfate, ferric chloride, epichlorohydrin-dimethylamine (“EPI-DMA”), an EPI-DMA ammonia crosslinked polymer, a polymer of ethylene dichloride and ammonia, a polymer of ethylene dichloride, a polymer of dimethylamine, a condensation polymer of multifunctional diethylenetriamine, a condensation polymer of multifunctional tetraethylenepentamine, a condensation polymer of multifunctional hexamethylenediamine, a condensation polymer of multifunctional ethylenedichloride, a melamine polymer, a formaldehyde resin polymer, a cationically charged vinyl addition polymer, and combinations thereof.
10. The method of claim 7 , wherein the coagulant is an AcAm/DADMAC copolymer.
11. The method of claim 1 , wherein the glyoxylated acrylamide/DADMAC copolymer is present in the paper mat at a ratio of 0.3 to 5 kg of strength additive per ton of the solid portion of the paper mat.
12. The method of claim 1 , wherein the paper mat has a solid portion, and the filler in the paper mat comprises up to 50% by mass of the solid portion of the paper mat.