Crosslinkable urethane acrylate charge transport molecules for overcoat
View Patent ↗An overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a urethane methacrylate functional charge transport molecule, and a photoinitiator. The urethane acrylate functional charge transport molecule is a reaction product of hydroxyl functional charge transport molecule and a monomer having an isocyanate group and an acrylate group. This overcoat layer improves wear resistance of the organic photoconductor drum without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its useful life.
1. An overcoat layer for an organic photoconductor drum, the overcoat layer prepared from a curable composition comprising:
a urethane acrylate functional charge transport molecule that is a reaction product of hydroxyl functional charge transport molecule and a monomer having an isocyanate group and an acrylate group; and
a photoinitiator.
2. The overcoat layer of claim 1 , wherein the hydroxyl functional charge transport molecule is selected from the group consisting of a di-hydroxy functional charge transport molecule, a tri-hydroxy functional charge transport molecule, and a tetra-hydroxy functional charge transport molecule.
3. The overcoat layer of claim 1 , wherein the urethane acrylate functional charge transport molecule comprises tri-arylamine of formulae (I)-(IV):
wherein x has a value of a whole number; n has a value of a counting number; R′ is H or CH 3 ; and R is H or CH 3 .
4. The overcoat layer of claim 1 , wherein the urethane acrylate functional charge transport molecule comprises tetra-aryl benzidine of formulae (V)-(XII):
wherein x has a value of a whole number; n has a value of a counting number; R is H or CH 3 ; R1 is H or CH 3 ; and R2 is H or CH 3 .
5. The overcoat layer of claim 1 , wherein the urethane acrylate functional charge transport molecule comprises tetra-aryl phenylene diamine of formulae (XIII)-(XVI):
wherein x has a value of a whole number; n has a value of a counting number; R is H or CH 3 ; R1 is H or CH 3 ; and R2 is H or CH 3 .
6. The overcoat layer of claim 1 , wherein the curable composition further comprises crosslinkable additives comprising acrylates, diacrylates or urethane acrylates.
7. The overcoat layer of claim 1 , wherein the curable composition further comprises a hexa-functional aromatic urethane acrylate resin.
8. The overcoat layer of claim 1 , wherein the curable composition further comprises a hexa-functional aliphatic urethane acrylate resin.
9. The overcoat layer of claim 1 , wherein the overcoat layer has a thickness of about 0.1 μm to about 10 μm.
10. An organic photoconductor drum comprising:
a support element;
a charge generation layer disposed over the support element;
a charge transport layer disposed over the charge generation layer; and
a protective overcoat layer formed as an outermost layer of the organic photoconductor drum, the protective overcoat layer being formed from a curable composition including:
a urethane methacrylate functional charge transport molecule or urethane acrylate functional charge transport molecule that is a reaction product of hydroxyl functional charge transport molecule and a monomer having an isocyanate group and an acrylate group; and
a photoinitiator.
11. The overcoat layer of claim 10 , wherein the hydroxyl functional charge transport molecule is selected from the group consisting of a di-hydroxy functional charge transport molecule, a tri-hydroxy functional charge transport molecule, and a tetra-hydroxy functional charge transport molecule.