Photo conductor overcoat comprising radical polymerizable charge transport molecules and hexa-functional urethane acrylates
View Patent ↗An overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from an (UV) ultraviolet curable composition including a urethane resin having at least six radical polymerizable functional groups and a charge transport molecule having at least one radical polymerizable functional group. The amount of the urethane resin having at least six radical polymerizable functional groups in the curable composition is about 35 percent to about 65 percent by weight. The amount of the charge transport molecules having at least one radical polymerizable functional group in the curable composition is about 35 percent to about 65 percent by weight. This overcoat layer improves wear resistance of the organic photoconductor drum without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its useful life.
1. An overcoat layer for an organic photoconductor drum, comprising an ultraviolet curable composition including:
about 35 percent to about 65 percent by weight of a urethane acrylate resin having at least six radical polymerizable functional groups,
about 35 percent to about 65 percent by weight of a charge transport molecule having at least one radical polymerizable functional group,
an organic solvent;
and a photoinitiator.
2. The overcoat layer of claim 1 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aromatic urethane acrylate resin.
3. The overcoat layer of claim 1 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aliphatic urethane acrylate resin.
4. The overcoat layer of claim 1 , wherein the charge transport molecule comprises a tryarylamine having at least one radical polymerizable functional group.
5. The overcoat layer of claim 1 , wherein the charge transport molecule comprises a tetraphenylbenzidine having at least one radical polymerizable functional group.
6. The overcoat layer of claim 1 , wherein the curable composition further includes a monomer or oligomer having at most five radical polymerizable functional groups.
7. The overcoat layer of claim 1 , wherein the curable composition further includes a non-radical polymerizable additive at an amount equal to or less than about 10 percent by weight of the curable composition.
8. The overcoat layer of claim 7 , wherein the amount of non-radical polymerizable additive is about 0.1 to about 5 percent by weight of the curable composition.
9. The overcoat layer of claim 1 , wherein a cured curable composition has a thickness of about 0.1 μm to about 10 μm.
10. An organic photoconductor drum comprising:
a support element;
a charge generation layer disposed over the support element;
a charge transport layer disposed over the charge generation layer; and
a protective overcoat layer formed as an outermost layer of the organic photoconductor drum, the protective overcoat layer being formed from a curable composition including:
about 35 percent to about 65 percent by weight of a urethane acrylate resin having at least six radical polymerizable functional groups; and
about 35 percent to about 65 percent by weight of a charge transport molecule having at least one radical polymerizable functional group.
11. The organic photoconductor drum of claim 10 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aromatic urethane acrylate resin.
12. The organic photoconductor drum of claim 11 , wherein the overcoat layer has a thickness of about 0.1 μm to about 10 μm.
13. The organic photoconductor drum of claim 10 , wherein the urethane acrylate resin having at least six radical polymerizable functional groups is a hexa-functional aliphatic urethane acrylate resin.
14. The organic photoconductor drum of claim 10 , wherein the charge transport molecule comprises a tryarylamine having at least one radical polymerizable functional group.
15. The organic photoconductor drum of claim 10 , wherein the charge transport molecule comprises a tetraphenylbenzidine having at least one radical polymerizable functional group.
16. The organic photoconductor drum of claim 10 , wherein the curable composition further includes a monomer or oligomer having at most five radical polymerizable functional groups.
17. The organic photoconductor drum of claim 10 , wherein the curable composition further includes a non-radical polymerizable additive at an amount equal to or less than about 10 percent by weight of the curable composition.
18. The organic photoconductor drum of claim 17 , wherein the amount of non-radical polymerizable additive is about 0.1 to about 5 percent by weight of the curable composition.