Solid tablet unit dose oven cleaner
A solidification matrix includes sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer or salt or derivative thereof, and additional functional ingredients. The sodium hydroxide, sodium carbonate, a water charge, an anhydrous metasilicate, a polycarboxylic acid polymer, and additional functional ingredients interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition. Methods of making solid detergent compositions are disclosed.
1. A hydrate solid detergent composition consisting essentially of:
an alkali metal hydroxide alkalinity source;
sodium carbonate;
an anhydrous silicate secondary alkalinity source;
water;
at least one functional ingredient selected from the group consisting of a secondary alkalinity source, detergent builder, surfactant, corrosion inhibitor, water conditioning agent, chelant, flow aid and combinations thereof;
wherein the solid detergent composition is phosphorus-free and is a dimensionally stable hydrate solid that if heated at a temperature of 120 degrees Fahrenheit, the hydrate solid detergent composition has a growth exponent of less than 3%.
2. The composition of claim 1 , wherein the at least one functional ingredient is selected from the group consisting of a secondary alkalinity source, detergent builder, surfactant, corrosion inhibitor, water conditioning agent, chelant, flow aid and combinations thereof.
3. The composition of claim 1 , wherein the functional ingredient is a polyacrylic acid polymer or salt or derivative thereof.
4. The composition of claim 1 , wherein the functional ingredient is a polycarboxylic acid polymer is a polyacrylic acid polymer or a polyacrylate polymer, and constitutes between about 0.1% and about 15% by weight of the composition.
5. The composition of claim 1 , wherein the sodium carbonate constitutes between about 20% and about 90% by weight of the composition.
6. The composition of claim 1 , wherein the water constitutes between about 0.1% and about 10% by weight of the composition.
7. The composition of claim 1 , wherein the composition does not include a polyethylene glycol(s) and/or urea.
8. The composition of claim 1 , wherein the alkali metal hydroxide is sodium hydroxide and constitutes between about 5% and 70% by weight of the composition.
9. The composition of claim 1 , wherein the at least one functional ingredient is a secondary alkalinity source and constitutes between about 1% and 50% by weight of the composition.
10. The composition of claim 1 , wherein the at least one functional ingredient is a chelant and constitutes between about 1% and 50% by weight of the composition.
11. The composition of claim 1 wherein the composition is a hydrate solid tablet.
12. A hydrate solid detergent composition consisting essentially of:
between about 5% and about 70% sodium hydroxide by weight of the solid detergent composition;
between about 20% and about 90% sodium carbonate by weight of the solid detergent composition;
between about 0.1% and about 15% polycarboxylic acid polymer or salt or derivative thereof by weight of the solid detergent composition;
between about 0.1% and about 10% water by weight of the solid detergent composition;
between about 1% and about 50% secondary alkalinity source by weight of the solid detergent composition, wherein said alkalinity source is an anhydrous metasilicate;
between about 1% and about 50% chelant by weight of the solid detergent composition;
wherein the hydrate solid detergent composition is a phosphorus-free solid, wherein said hydrate solid if heated at a temperature of 120 degrees Fahrenheit is dimensionally stable and has a growth exponent of less than 3%.
13. The composition of claim 12 , wherein the sodium hydroxide constitutes between about 10% and 50% by weight of the composition, the sodium carbonate constitutes between about 30% and 70% by weight of the composition, the polycarboxylic acid polymer or salt or derivative thereof is a polyacrylate polymer and constitutes between about 2.5% and 10% by weight of the composition, the water constitutes between about 1% and 5% by weight of the composition, the secondary alkalinity source constitutes between about 1% and 20% by weight of the composition, and the chelant constitutes between about 5% and 25% by weight of the composition.
14. The composition of claim 13 , wherein the composition is a hydrate solid tablet that does not include polyethylene glycol(s), urea and/or potassium carbonate.
15. A method of forming a hydrate solid detergent composition, the method comprising:
combining sodium carbonate, an anhydrous metasilicate secondary alkalinity source and a chelant to form a powder pre-mix; mixing the powder pre-mix with a water source to form a solid hydrate; and combining the solid hydrate with a source of sodium hydroxide and a polycarboxylic acid polymer or salt or derivative thereof; wherein the composition consists essentially of between about 5% and about 70% sodium hydroxide by weight of the solid detergent composition, between about 20% and about 90% sodium carbonate by weight of the solid detergent composition, between about 0.1% and about 15% polycarboxylic acid polymer or salt or derivative thereof by weight of the solid detergent composition, between about 0.1% and about 10% water by weight of the solid detergent composition, between about 1% and about 50% secondary alkalinity source by weight of the solid detergent composition, and between about 1% and about 50% chelant by weight of the solid detergent composition;
wherein the solid detergent composition is phosphorous free, and wherein if heated at a temperature of 120 degrees Fahrenheit, the solid detergent composition is dimensionally stable and has a growth exponent of less than 3%.
16. The method of claim 15 , wherein the solid detergent composition is a tablet.
17. The method of claim 15 , wherein the solid detergent composition comprises between about 5% and about 70% sodium hydroxide, between about 20% and about 90% sodium carbonate, between about 0.1% and about 15% polycarboxylic acid polymer or salt or derivative thereof, between about 0.1% and about 10% water, between about 1% and about 50% secondary alkalinity source, and between about 1% and about 50% chelant by weight of the solid detergent composition.
18. The method of claim 15 , further comprising solidifying the composition at an ambient temperature between about 30° C. to about 50° C.
19. The method of claim 15 , wherein the dimensional stability of the solid detergent composition has a growth exponent of less than 2%.
20. The method of claim 15 , wherein the sodium hydroxide constitutes between about 10% and 50% by weight of the composition, the sodium carbonate constitutes between about 30% and 70% by weight of the composition, the polycarboxylic acid polymer or salt or derivative thereof is a polyacrylate polymer or salt or derivative thereof and constitutes between about 2.5% and 10% by weight of the composition, the water constitutes between about 1% and 5% by weight of the composition, the secondary alkalinity source constitutes between about 1% and 20% by weight of the composition, and the chelant constitutes between about 5% and 25% by weight of the composition.