Barrier layers comprising Ni-inclusive alloys and/or other metallic alloys, double barrier layers, coated articles including double barrier layers, and methods of making the same
View Patent ↗Certain example embodiments relate to Ni-inclusive ternary alloy being provided as a barrier layer for protecting an IR reflecting layer comprising silver or the like. The provision of a barrier layer comprising nickel, chromium, and/or molybdenum and/or oxides thereof may improve corrosion resistance, as well as chemical and mechanical durability. In certain examples, more than one barrier layer may be used on at least one side of the layer comprising silver. In still further examples, a Ni x Cr y Mo z -based layer may be used as the functional layer, rather than or in addition to as a barrier layer, in a coating.
1. A method of making a coated article including a coating supported by a glass substrate, the method comprising:
disposing a first dielectric layer on the substrate;
disposing a first sub-barrier layer comprising one or more of Nb, Ti, Cr, and Zr over the dielectric layer;
disposing a first barrier layer comprising a Ni-inclusive alloy over the first sub-barrier layer;
disposing an IR reflecting layer comprising silver over and contacting the first barrier layer comprising an Ni-inclusive alloy;
disposing a second oxided barrier layer comprising 54-58 wt. % Ni, 20-22.5 wt. % Cr, and 12.5-14.5 wt. % Mo over and contacting the IR reflecting layer; and
disposing a second sub-barrier layer comprising one or more of Nb, Ti, Cr, and Zr over the second oxided barrier layer.
2. The method of claim 1 , wherein the coating is used as a low-E coating.
3. The method of claim 1 , wherein the first barrier layer comprising an Ni-inclusive alloy comprises NiTi or an oxide thereof.
4. The method of claim 1 , wherein the first barrier layer comprising an Ni-inclusive alloy comprises NiCr or an oxide thereof.
5. The method of claim 1 , wherein the first barrier layer comprising an Ni-inclusive alloy comprises NiCrMo or an oxide thereof.
6. The method of claim 1 , wherein at least one of the first and second sub-barrier layers comprises NbZr.
7. The method of claim 1 , wherein the first and second barrier layers comprise 54-58 wt. % Ni, 20-22.5 wt. % Cr, and 12.5-14.5 wt. % Mo, and wherein the first and second sub-barrier layers comprise NbZr.
8. The method of claim 1 , wherein the first and second sub-barrier layers are each sandwiched by dielectric layers.
9. The method of claim 1 , further comprising disposing a second dielectric layer between the first sub-barrier layer and the first barrier layer.
10. The method of claim 9 , further comprising disposing a third dielectric layer between the second barrier layer and the second sub-barrier layer.
11. The method of claim 1 , wherein the first barrier layer is provided over and directly contacting the first sub-barrier layer.
12. The method of claim 1 , wherein the second sub-barrier layer is provided over and directly contacting the second barrier layer.
13. The method of claim 1 , wherein the first barrier layer is provided over and directly contacting the first sub-barrier layer, and wherein the second sub-barrier layer is provided over and directly contacting the second barrier layer.
14. The method of claim 1 , wherein the coating comprises a second IR reflecting layer comprising silver.
15. The method of claim 14 , wherein the coating further comprises a third barrier layer comprising Ni, Cr, Ti, and/or Mo over and contacting the second IR reflecting layer, and a third-sub barrier layer comprising one or more of Nb, Ti, Cr, and Zr over and contacting the third barrier layer.
16. A method of making an insulated glass (IG) unit, the method comprising:
providing the coated article of claim 1 ; and
providing a second substrate;
positioning the coated article relative to the second substrate so that the coating on the coated article is located on surface 1 or on surface 4 of the IG unit in making the IG unit.
17. A method of making an insulated glass (IG) unit, the method comprising:
providing first and second coated articles according of claim 1 ; and
positioning the first and second coated article relative to one another so that the of the first and/or second coatings on the first and/or second coated articles is/are on an exterior surface of the IG unit in making the IG unit.
18. A method of making a coated article including a coating supported by a glass substrate, the method comprising:
disposing a dielectric layer on the substrate;
disposing a first sub-barrier layer comprising one or more of Nb, Ti, Cr, and Zr over the dielectric layer;
disposing a first barrier layer comprising Ni, Cr, Ti, and/or Mo over the first sub-barrier layer;
disposing an IR reflecting layer comprising silver over and contacting the first barrier layer comprising Ni, Cr, Ti, and/or Mo;
disposing a second oxided barrier layer comprising 54-58 wt. % Ni, 20-22.5 wt. % Cr, and 12.5-14.5 wt. % Mo over and contacting the IR reflecting layer; and
disposing a second sub-barrier layer comprising one or more of Nb, Ti, Cr, and Zr over the second oxided barrier layer.
19. The method of claim 18 , wherein the coating comprises only one IR reflecting layer, and wherein the coated article is used monolithically.
20. A method of making an insulated glass (IG) unit, the method comprising:
providing the coated article of claim 18 ; and
providing a second substrate;
positioning the coated article relative to the second substrate so that the coating on the coated article is located on surface 1 or on surface 4 of the IG unit in making the IG unit.
21. A method of making an insulated glass (IG) unit, the method comprising:
providing first and second coated articles according of claim 18 ; and
positioning the first and second coated article relative to one another so that the of the first and/or second coatings on the first and/or second coated articles is/are on an exterior surface of the IG unit in making the IG unit.
22. A method of making a coated article, the method comprising:
disposing a dielectric layer on a glass substrate;
disposing a first oxided barrier layer comprising 54-58 wt. % Ni, 20-22.5 wt. % Cr, and 12.5-14.5 wt. % Mo over the dielectric layer;
disposing an IR reflecting layer comprising silver over and contacting the first oxided barrier layer;
disposing a second barrier layer comprising NiTi or an oxide thereof over and contacting the IR reflecting layer;
disposing a third barrier layer comprising NiCr or an oxide thereof over and contacting the second barrier layer; and
disposing a fourth barrier layer comprising an oxide of Sn, Ti, Cr, Nb, Zr, Mo, W, and/or Co over and contacting the third barrier layer.