Aqueous polymer dispersions
View Patent ↗An aqueous polymer composition is described comprising a homogeneous acrylic polymer dispersion produced by emulsion polymerization of a monomer mixture comprising: (A) from 85 to 99.9 wt % of one or more main monomers selected from C 1 -C 12 -alkyl esters of acrylic acid or C 5 -C 12 -alkyl esters of methacrylic acid, styrene, and vinyl toluene in such a ratio as to produce a polymer having a Tg in the range of −20 to +65° C.; and (B) from 0.1 to 5 wt % of at least one stabilizing monomer selected from ethylenically unsaturated monocarboxylic acids or amides thereof, ethylenically unsaturated dicarboxylic acids or anhydrides or amides thereof, ethylenically unsaturated sulfonic acids, ethylenically unsaturated phosphoric acids, and ethylenically unsaturated phosphonic acids. The emulsion polymerization is conducted in the presence of 0.05 to 3 wt %, based on the total weight of monomers in the monomer mixture, of a chain transfer agent (C).
1. An aqueous polymer composition comprising a heterogeneous polymer dispersion prepared by a stepwise emulsion polymerization process comprising polymerizing in a first stage a first monomer composition comprising:
(A1) from 50 to 80% by weight of at least one main monomer whose homopolymer has a glass transition temperature below about 0° C.;
(A2) from 19.3 to 50% by weight of at least one main monomer whose homopolymer has a glass transition temperature above about 65° C.; and
(B) from 0.5 to 5% by weight of at least one stabilising monomer selected from ethylenically unsaturated monocarboxylic acids or amides thereof, ethylenically unsaturated dicarboxylic acids or anhydrides or amides thereof, ethylenically unsaturated sulfonic acids, ethylenically unsaturated phosphoric acids, and ethylenically unsaturated phosphonic acids; and
wherein the first polymerization stage is conducted in the presence of 0.05 to 3 wt %, based on the total weight of monomers in the first monomer composition, of a chain transfer agent (C) to produce a first polymer phase having a Tg less than or equal to 20° C.; and
polymerizing in a second stage, and in the presence of the first polymer phase, a second monomer composition comprising:
(A1) from 5 to 45% by weight at least one monomer whose homopolymer has a glass transition temperature below about 0° C.; and
(A2) from 65 to 90% by weight at least one monomer whose homopolymer has a glass transition temperature above about 65° C. to produce a second polymer phase having a Tg of at least 40° C.
2. The aqueous polymer composition of claim 1 , wherein the first polymer phase has a Tg less than or equal to 0° C.
3. The aqueous polymer composition of claim 1 , wherein the second polymer phase has a Tg of at least 50° C.
4. The aqueous polymer composition of claim 1 , wherein the difference in glass transition temperature between the first and second polymer phases is at least 20° C.
5. The aqueous polymer composition of claim 1 , wherein the weight ratio of the first polymer phase to the second copolymer phase is from generally from 50:50 to 75:25.
6. The aqueous polymer composition of claim 1 , wherein the monomers (A1) of the first and second monomer compositions are separately selected from the group consisting of C 1 -C 12 -alkyl esters of acrylic acid and C 5 -C 12 -alkyl esters of methacrylic acid.
7. The aqueous polymer composition of claim 1 , wherein the monomers (A2) of the first and second monomer compositions are separately selected from the group consisting of styrene, vinyltoluene, acrylonitrile, methacrylonitrile, and C1-C4-alkyl esters or cycloalkyl esters of methacrylic acid.
8. The aqueous polymer composition of claim 1 , wherein the second monomer composition further comprises up to 4% by weight, based on the total weight of monomers in the second monomer composition, of (B) of at least one stabilising monomer selected from ethylenically unsaturated monocarboxylic acids or amides thereof, ethylenically unsaturated dicarboxylic acids or anhydrides or amides thereof, ethylenically unsaturated sulfonic acids, ethylenically unsaturated phosphoric acids, and ethylenically unsaturated phosphonic acids.
9. The aqueous polymer composition of claim 1 , wherein the second monomer composition further comprises up to 5% by weight, based on the total weight of monomers in the second monomer composition, of a chain transfer agent (C).
10. The aqueous polymer composition of claim 9 , wherein the ratio of the amount of chain transfer agent used in the polymerization of the first monomer composition to the amount of chain transfer agent used in the polymerization of the second monomer composition is greater than 1:1.
11. The aqueous polymer composition of claim 1 , wherein each of the first and second monomer compositions further includes up to 10% by weight of at least one ethylenically unsaturated functional monomer containing one or more carbonyl groups.
12. The aqueous polymer composition of claim 1 , wherein the at least one chain transfer agent (C) comprises a mercaptan.
13. The aqueous polymer composition of claim 1 , wherein the polymer dispersion has an average particle diameter size ranging from about 60 nm to about 150 nm.
14. The aqueous polymer composition of claim 1 and further comprising an aqueous autoxidable material comprising an alkyd resin.
15. The aqueous polymer composition of claim 14 , wherein the polymer dispersion is present in an amount from about 50 weight percent to about 90 weight percent based on the total weight of the polymer composition and the aqueous autoxidable material is present in an amount from about 10 weight percent to about 50 weight percent based on the total weight of the polymer composition.
16. The aqueous polymer composition of claim 14 , wherein the aqueous autoxidable material comprises an acrylic and urethane modified alkyd resin.
17. The aqueous polymer composition of claim 14 , wherein the aqueous autoxidable material has an average particle diameter size of less than about 300 nm.
18. A coating composition comprising the aqueous polymer composition of claim 14 .
19. The aqueous polymer composition of claim 1 , wherein the first polymerization stage is conducted in the presence of 0.5 to 2 wt%, based on the total weight of monomers in the first monomer composition, of a chain transfer agent (C) to produce a first polymer phase having a Tg less than or equal to 20° C.