X-ray and/or metal detectable articles and method of making the same
View Patent ↗An article and thermoplastic composition including polycarbonate, a polysiloxane-polycarbonate and an x-ray detectable or metal detectable agent having good magnetic permeability and/or electrical conductivity wherein the composition may be used in articles for food preparation. The thermoplastic compositions are useful in forming molds for manufacturing a food product, such as chocolate molds.
1. A thermoplastic composition comprising:
from 65 to 95% by weight of polycarbonate;
from 5 to 35% by weight of a polysiloxane-polycarbonate copolymer; and
from 0.01 to 10% by weight of a metal detectable agent having a median particle size of less than or equal to 5 micrometers;
wherein the thermoplastic composition has a siloxane content of 0.1 to 4 wt % siloxane units, based on the total weight of the thermoplastic composition,
wherein an article molded from the thermoplastic composition and having a thickness of 3.2 mm has a notched Izod impact (NII) strength of greater than or equal to 500 J/m, when measured at a temperature of 23° C. according to ASTM D256-04, and a notched Izod impact strength of greater than or equal to 350 J/m, when measured at a temperature of 0° C. according to ASTM D256-04.
2. The composition of claim 1 , wherein the polysiloxane-polycarbonate copolymer comprises 65 to 85 wt % of carbonate units and 5-35 wt % siloxane units, based on the total weight of the polysiloxane-polycarbonate.
3. The composition of claim 1 , comprising polysiloxane-polycarbonate in an amount of 10 to 25 parts by weight, and polycarbonate in an amount of 75 to 90 parts by weight, based on combined 100 parts by weight of polysiloxane-polycarbonate and any added polycarbonate.
4. The composition of claim 1 , wherein the metal detectable agent has a median particle size of 0.01 to 0.5 micrometers.
5. The composition of claim 1 , wherein the metal detectable agent has a median particle size of less than or equal to 1 micrometer.
6. The composition of claim 1 , wherein the metal detectable agent is a ferrous metal.
7. The composition of claim 6 , wherein the metal detectable agent comprises magnetite.
8. The composition of claim 7 , wherein the magnetite has a median particle size of 0.01 to about 0.5 micrometers.
9. The composition of claim 1 wherein the polysiloxane-polycarbonate copolymer comprises 65 to 85 wt % of carbonate units and 5-35 wt % siloxane units, based on the total weight of the polysiloxane-polycarbonate.
10. The composition of claim 1 , wherein the thermoplastic composition further comprises additives including impact modifiers, fillers, colorants including dyes and pigments, antioxidants, heat stabilizers, light, stabilizers, UV light stabilizers, plasticizers, lubricants, mold release agents, flame retardants, antistatic agents, anti-drip agents, radiation stabilizers, or a combination comprising at least one of the foregoing additives.
11. An article comprising a thermoplastic composition comprising:
from 65 to 95% by weight of polycarbonate;
from 5 to 35% by weight of a polysiloxane-polycarbonate copolymer; and
from 0.01 to 10% by weight of magnetite having a median particle size of less than or equal to 5 micrometers;
wherein the thermoplastic composition has a siloxane content of 0.1 to 4 wt % siloxane units, based on the total weight of the thermoplastic composition,
wherein an article molded from the thermoplastic composition and having a thickness of 3.2 mm has a notched Izod impact (NII) strength of greater than or equal to 500 J/m, when measured at a temperature of 23° C. according to ASTM D256-04, and a notched Izod impact strength of greater than or equal to 350 J/m, when measured at a temperature of 0° C. according to ASTM D256-04.
12. The article of claim 11 , wherein the article is an article for the food service industry, a medical device, or a toy.
13. A mold for manufacturing a food product, comprising a thermoplastic composition comprising:
a) from 65 to 95% by weight of polycarbonate;
b) from 5 to 35% by weight of a polysiloxane-polycarbonate copolymer; and
c) from 0.01 to 10% by weight of a metal detectable agent having a median particle size of less than or equal to 5 micrometers;
wherein the thermoplastic composition has a siloxane content of 0.1 to 4 wt % siloxane units, based on the total weight of the thermoplastic composition,
wherein an article molded from the thermoplastic composition and having a thickness of 3.2 mm has a notched Izod impact (NII) strength of greater than or equal to 500 J/m, when measured at a temperature of 23° C. according to ASTM D256-04, and a notched Izod impact strength of greater than or equal to 350 J/m, when measured at a temperature of 0° C. according to ASTM D256-04;
wherein degradation of the mold is metal detectable.
14. A method for increasing the metal detectability in an article comprising a thermoplastic composition, comprising
combining a metal detectable agent having a median particle size of less than or equal to 5 micrometers with polycarbonate and a polysiloxane-polycarbonate copolymer to form the thermoplastic composition; wherein the thermoplastic composition has a siloxane content of 0.1 to 4 wt % siloxane units, based on the total weight of the thermoplastic composition; and
forming the article from the thermoplastic composition,
wherein a molded article, molded from the thermoplastic composition and having a thickness of 3.2 mm has a notched Izod impact (NII) strength of greater than or equal to 500 J/m, when measured at a temperature of 23° C. according to ASTM D256-04, and
a notched Izod impact strength of greater than or equal to 350 J/m, when measured at a temperature of 0° C. according to ASTM D256-04.