Hot dip galvannealed steel sheet and method for producing the same
View Patent ↗Exemplary embodiments of the present invention can provide a hot dip galvannealed steel sheet which has excellent corrosion resistance, workability, coatability and appearance. The exemplary galvannealed sheet can include an ultra-low carbon steel sheet having a plating layer which includes about 8 to 13% Fe, about 0.05 to 1.0% Ni, about 0.15 to 1.5% Al, and a balance of Zn and unavoidable impurities. An exemplary method for producing a hot dip galvannealed steel sheet is also provided which can include cleaning an annealed ultra-low carbon steel sheet, preplating it with Ni, rapidly heating the sheet in a nonoxidizing or reducing atmosphere, plating the sheet in a galvanization bath containing Al, wiping it, then rapidly reheating it and either cooling the sheet without any soaking time or soaking and holding it for less than 15 seconds and then cooling it.
1. A method for producing a hot dip galvannealed steel sheet having an average thickness of a Γ layer of a base iron boundary of 1 μm or less, and having a variation of said average thickness of ±0.3 μm or less, comprising:
cleaning a surface of a steel sheet comprising 0.005% C or less, wherein a solutal carbon in the steel sheet is eliminated by adding Ti or Nb, alone or complexly, to the steel sheet;
preplating the annealed steel sheet with between about 0.05 and about 1.0 g/m 2 of Ni;
preparing the annealed steel sheet by heating it in at least one of a nonoxidizing atmosphere or a reducing atmosphere to a temperature between about 430° C. and about 500° C. at a rate of at least about 30° C/sec;
plating the carbon steel sheet in a hot dip galvanization bath comprising between about 0.07 and about 0.2 mass % Al;
wiping the carbon steel sheet;
reheating the carbon steel sheet to between about 470° C. and about 600° C. at a rate of at least about 30° C/sec; and
cooling the carbon steel sheet without any soaking time, or soaking and holding the carbon steel sheet for 4 seconds or less and then cooling the carbon steel sheet, to form the galvannealed steel sheet.
2. The method of claim 1 , wherein the carbon steel sheet is preplated with between about 0.1 and about 1.0 g/m 2 of Ni.
3. The method of claim 1 , wherein the carbon steel sheet is preplated with between about 0.5 and about 1.0 g/m 2 of Ni.
4. The method of claim 1 , wherein the carbon steel sheet is preplated with between about 0.1 and about 0.8 g/m 2 of Ni.
5. The method of claim 1 , wherein the hot dip galvanization bath comprises between about 0.1 and about 0.2 mass % of Al.
6. The method of claim 1 , wherein the hot dip galvanization bath comprises between about 0.12 and about 0.2 mass % of Al.
7. The method of claim 1 , wherein the heating is performed such that the carbon steel sheet reaches a temperature between about 430° C. and about 480° C.
8. The method of claim 1 , wherein the reheating is performed such that the carbon steel sheet reaches a temperature between about 470° C. and about 550° C.
9. The method of claim 1 , wherein the concentration of Al in the galvanization bath (expressed as [X] mass %) and the amount of Ni preplating (expressed as [Y] g/m 2 of Ni) satisfy the relationship [Y]≦15 ·[X]−1.