Heat transferable material for improved image stability
View Patent ↗A heat transferable material includes a heat transferable polymeric binder and a light stabilizer that is an N-oxyl radical derived from a hindered amine. The N-oxyl radical has the following formula (A) or formula (B): wherein R 1 , R 2 , R 5 , and R 6 are each a straight or branched C 1 -C 6 alkyl or alkene, and R 3 and R 4 are each independently H, CH 2 CH 3 , CH 3 , OH, OR, COOH, COOR, or NH—C(═O)R, wherein R is a straight or branched C 1 -C 6 alkyl or alkene, and having a molecular weight of 600 or less. At least one of R 3 and R 4 is not hydrogen. The heat transferable material can be in a section or patch on a thermal donor element to provide a protective overcoat material. A patch in the donor element can include a dye. The heat transferable material provides better image stability and improved iridescence when transferred to a receiver of some type.
1. A heat transferable donor element comprising a polymeric support, the support having at least one portion thereof coated with a heat transferable material comprising: crosslinked elastomeric organic beads; at least one light stabilizer that is an N-oxyl radical derived from a hindered amine, the N-oxyl radical having the following formula (A) or formula (B):
wherein R 1 , R 2 , R 5 , and R 6 are each independently selected from a straight or branched C 1 -C 6 alkyl or alkene, R 3 and R 4 are each independently selected from H, CH 2 CH 3 , CH 3 , OH, OR, COOH, COOR, or NH—C(═O)R, R is a straight or branched C 1 -C 6 alkyl or alkene, at least one of R 3 and R 4 is not hydrogen, and the N-oxyl radical has a molecular weight of 600 or less; at least one styrene/allyl alcohol copolymer resin; a UV absorbing material; and at least one poly(vinyl acetal) resin having the following Formula I:
wherein n is from 10 to 100, the heat transferable material comprising 40% to 90% by weight of the at least one poly(vinyl acetal) resin and 2% to 20% by weight of the UV absorbing material, based on the total dry weight of the heat transferable material.
2. The donor element of claim 1 , wherein the donor element further comprises one or more colored dye patches.
3. The donor element of claim 1 , wherein R 1 , R 2 , R 5 , and R 6 are independently H, CH 3 , or CH 2 CH 3 .
4. The donor element of claim 1 , wherein each of R 1 , R 2 , R 5 , and R 6 is CH 3 or each of R 1 , R 2 , R 5 , and R 6 is CH 2 CH 3 .
5. The donor element of claim 1 , wherein at least one of R 3 and R 4 is OH, CH 2 CH 3 , CH 3 , or —NH—C(═O)CH 3 .
6. A heat transferable overcoat material comprising:
crosslinked elastomeric organic beads; a light stabilizer that is an N-oxyl radical derived from a hindered amine, the N-oxyl radical having the following formula (A) or formula (B):
wherein R 1 , R 2 , R 5 , and R 6 are each independently selected from a straight or branched C 1 -C 6 alkyl or alkene, R 3 and R 4 are each independently selected from H, CH 2 CH 3 , CH 3 , OH, OR, COOH, COOR, or NH—C(═O)R, R is a straight or branched C 1 -C 6 alkyl or alkene at least one of R 3 and R 4 is not hydrogen, and the N-oxyl radical has a molecular weight of 600 or less; at least one styrene/allyl alcohol copolymer resin; a UV absorbing material; and at least one poly(vinyl acetal) resin having the following Formula I:
wherein n is from 10 to 100, the heat transferable overcoat material comprising 40% to 90% by weight of the at least one poly(vinyl acetal) resin and 2% to 20% by weight of the UV absorbing material, based on the total dry weight of the heat transferable material.
7. The overcoat material of claim 6 , wherein each of R 1 , R 2 , R 5 , and R 6 is CH 3 or each of R 1 , R 2 , R 5 , and R 6 is CH 2 CH 3 , and wherein at least one of R 3 and R 4 is OH, CH 2 CH 3 , CH 3 , or NH—C(═O)CH 3 .
8. A donor element comprising a polymeric support and the heat transferable overcoat material of claim 6 .
9. A method of coating a receiver element with a protective overcoat material, comprising:
contacting the donor element of claim 8 with the receiver element;
applying heat or pressure sufficient to transfer the heat transferable overcoat material from the donor element to the receiver element.
10. The method of claim 9 , wherein the receiver element is selected from the group consisting of an inkjet receiver, a thermal receiver, an electrophotographic receiver, and a silver halide print.
11. A thermal transfer assemblage comprising a receiver element in contact with at least a portion of a heat transferable donor element, wherein the donor element comprises a polymeric support, at least one portion thereof coated with a heat transferable overcoat material comprising: crosslinked elastomeric organic beads; a light stabilizer that is an N-oxyl radical derived from a hindered amine, the N-oxyl radical having the following formula (A) or formula (B):
wherein R 1 , R 2 , R 5 , and R 6 are each independently selected from a straight or branched C 1 -C 6 alkyl or alkene, R 3 and R 4 are each independently selected from H, CH 2 CH 3 , CH 3 , OH, OR, COOH, COOR, or NH—C(═O)R, R is a straight or branched C 1 -C 6 alkyl or alkene, at least one of R 3 and R 4 is not hydrogen, and the N-oxyl radical has a molecular weight of 600 or less; at least one styrene/allyl alcohol copolymer resin; a UV absorbing material; and at least one poly(vinyl acetal) resin having the following Formula I:
wherein n is from 10 to 100, the heat transferable overcoat material comprising 40% to 90% by weight of the at least one poly(vinyl acetal) resin and 2% to 20% by weight of the UV absorbing material, based on the total dry weight of the heat transferable material.
12. The assemblage of claim 11 , wherein the donor element comprises two or more patches, and wherein at least one patch includes a dye and at least one patch includes the heat transferable overcoat material.
13. The assemblage of claim 11 , wherein the receiver element is selected from the group consisting of an inkjet receiver, a thermal receiver, an electrophotographic receiver, and a silver halide print.
14. The assemblage of claim 11 , wherein each of R 1 , R 2 , R 5 , and R 6 is CH 3 or each of R 1 , R 2 , R 5 , and R 6 is CH 2 CH 3 , and wherein at least one of R 3 and R 4 is OH, CH 2 CH 3 , CH 3 , or NH—(C═O)CH 3 .
15. The assemblage of claim 11 , wherein the receiver element comprises a receiver layer and the receiver layer comprises a plasticizer.