IP Library Granted Patent US 9,819,040
Granted Patent B2
US 9,819,040 · App. 13/746,564 · Granted Nov 14, 2017

Printed fuel cell with integrated gas channels

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Quick Facts
Patent No.
US 9,819,040
App. No.
13/746,564
Granted
Nov 14, 2017
Kind
B2
Abstract

A printed fuel cell having integrated gas channels, and having an anode layer, where a first gas diffusion electrode layer is periodically fixed to the anode layer, wherein the periodically fixed first gas diffusion electrode layer defines hydrogen flow field channels. A first catalyst material is coated or infused to the first gas diffusion electrode layer. An electrolyte membrane covers portions of the anode layer and first gas diffusion electrode layer with the first catalyst material. A second catalyst material is coated or infused to the electrolyte membrane. A second gas diffusion electrode layer is in operative association with the electrolyte membrane and second catalyst material, on a surface of the electrolyte membrane different from a surface of the electrolyte membrane which is in contact with the first gas diffusion electrode layer, and a perforated cathode is in contact with the second gas diffusion electrode layer.

Claims (21)

1. A printed fuel cell, having integrated flow channels comprising:

an anode layer wherein the anode layer is a solid conductive material without through holes;

a first gas diffusion electrode layer periodically fixed to the anode layer, wherein the first gas diffusion electrode layer defines integrated flow channels;

a first catalyst material coated or infused to the first gas diffusion electrode layer;

an electrolyte membrane covering portions of the anode layer and the first gas diffusion electrode layer with the first catalyst material, the electrolyte membrane configured to not have mechanical integrity when formed as a discrete sheet;

a second catalyst material coated or infused to the electrolyte membrane;

a second gas diffusion electrode layer in operative association with the electrolyte membrane and the second catalyst material, on a surface of the electrolyte membrane different from a surface of the electrolyte membrane which is in contact with the first gas diffusion electrode layer; and

a cathode in contact with the second gas diffusion electrode layer,

wherein the integrated flow channels are located between the anode and the cathode, and wherein structural support for the fuel cell is provided substantially entirely by the anode and wherein the printed fuel cell is a monolithic device.

2. The printed fuel cell of claim 1 , wherein a first surface of the electrolyte membrane is non-planar and an entirety of second surface of the electrolyte membrane is planarized.

3. The printed fuel cell of claim 1 , wherein the electrolyte membrane is in contact with the anode through the first gas diffusion electrode layer and the first catalyst material.

4. The printed fuel cell of claim 1 , wherein the fuel cell is a hydrogen fuel cell.

5. The printed fuel cell of claim 1 , wherein at least one of the first and second gas diffusion electrode layers comprises porous conductive material impregnated with hydrophobic material.

6. The printed fuel cell of claim 1 , wherein the electrolyte membrane is a non-crosslinked or heterogeneous ion exchange resin.

7. The printed fuel cell of claim 1 , wherein the cathode is a perforated cathode with through holes arrayed throughout the cathode.

8. The printed fuel cell of claim 1 , wherein the integrated fuel channels each include a layer of approximately 5-10 μm thick carbon black or polytetrafluorethylene surrounding an inside of each of the channels.

9. The printed fuel cell of claim 1 , wherein the monolithic device includes at least one of micro-structures, thin film structures and thick film structures, optimized for high performance.

10. The printed fuel cell of claim 1 , wherein the monolithic device includes at least one of printed structures and spray coated structures.

11. The printed fuel cell of claim 1 , wherein the integrated fuel channels each include a layer of approximately 5-10 μm thick carbon black or polytetrafluorethylene surrounding an inside of each of the channels.

12. The printed fuel cell of claim 1 , wherein the monolithic device includes at least one of micro-structures, thin film structures, and thick film structures optimized for high performance.

13. The printed fuel cell of claim 1 , wherein a structure of the first gas diffusion electrode layer defines the integrated flow channels which are located between a surface of the anode and the first gas diffusion electrode layer, and wherein the structure of the first gas diffusion electrode layer corresponds to a provided sacrificial material.

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →