Method for dispersing and aggregating components of mineral slurries and low molecular weight multivalent polymers for mineral aggregation
The disclosure relates generally to the use of low molecular weight polymers to aggregate mineral components in aqueous mineral slurries to release and separate individual components of the slurry, which may then be recovered from the slurry.
1. A method of treating an aqueous mineral slurry to disperse and separate the components of the slurry, to enhance recovery of components of the slurry, and to enhance dewatering of the solids in the resulting residual slurry for water recovery and solids reclamation, said method comprising:
(a) providing an aqueous slurry comprising slurrying water and solid mineral components;
(b) optionally adding to the slurry of (a) a sodium or potassium zeolite having a weight ratio of aluminum to silicon in the range of about 0.72:1 to about 1.3:1 in an amount sufficient to disperse and separate the components of the slurry to form a dispersed slurry;
(c1) adding to the dispersed slurry of (a) sufficient quantities of a water solution of a polymer reactive with said solid mineral components, said polymer being selected from the group consisting of water-soluble multivalent cation-containing acrylate copolymers, said polymers having an intrinsic viscosity of less than 5 dl/gm (measured in 1 M NaCl at 25 degrees C.), to cause the polymer to react with the solid mineral components to cause the solid mineral components to immediately begin to floc and settle to form a product comprising a floc and supernatant water, thereby enhancing separation and subsequent recovery of solid mineral components of the slurry and enhancing subsequent water removal and consolidation of residual components of the product; or
(c2) adding to the dispersed slurry of (b) sufficient quantities of a water solution of a polymer reactive with said mineral components, said polymer being selected from the group consisting of water-soluble multivalent cation-containing acrylate copolymers, said polymers having an intrinsic viscosity of less than 5 dl/gm (measured in 1 M NaCl at 25 degrees C.), to cause the polymer to react with the zeolite and solid mineral components to immediately neutralize the dispersive effect of the zeolite in (b) to cause the solid mineral components to immediately begin to aggregate and settle to form an aggregate and supernatant water, thereby enhancing separation and subsequent recovery of solid mineral components of the slurry and enhancing subsequent water removal and consolidation of residual components of the product.
2. The method of claim 1 wherein the intrinsic viscosity of the polymer is at least 3 dl/gm (measured in 1 M NaCl at 25 degrees C.).
3. The method of claim 1 wherein the polymer solution is substantially free of monovalent cation-containing acrylate polymers.
4. The method of claim 1 wherein the multivalent cations are selected from the group consisting of calcium, magnesium, iron, and aluminum.
5. The method of claim 1 wherein only a single species of multivalent cation is present in the polymer solution.
6. The method of claim 1 wherein the polymer is a calcium- or magnesium-containing diacrylate copolymer with acrylamide.
7. The method of claim 6 wherein the polymer is a diacrylate/acrylamide/2-acrylamido-2-methylpropane sulfonic acid (AMPS) terpolymer.
8. The method of claim 1 wherein the slurry of mineral components comprises fine components less than 44 microns in size alone or in combination with coarser components.
9. The method of any of claim 1 wherein said polymer is a calcium diacrylate/acrylamide copolymer, or a calcium diacrylate/acrylamide/2-acrylamido-2-methylpropane sulfonic acid (AMPS) terpolymer.
10. The method of claim 9 wherein said polymer has a calcium diacrylate content of at least 5 mole %.
11. The method of claim 1 comprising applying mechanical shear to a solution of the polymer sufficient to reduce the molecular weight of the polymer or the breadth of the molecular weight distribution of the polymer.
12. The method of claim 1 wherein said slurry of (a) contains clay.
13. The method of claim 12 wherein the clay is a swellable, sodium clay.
14. The method of claim 13 wherein the clay is a bentonite/montmorillonite clay.
15. The method of claim 14 wherein the clay is expressed as Na.Al 2 SO 3 .4SiO 2 .H 2 O.
16. The method of claim 1 wherein the polymer is a calcium- or magnesium-containing diacrylate copolymer.
17. The method of claim 1 wherein the polymer is a diacrylate/acrylamide copolymer.
18. The method of claim 1 wherein the polymer is a diacrylate/acrylamide/2-acrylamido-2-methylpropane sulfonic acid (AMPS) terpolymer.
19. The method of claim 1 wherein said slurry of (a) contains organic materials.
20. The method of claim 1 wherein said solid components comprise a mineral ore.
21. The method of claim 1 wherein said slurry contains bitumen.
22. The method of claim 1 wherein said slurry contains sand, clay, bitumen, and water.
23. The method of claim 22 wherein the clay is a swellable, sodium clay.
24. The method of claim 23 wherein the clay is a bentonite/montmorillonite clay.
25. The method of claim 24 wherein the clay is expressed as Na.Al 2 SO 3 .4SiO 2 .H2O.
26. The method of claim 1 wherein the polymer is branched.
27. The method of claim 26 wherein the branched polymer is prepared by reacting monomers comprising a source of multivalent cations, a source of acrylate, a monomer selected from the group consisting of acrylamide and 2-acrylamido-2-methylpropane sulfonic acid (AMPS), and a cross-linking agent.
28. The method of claim 27 wherein the cross-linking agent is present in an amount in the range of 0.1 ppm to 5 ppm based on the total weight of said monomers.
29. The method of claim 1 , comprising centrifuging said slurry to separate the components of the slurry into supernatant water and solid particles.