Solid herbicide compositions with built-in adjuvant
View Patent ↗The present disclosure concerns improved solid herbicidal compositions, such as granules and powders, containing built-in adjuvant, which have improved stability and exhibit acceptable herbicidal efficacy when used to control weeds in flooded rice paddies or fields, or cereal crop fields.
1. A solid herbicidal composition comprising:
a) at least one herbicide selected from the class of ACCase and ALS enzyme inhibitors and compounds of the Formula
wherein
Ar represents a phenyl group substituted with one to four substituents independently selected from halogen, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 2 -C 4 alkoxyalkyl, C 2 -C 6 alkylcarbonyl, C 1 -C 6 alkylthio, C 1 -C 6 haloalkyl, C 1 -C 6 haloalkoxy, C 2 -C 4 haloalkoxyalkyl, C 2 -C 6 haloalkylcarbonyl, C 1 -C 6 haloalkylthio, —OCH 2 CH 2 —, —OCH 2 CH 2 CH 2 —, —OCH 2 O—, or —OCH 2 CH 2 O—;
R represents H or F;
X represents Cl or vinyl; and Y represents Cl, vinyl or methoxy;
and their salts and esters;
wherein the herbicide(s) is present in the composition in an amount of from about 1 gram per kilogram (g/kg) to about 200 g/kg relative to the total weight of the composition;
b) one or more built-in adjuvant, wherein the built-in adjuvant(s) is present in the composition in an amount of from about 50 g/kg to about 750 g/kg relative to the total weight of the composition, wherein the built-in adjuvant is a non-ionic surfactant or water-immiscible liquid; and
c) one or more solid, water soluble polymer or oligomer, wherein the solid, water soluble polymer(s) or oligomer(s) is present in the composition in an amount of from about 200 g/kg to about 700 g/kg relative to the total weight of the composition;
wherein the composition does not comprise solid carbohydrate,
wherein when the one or more solid, water soluble polymers or oligomers comprises polyvinyl alcohol, the polyvinyl alcohol is present in the composition in an amount less than 7% by weight relative to the total weight of composition;
wherein the composition exhibits less caking and adjuvant leaking when stored at 40° C. at 45% relative humidity over eight days, than an otherwise same composition further comprising sucrose in an amount from 10 g/kg to 700 g/kg relative to the total weight of the composition; or
wherein the composition is exhibits greater stability at higher temperatures, as measured by DSC, than an otherwise same composition further comprising sucrose in an amount from 10 g/kg to 700 g/kg relative to the total weight of the composition.
2. The composition of claim 1 , wherein the solid herbicidal composition is a powder.
3. The composition of claim 1 , wherein the solid herbicidal composition is a granule.
4. The composition of claim 1 , further comprising one or more additional inert ingredients.
5. The composition of claim 1 , further comprising one or more additional agriculturally active ingredients.
6. The composition of claim 1 , in which the herbicide is at least one of cyhalofop-butyl; penoxsulam; bensulfuron-methyl; azimsulfuron; imazosulfuron; fenoxaprop-P-ethyl; the compound of Formula
or a C 1 -C 6 alkyl ester or salt thereof; or the compound of Formula
or a C 1 -C 12 alkyl or C 7 -C 12 arylalkyl ester or salt thereof.
7. The composition of claim 1 , in which the herbicide is at least one of cyhalofop-butyl; penoxsulam; bensulfuron-methyl; the compound of Formula
or a C 1 -C 6 alkyl ester or salt thereof; or the compound of Formula
or a C 1 -C 12 alkyl or C 7 -C 12 arylalkyl ester or salt thereof.
8. The composition of claim 1 , in which the built-in adjuvant comprises one or more of water-immiscible organic liquid.
9. The composition of claim 1 , in which the built-in adjuvant comprises one or more of a petroleum derived paraffinic hydrocarbon, a petroleum derived aromatic hydrocarbon, a plant derived oil, or a C 1 -C 6 ester of a plant derived oil.
10. The composition of claim 1 , in which the build-in adjuvant comprises one or more of a seed oil, or a C 1 -C 6 ester of plant derived oil.
11. The composition of claim 1 , in which the build-in adjuvant comprises methyl soyate.
12. The composition of claim 1 , wherein the build-in adjuvant is in an amount of from about 200 g/kg to about 600 g/kg relative to the total weight of the composition.
13. The composition of claim 1 , wherein the build-in adjuvant is in an amount of from about 300 g/kg to about 600 g/kg relative to the total weight of the composition.
14. The composition of claim 1 , in which the solid, water soluble polymer or oligomer is selected from the group consisting of one or more lignosulfonates, polyvinyl alcohols with a degree of hydrolysis from about 87 to about 99 percent, alkyl naphthalene sulfonate formaldehyde condensates, and mixtures thereof.
15. The composition of claim 1 , in which the solid, water soluble polymer or oligomer comprises one or more of polyvinyl alcohols or lignosulfonates.
16. The composition of claim 1 , in which the solid, water soluble polymer or oligomer comprises one or more of polyvinyl alcohols derived from the hydrolysis of polyvinyl acetate, that vary in the degree of hydrolysis from about 87 to about 99%.
17. The composition of claim 1 , wherein the solid, water soluble polymer or oligomer is in an amount of from about 300 g/kg to about 600 g/kg relative to the total weight of the composition.
18. The composition of claim 1 , which comprises no polyvinyl alcohol, or which comprises polyvinyl alcohol wherein the polyvinyl alcohol has a degree of hydrolysis from about 87 to about 99 percent.
19. The composition of claim 1 , which comprises mineral powder in an amount of less than about 60% w/w relative to the total weight of the composition.
20. A method of controlling undesirable vegetation in an aquatic environment, which comprises broadcasting, spraying or adding an herbicidally effective amount of the composition of claim 1 , to the aquatic environment either before emergence or after emergence of the undesirable vegetation.
21. A method of controlling undesirable vegetation in a flooded rice paddy, which comprises broadcasting, spraying or adding an herbicidally effective amount of the composition of claim 1 , to the flooded rice paddy either before emergence or after emergence of the undesirable vegetation.
22. A method of preparing the solid herbicidal composition of claim 1 , in the form of a granule or a powder which comprises:
a) mixing the solid, water soluble polymers or oligomers in water to form an aqueous phase;
b) mixing the built-in adjuvant and the at least one herbicide according to claim 1 to form an oil phase;
c) adding the oil phase prepared in step b) to the aqueous phase prepared in step a) under high shear homogenization to provide a mixture;
d) drying the mixture prepared in c) to provide an herbicidal powder or an herbicidal granule; and
e) optionally, agglomerating the herbicidal powder prepared in d) by a low shear granulation process to prepare an herbicidal granule, wherein
the built-in adjuvant is a non-ionic surfactant or water-immiscible liquid; and
when the one or more solid, water soluble polymers or oligomers comprises polyvinyl alcohol, the polyvinyl alcohol is present in the composition in an amount less than 7% by weight relative to the total weight of composition.
23. The composition according to claim 1 , wherein the polyvinyl alcohol, if present, is present in an amount of less than 5% by weight relative to the total weight of the composition.
24. The composition according to claim 1 , wherein the polyvinyl alcohol, if present, is present in an amount of less than 3% by weight relative to the total weight of the composition.
25. The composition according to claim 1 , wherein the polyvinyl alcohol, if present, is present in an amount of less than 1% by weight relative to the total weight of the composition.
26. The composition of claim 1 , which comprises no mineral powder.
27. The composition of claim 1 , comprising a water immiscible liquid built-in adjuvant in an amount greater than 150 g/kg relative to the total weight of the composition.