IP Library Granted Patent US 9,337,512
Granted Patent B2
US 9,337,512 · App. 13/749,769 · Granted May 10, 2016

Non-aqueous electrolyte for lithium secondary battery and lithium secondary battery comprising the same

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Quick Facts
Patent No.
US 9,337,512
App. No.
13/749,769
Granted
May 10, 2016
Kind
B2
Abstract

Disclosed is a non-aqueous electrolyte for a lithium secondary battery and a lithium secondary battery comprising the same. The non-aqueous electrolyte including a lithium salt and an organic solvent may further include, as an additive, (a) halogenated alkyl silane and (b) any one of (b-1) succinic anhydride, (b-2) (meth)acrylic acid ester of pentaerythritol or dipentaerythritol, and (b-3) mixtures thereof. The non-aqueous electrolyte for a lithium secondary battery may improve the high-temperature storage performance and the cycling performance.

Claims (16)

1. A non-aqueous electrolyte for a lithium secondary battery comprising a lithium salt and an organic solvent, the non-aqueous electrolyte comprising:

as an additive,

(a) fluorotrimethylsilane; and

(b) dipentaerythritol hexaacrylate,

wherein a mix ratio by weight of (a):(b) is 1:10 to 1:20.

2. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 ,

wherein the content of the additive is 0.1 to 1 part by weight per 100 parts by weight of the non-aqueous electrolyte.

3. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 ,

wherein an anion of the lithium salt is selected from the group consisting of F − , Cl − , Br − , I − , NO 3 − , N(CN) 2 − , BF 4 − , ClO 4 − , AlO 4 − , AlCl 4 − , PF 6 − , SbF 6 − , AsF 6 − , BF 2 C 2 O 4 − , BC 4 O 8 − , (CF 3 ) 2 PF 4 − , (CF 3 ) 3 PF 3 − , (CF 3 ) 4 PF 2 − , (CF 3 ) 5 PF − , (CF 3 ) 6 P − , CF 3 SO 3 − , C 4 F 9 SO 3 − , CF 3 CF 2 SO 3 − , (CF 3 SO 2 ) 2 N − , (FSO 2 ) 2 N − , CF 3 CF 2 (CF 3 ) 2 CO − , (CF 3 SO 2 ) 2 CH − , (SF 5 ) 3 C − , (CF 3 SO 2 ) 3 C − , CF 3 (CF 2 ) 7 SO 3 − , CF 3 CO 2 − , CH 3 CO 2 − , SCN − , and (CF 3 CF 2 SO 2 ) 2 N − .

4. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 ,

wherein the organic solvent is any one selected from the group consisting of propylene carbonate, ethylene carbonate, diethyl carbonate, dimethyl carbonate, ethylmethyl carbonate, dipropyl carbonate, dimethylsulfoxide, acetonitrile, dimethoxyethane, diethoxyethane, vinylene carbonate, sulfolane, γ-buryrolactone, ethylene sulfite, propylene sulfite, and tetrahydrofuran, or mixtures thereof.

5. A lithium secondary battery comprising:

a cathode of lithium-containing oxide;

an anode of a carbon-based material capable of intercalating and deintercalating lithium ions; and

a non-aqueous electrolyte,

wherein the non-aqueous electrolyte is defined in claim 1 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2021
From: LG CHEM, LTD.
To: LG ENERGY SOLUTION, LTD.
Reel/Frame 058295/0068 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2013
From: AN, YU-HA; YU, SUNG-HOON; SHIN, BO-RA
To: LG CHEM, LTD.
Reel/Frame 031091/0225 →