Methods for producing aluminum trifluoride
View Patent ↗Methods for producing aluminum trifluoride by acid digestion of fluoride salts of alkali metal or alkaline earth metal and aluminum, optionally, in the presence of a source of silicon; methods for producing silane that include acid digestion of by-products of silane production to produce aluminum trifluoride.
1. A method for producing aluminum trifluoride, the method comprising:
contacting a fluoroaluminate feed comprising at least about 30% by weight fluoride salts of alkali metal or alkaline earth-metal and aluminum with substantially anhydrous acid, the fluoride salt being introduced to a fluidized bed reactor which contains acid as a fluidizing gas to produce aluminum trifluoride and at least one by-product;
wherein the fluoroaluminate feed comprises silicon in an amount less than the stoichiometric molar ratio at which silicon tetrafluoride is produced by reacting silicon with the acid and fluoride salts of alkali metal or alkaline earth-metal and aluminum.
2. The method as set forth in claim 1 wherein particulate aluminum trifluoride and a chloride or sulfate salt of alkali or alkaline earth-metal are produced in the fluidized bed reactor.
3. The method as set forth in claim 2 comprising introducing the particulate aluminum trifluoride and the chloride or sulfate salt into a wash unit to separate the aluminum trifluoride from the chloride or sulfate salt.
4. The method as set forth in claim 2 wherein a spent gas is produced, the spent gas comprising hydrogen, hydrogen fluoride and unreacted acid.
5. The method as set forth in claim 4 comprising separating at least one of hydrogen, hydrogen fluoride and unreacted acid in a distillation column.
6. The method as set forth in claim 1 wherein the fluoroaluminate feed comprises at least about 70% by weight fluoride salts of alkali metal or alkaline earth-metal and aluminum.
7. The method as set forth in claim 1 wherein the fluoroaluminate feed comprises at least about 80% by weight fluoride salts of alkali metal or alkaline earth-metal and aluminum.
8. The method as set forth in claim 1 wherein the fluoroaluminate feed comprises at least about 90% by weight fluoride salts of alkali metal or alkaline earth-metal and aluminum.
9. The method as set forth in claim 1 wherein the fluoroaluminate feed comprises from about 30% to about 95% by weight fluoride salts of alkali metal or alkaline earth-metal and aluminum.
10. The method as set forth in claim 1 wherein the fluoroaluminate feed comprises from about 70% to about 95% by weight fluoride salts of alkali metal or alkaline earth-metal and aluminum.
11. The method as set forth in claim 1 wherein the acid is hydrochloric acid.
12. The method as set forth in claim 1 wherein the acid is sulfuric acid.
13. The method as set forth in claim 1 wherein the feed is contacted with acid in the absence of a source of silicon.
14. The method as set forth in claim 1 wherein the fluoride salt of alkali metal or alkaline earth-metal and aluminum is selected from the group consisting of NaAlF 4 , Na 5 Al 3 F 14 , Na 3 AlF 6 and mixtures thereof.
15. The method as set forth in claim 1 wherein hydrogen fluoride is produced as a by-product.
16. The method as set forth in claim 15 wherein, in addition to aluminum trifluoride, silicon tetrafluoride is produced, the method further comprising contacting the hydrogen fluoride with a source of silicon to produce silicon tetrafluoride.
17. The method as set forth in claim 1 wherein the fluoride salt is a by-product of silane production.