Refrigeration oil and compositions with hydrocarbon refrigerants
View Patent ↗Polyol ester lubricant compositions comprising predominately straight chain C 5-10 alkylcarboxlate esters of neopentyl alcohols, for example, straight chain C 5-10 alkylcarboxlate esters of one or more of trimethylol propane, pentaerythritol, di-pentaerythritol, tri-pentaerythritol or pentaerythritol oligomers, and working fluids comprising said lubricant compositions and a hydrocarbon refrigerant, suitable for heat transfer devices including refrigeration and air conditioning systems are provided. The polyol ester lubricant compositions have a kinematic viscosity at 40° C. of 22-125 cSt and a viscosity index of greater than 140, and are characterized by having very high lubricity, excellent load carrying properties and excellent low temperature properties.
1. A working fluid for a heat transfer device comprising:
i) a C 1-6 hydrocarbon refrigerant and
ii) a polyol ester lubricant composition having a kinematic viscosity at 40° C. of 22-125 cSt, a viscosity index of greater than 140 and comprising a mixture of compounds of formula I
wherein n is an integer of from 1 to 12,
each R is independently an alkyl carbonyl of from 5 to 10 carbon atoms,
each R 1 is independently selected and is either a group R or a substituent of formula II:
wherein at least 80 molar % of all R groups are independently selected from straight chain alkylcarbonyls of from 7 to 10 carbon atoms, and
wherein the polyol ester lubricant composition comprises
a) from about 30 to about 55 wt % of a compound of formula I wherein n is 1 and each R 1 is independently selected and is a group R,
b) from about 1 to about 20 wt % of a compound of formula I wherein n is 2 and each R 1 is independently selected and is a group R,
c) from about 1 to about 10 wt % of a compound of formula I wherein n is 3 and each R 1 is independently selected and is a group R, and
d) from about 25 to about 45 wt % of a compound of formula I which are pentaerythritol oligomers of 4 or more pentaerythritol monomer groups,
wherein the wt % is based on the weight of all compounds of formula I present in the lubricant composition.
2. The working fluid according to claim 1 wherein at least 90 molar % of all R groups are independently selected from straight chain alkylcarbonyls of 7, 8 and 10 carbon atoms.
3. The working fluid according to claim 1 wherein the C 1-6 hydrocarbon refrigerant is the only refrigerant present and is one or more refrigerants selected from the group consisting of ethane, propane, propene, butane, isobutane, butene, iso butene, pentane and iso-pentane.
4. The working fluid according to claim 3 wherein the refrigerant is one or more refrigerants selected from the group consisting of propane, butane, isobutane, butene and iso butene.
5. The working fluid according to claim 1 further comprising in addition to components i) and ii), one or more compounds selected from the group consisting of mineral oils, poly-α-olefins, alkylbenzenes, carboxylic acid esters other than a compound of formula I, polyethers, polyvinyl ethers, perfluoropolyethers, and phosphoric acid esters.
6. The working fluid according to claim 1 further comprising one or more antioxidant, extreme-pressure additive, antiwear additive, friction reducing additive, defoaming agent, profoaming agent, metal deactivator, acid scavenger or mixture thereof.
7. The working fluid according to claim 1 , wherein the polyol ester lubricant composition comprises a mixture of compounds of formula I and C 5-10 alkylcarboxlate esters of trimethylol propane wherein at least 80 molar % of all alkyl carbonyls in the esters of trimethyl polyol are independently selected from straight chain alkylcarbonyls of from 7 to 10 carbon atoms.
8. The working fluid according to claim 7 wherein at least 50% by weight of all esters in the polyol ester lubricant composition are compounds of formula I.
9. The working fluid according to claim 7 wherein at least 75% by weight of all esters in the polyol ester lubricant composition are compounds of formula I.
10. The working fluid according to claim 1 wherein at least 90% by weight of all esters in the polyol ester lubricant composition are compounds of formula I.