Non-aqueous electrolyte for lithium secondary battery and lithium secondary battery comprising the same
Disclosed is a non-aqueous electrolyte for a lithium secondary battery and a lithium secondary battery comprising the same. The non-aqueous electrolyte including an ionizable lithium salt and an organic solvent may further include (a) 1 to 10 parts by weight of a compound having a vinylene group or vinyl group per 100 parts by weight of the non-aqueous electrolyte, and (b) 10 to 300 parts by weight of a dinitrile compound having an ether bond per 100 parts by weight of the compound having the vinylene group or vinyl group. The lithium secondary battery comprising the non-aqueous electrolyte may effectively suppress the swelling and improve the charge/discharge cycle life.
1. A non-aqueous electrolyte for a lithium secondary battery consisting of: an ionizable lithium salt; an organic solvent
1 to 3 parts by weight of vinylene carbonate per 100 parts by weighty of the non-aqueous electrolyte;
1 to 3 parts by weight of ethyleneglycol bis(2-cyanoethyl)ether per 1 part by weight of the vinylene carbonate; and
2 to 3 parts by weight of fluoroethylene carbonate per 100 parts by weight of the non-aqueous electrolyte.
2. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 , wherein an anion of the ionizable lithium salt is any one selected from the group consisting of F − , Cl − , Br − , I − , NO 3 − , N(CN) 2 − , BF 4 − , ClO 4 − , PF 6 − , (CF 3 ) 2 PF 4 − , (CF 3 ) 3 PF 3 − , (CF 3 ) 4 PF 2 − , (CF 3 ) 5 PF − , (CF 3 ) 6 P − , CF 3 SO 3 − , CF 3 CF 2 SO 3 − , (CF 3 SO 2 ) 2 N − , (FSO 2 ) 2 N − , CF 3 CF 2 (CF 3 ) 2 CO − , (CF 3 SO 2 ) 2 CH − , (SF 5 ) 3 C − , (CF 3 SO 2 ) 3 C − , CF 3 (CF 2 ) 7 SO 3 − , CF 3 CO 2 − , CH 3 CO 2 − , SCN − , and (CF 3 CF 2 SO 2 ) 2 N − .
3. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 , wherein the organic solvent comprise ethylene carbonate and propylene carbonate.
4. The non-aqueous electrolyte for a lithium secondary battery according to claim 3 , wherein the organic solvent further comprise diethyl carbonate, methyl propionate, ethyl propionate, or mixtures of at least two thereof.
5. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 , wherein the organic solvent comprise ethylene carbonate, propylene carbonate, and diethyl carbonate.
6. The non-aqueous electrolyte for a lithium secondary battery according to claim 1 , wherein the organic solvent comprise ethylene carbonate, propylene carbonate, and ethyl propionate.
7. The non-aqueous electrolyte for a lithium secondary battery according to claim 5 , wherein the ethylene carbonate, the propylene carbonate, and the diethyl carbonate are in a ratio of 3:2:5.
8. A lithium secondary battery comprising: an electrode assembly including a cathode, an anode, and a separator interposed there between; a battery casing receiving the electrode assembly; and the non-aqueous electrolyte of claim 1 injected in the battery casing.
9. The lithium secondary battery according to claim 8 , wherein the anode further includes an aqueous binder.