Liquid crystal display device
View Patent ↗The present invention provides a liquid crystal display device including a first substrate and a second substrate that are arranged to face each other while sandwiching liquid crystal, wherein: a first electrode and plural second electrodes are formed at a pixel area on the first substrate on the liquid crystal side; an alignment layer is provided which includes a first alignment layer formed on the first substrate on the liquid crystal side to cover the second electrodes and a second alignment layer formed on the first alignment layer on the liquid crystal side; the resistance of the second alignment layer is lower than that of the first alignment layer; and the transmittance of the second alignment layer is lower than that of the first alignment layer.
1. A liquid crystal display device comprising a first substrate and a second substrate that are arranged to face each other while sandwiching liquid crystal,
wherein a first electrode and a plurality of second electrodes overlapped with the first electrode through an insulating film are formed at a pixel area on the liquid crystal side of the first substrate, one of the first electrode and the second electrodes is used as a pixel electrode, and the other is used as an opposite electrode;
an alignment layer which is a two-layer structure is provided which includes a first alignment layer comprising a first polyimide and/or polyamic acid formed on the liquid crystal side of the first substrate to cover the second electrodes and the whole display area, and a second alignment layer comprising a second polyimide and/or polyamic acid formed on the liquid crystal side of the first alignment layer to cover the first alignment layer and the whole display area;
the resistance of the second alignment layer is lower than that of the first alignment layer, and the transmittance of the second alignment layer is lower than that of the first alignment layer for the wavelength span of 400 nm to 500 nm of light; and
at least the second alignment layer is configured using a polyimide and/or polyamic acid compound obtained by polymerizing PMDA (pyromellitic acid dianhydride) serving as a first compound with a hydrocarbon organic material,
wherein the mass molar concentration of polymerized PMDA is higher in the second alignment layer than in the first alignment layer.
2. The liquid crystal display device according to claim 1 , wherein the mass molar concentration of polymerized PMDA is 14% or higher in the second alignment layer.
3. The liquid crystal display device according to claim 1 , wherein the hydrocarbon organic material forming the second alignment layer is a diamine compound represented by the following general expression (10)
H 2 N—R—NH 2 (10)
wherein R is selected from benzene and linear alkyl bond (Ph-(CH 2 ) n -Ph), benzene hetero bond (Ph-O-Ph), or benzene alkyl hetero bond (Ph-O—(CH 2 ) n —O-Ph).
4. The liquid crystal display device according to claim 3 , wherein the second alignment layer is a compound having a structure represented by the following general expression (13) composed of compounds shown by copolymerization of the following general expressions (11) and (12)
wherein x and y are 1 or more in general expression (13).
5. The liquid crystal display device according to claim 4 ,
wherein the first alignment layer is configured using a compound having a structure represented by the general expression (13) as similar to the second alignment layer, and
the mass molar concentration of PMDA (pyromellitic acid dianhydride) forming the first alignment layer is 14% or lower.