IP Library Granted Patent US 9,011,788
Granted Patent B2
US 9,011,788 · App. 13/767,604 · Granted Apr 21, 2015

Advanced fischer tropsch system

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Quick Facts
Patent No.
US 9,011,788
App. No.
13/767,604
Granted
Apr 21, 2015
Kind
B2
Abstract

A Fischer Tropsch (“FT”) unit that includes an FT tube that is packed with a catalyst. The catalyst is designed to catalyze an FT reaction to produce a hydrocarbon. An insert that is positioned within the FT tube. The insert comprises at least one cross-piece that contacts an inner surface of the FT tube and at least one cross-fin extending from the cross-piece. There may be a corresponding second cross-fin adjacent each cross-fin. Both the cross-fins and the second cross-fins may be disposed radially outwardly such that the edge of the cross-fins are closer to the inner surface of the FT tube than is the base of the cross-fins.

Claims (29)

1. A Fischer Tropsch (“FT”) unit comprising:

an FT tube;

an insert that is positioned within the FT tube, the insert comprising:

at least one cross-piece that contacts an inner surface of the FT tube; and

wherein each cross-piece comprises a plurality of cross-fins along the cross-piece and extending from the cross-piece, wherein each cross-fin positioned closer to the FT tube is longer than each cross-fin positioned closer to a center of the insert.

2. The FT unit as in claim 1 , wherein the insert comprises three cross-pieces, wherein each cross-piece contacts the inner wall of the FT tube, wherein the three cross-pieces generally form a “snowflake” configuration.

3. The FT unit as in claim 2 , wherein the end of each cross-piece comprises a pad, wherein each pad contacts the inner surface of the FT tube.

4. The FT unit as in claim 3 , wherein there is a corresponding second cross-fin that is positioned adjacent each cross-fin.

5. The FT unit as in claim 4 , wherein each cross-fin and each corresponding second cross-fin are disposed towards the inner surface of the FT tube.

6. The FT unit as in claim 5 , wherein each cross-piece comprises two cross-fins and two corresponding second cross-fins.

7. The FT unit as in claim 1 , further comprising a thermocouple in communication with the insert.

8. The FT unit as in claim 6 , wherein a thermocouple opening is positioned at the center of the insert.

9. The FT unit as in claim 1 , wherein the insert is made of a heat conductive metal.

10. The FT unit as in claim 9 , wherein the insert is made of aluminum.

11. The FT unit as in claim 1 , wherein the FT tube has an inner diameter of greater than or equal to about ⅝ of an inch.

12. The FT unit as in claim 1 , wherein the FT tube has an inner diameter of less than or equal to about 10 inches.

13. The FT unit as in claim 1 , wherein the FT tube has an inner diameter of between about 1 inch and about 10 inches.

14. The FT unit as in claim 1 , further comprising a heat removal media in communication with an outer surface of the FT tube.

15. The FT unit as in claim 14 , wherein the heat removal media comprises a cooling fluid.

16. The FT unit as in claim 15 , wherein the cooling fluid comprises one of water or oil.

17. The FT unit as in claim 14 , wherein the heat removal media comprises a cooling block.

18. The FT unit as in claim 17 , wherein the cooling block comprises cooling channels for receiving a cooling fluid.

19. The FT unit as in claim 1 , further comprising means for controlling the temperature of the FT unit.

20. The FT unit as in claim 1 , wherein the FT unit is configured to operate at a temperature T(r) between about 210° C. and about 235° C. where

T(r)=T w +[q′″r w 2 /4k][1−(r/r w ) 2 ], and where T w is the temperature at a wall of the FT tube, q′″ is the heat generation rate for a given catalyst activity, r w is the FT tube radius, k is the effective bed conductivity, and r is the radius within the tube at which the temperature of the FT unit is measured.

21. The FT unit as in claim 1 , wherein the temperature difference between a operational temperature at a wall of the FT tube and the approximate center of the FT tube is less than about 25° C.

22. An insert that is designed to be positioned within an Fischer Tropsch (“FT”) reactor tube, the insert comprising:

three cross-pieces arranged to have dihedral symmetry;

a plurality of cross-fins along each cross-piece and extending from the cross-piece, wherein each cross-fin positioned closer to the FT tube is longer than each cross-fin positioned closer to a center to the insert, wherein each cross-fin extends radially outwardly from the cross-piece such that the edge of the cross-fin is closer to the inner surface of the FT reactor tube than the base of the cross-fin.

Assignments (5)
TERMINATION AND RELEASE OF CONFIRMATORY GRANT OF SECURITY INTEREST IN PATENTS Recorded Oct 29, 2025
From: JPMORGAN CHASE BANK, N.A.
To: COORSTEK, INC.
Reel/Frame 073424/0583 →
SECURITY INTEREST Recorded Oct 28, 2025
From: COORSTEK, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 072705/0315 →
SECURITY INTEREST Recorded May 29, 2025
From: COORSTEK, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 071248/0824 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 27, 2023
From: CERAMATEC, INC
To: COORSTEK, INC.
Reel/Frame 062876/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2013
From: HARTVIGSEN, JOSEPH; ELANGOVAN, S.; FROST, LYMAN
To: CERAMATEC, INC.
Reel/Frame 030831/0320 →