LED light bulb

1. An LED light bulb, comprising:

an LED module including a substrate and an ultraviolet to violet light-emitting LED chip mounted on the substrate;

a base part on which the LED module is disposed;

a globe attached to the base part to cover the LED module;

a phosphor screen, provided on an inner surface of the globe separately from the LED chip, emitting white light by absorbing ultraviolet to violet light emitted from the LED chip;

a lighting circuit, provided in the base part, lighting the LED chip; and

a bayonet cap electrically connected to the lighting circuit,

wherein the phosphor screen includes a mixed phosphor containing a blue phosphor, a green to yellow phosphor, and a red phosphor,

wherein the blue phosphor comprises an europium activated alkaline earth chlorophosphate phosphor having a composition represented by a general formula:

(Sr 1-x-y-z Ba x Ca y Eu z ) 5 (PO 4 ) 3 .Cl  (1)

where, x, y, and z are numbers satisfying 0≦x<0.5, 0≦y<0.1, 0.0005≦z<0.1,

wherein the green to yellow phosphor comprises at least one selected from: an europium and manganese activated alkaline earth aluminate phosphor having a composition represented by a general formula:

(Ba 1-x-y-z Sr x Ca y Eu z )(Mg 1-u Mn u )Al 10 O 17   (2)

where, x, y, z, and u are numbers satisfying 0≦x<0.2, 0≦y<0.1, 0.005<z<0.5, 0.1<u<0.5;

an europium and manganese activated alkaline earth silicate phosphor having a composition represented by a general formula:

(Sr 1-x-y-z-u Ba x Mg y Eu z Mn u ) 2 SiO 4   (3)

where, x, y, z, and u are numbers satisfying 0.1≦x≦0.35, 0.025≦y≦0.105, 0.025≦z≦0.25, 0.0005≦u≦0.02;

a cerium activated rare-earth aluminate phosphor having a composition represented by a general formula:

RE 3 A x Al 5-x-y B y O 12 :Ce z   (4)

where, RE is at least one element selected from Y, Lu, and Gd, A and B are a pair of elements where (A, B) is an of (Mg, Si), (B, Sc), (B, In), and x, y, and z are numbers satisfying x<2, y<2, 0.9<x/y≦1.1, 0.05≦z≦0.5;

an europium activated SiAlON phosphor having a composition represented by a general formula:

(Si,Al) 6 (O,N) 8 :Eu x   (5)

where, x is a number satisfying 0<x<0.3; and

an europium activated SiAlON phosphor having a composition represented by a general formula:

(Sr 1-x Eu x ) α Si β Al γ O δ N ω   (6)

where, x, α, β, γ, δ, and ω are numbers satisfying 0<x<1, 0<≦3, 12≦β≦14, 2≦γ≦3.5, 1≦δ≦3, 20≦ω≦22,

wherein the red phosphor comprises at least one selected from: an europium activated lanthanum oxysulfide phosphor having a composition represented by a general formula:

(La 1-x-y Eu x M y ) 2 O 2 S  (7)

where, M is at least one element selected from Sm, Ga, Sb, and Sn, and x and y are numbers satisfying 0.08≦0.16, 0.000001≦y<0.003;

an europium activated yttrium oxide phosphor having a composition represented by a general formula:

(Y 1-x-y Eu x Bi y ) 2 O 3   (8)

where, x and y are numbers satisfying 0.01≦x<0.15, 0.001≦y<0.05;

an europium activated CASN phosphor having a composition represented by a general formula:

(Ca 1-x-y Sr x Eu y )SiAlN 3   (9)

where, x and y are numbers satisfying 0≦x<0.4, 0<y<0.5; and

an europium activated SiAlON phosphor having a composition represented by a general formula:

(Sr 1-x Eu x ) α Si β Al γ O δ N ω   (10)

where, x, α, β, γ, δ, and ω are numbers satisfying 0<x<1, 0<α≦3, 5≦β≦9, 1≦γ≦5, 0.5≦δ≦2, 5≦ω≦15,

wherein a total content of the europium and manganese activated alkaline earth silicate phosphor having the composition represented by the formula (3), the cerium activated rare-earth aluminate phosphor having the composition represented by the formula (4), the europium activated SiAlON phosphor having the composition represented by the formula (5), the europium activated SiAlON phosphor having the composition represented by the formula (6), the europium activated CASN phosphor having the composition represented by the formula (9), and the europium activated SiAlON phosphor having the composition represented by the formula (10) in the mixed phosphor is 20 mass % or less, and

wherein the phosphor screen has a color in which a* is −10 or more and +10 or less, b* is 0 (zero) or more and +30 or less, and L* is +40 or more when a body color of the phosphor screen is represented by an L*a*b* color system.

2. The LED light bulb according to claim 1 ,

wherein the LED module includes a plurality of the LED chips mounted on the substrate and a transparent resin layer provided on the substrate to cover the plurality of LED chips.

3. The LED light bulb according to claim 1 ,

wherein the globe has a dome shape or an eggplant shape.

4. The LED light bulb according to claim 1 ,

wherein the mixed phosphor contains 10 mass % or more and 60 mass % or less of the blue phosphor, 1 mass % or more and 30 mass % or less of the green to yellow phosphor, and 30 mass % or more and 90 mass % or less of the red phosphor, where a total amount of the blue, green to yellow, and red phosphors is 100 mass %.

5. The LED light bulb according to claim 1 ,

wherein the white light emitted from the phosphor screen has a correlated color temperature of 6500 K or less and an average color rendering index Ra of 85 or more.

6. The LED light bulb according to claim 1 ,

wherein the mixed phosphor further contains at least one selected from a blue-green phosphor and a deep red phosphor.

7. The LED light bulb according to claim 6 ,

wherein the blue-green phosphor comprises an europium and manganese activated alkaline earth silicate phosphor having a composition represented by a general formula:

(Ba 1-x-y-z-u Sr x Mg y Eu z Mn u ) 2 SiO 4   (11)

where, x, y, z, and u are numbers satisfying 0.1≦x≦0.35, 0.025≦y≦0.105, 0.025≦z≦0.25, 0.0005≦u≦0.02, and

wherein the deep red phosphor comprises a manganese activated magnesium phlorogermanate phosphor having a composition represented by a general formula:

αMgO.βMgF 2 .(Ge 1-x Mn x )O 2   (12)

where, α, β, and x are numbers satisfying 3≦α≦4, 0.04≦β≦0.6, 0.001≦x≦0.5.

8. The LED light bulb according to claim 6 ,

wherein the mixed phosphor contains 10 mass % or more and 60 mass % or less of the blue phosphor, 10 mass % or less of the blue-green phosphor, 1 mass % or more and 30 mass % or less of the green to yellow phosphor, 30 mass % or more and 90 mass % or less of the red phosphor, and 35 mass % or less of the deep red phosphor, where a total amount of the blue, blue-green, green to yellow, red, and deep red phosphors is 100 mass %.

9. The LED light bulb according to claim 7 ,

wherein a total content of the europium and manganese activated alkaline earth silicate phosphor having the composition represented by the formula (3), the cerium activated rare-earth aluminate phosphor having the composition represented by the formula (4), the europium activated SiAlON phosphor having the composition represented by the formula (5), the europium activated SiAlON phosphor having the composition represented by the formula (6), the europium activated CASN phosphor having the composition represented by the formula (9), the europium activated SiAlON phosphor having the composition represented by the formula (10), and the europium and manganese activated alkaline earth silicate phosphor having the composition represented by the formula (11) in the mixed phosphor is 20 mass % or less.

10. The LED light bulb according to claim 1 ,

wherein the phosphor screen has a film thickness in a range of 80 μm or more and 800 μm or less.

11. The LED light bulb according to claim 1 ,

wherein the globe is made of a material having a body color of transparent or white, and of Which transmittance of visible light is 90% or more.

12. The LED light bulb according to claim 1 ,

wherein the ultraviolet to violet light emitted from the LED chip has a emission peak wavelength in a range of 370 nm or more and 415 nm or less, and a half value width of emission spectrum in a range of 10 nm or more and 15 nm or less.