Electroconductive polymer solution, electroconductive polymer composition, and solid electrolytic capacitor therewith and method for producing same
View Patent ↗The present invention provides an electroconductive polymer solution in which the good dispersibility is maintained and the pH is arbitrarily adjusted, and an electroconductive polymer composition having an excellent heat resistance. Further, the present invention provides a solid electrolytic capacitor having an excellent reliability. The present invention is an electroconductive polymer solution, containing an electroconductive polymer in which a dopant is doped, a first compound having an amino group and a hydroxyl group, a second compound having a carboxylic acid group, and a dispersing medium.
1. An electroconductive polymer solution, comprising:
an electroconductive polymer in which a dopant is doped;
a first compound having an amino group and a hydroxyl group;
a second compound having a carboxylic acid group; and
a dispersing medium,
wherein the first compound is at least one kind selected from 2-amino-2-hydroxymethyl-1,3-propanediol, 2-amino-2-hydroxyethyl-1,3-propanediol, 3-methylamino-1,2-propanediol and 1-(methylamino)propanediol.
2. The electroconductive polymer solution according to claim 1 , wherein the second compound is a water-soluble compound with a low molecular weight.
3. The electroconductive polymer solution according to claim 1 , wherein the second compound is a water-soluble polymer.
4. The electroconductive polymer solution according to claim 1 , wherein the number ratio of the amino group comprised in the first compound and of the carboxylic acid group comprised in the second compound is in a range of 1.0:2.0 to 5.5.
5. The electroconductive polymer solution according to claim 1 , wherein the electroconductive polymer comprises at least one kind selected from the group consisting of polypyrroles, polythiophenes, polyanilines and derivatives thereof.
6. The electroconductive polymer solution according to claim 1 , wherein the electroconductive polymer comprises a repeating unit of 3,4-ethylenedioxythiophene or a derivative thereof.
7. The electroconductive polymer solution according to claim 1 , having a pH of 2.5 to 7.0.
8. An electroconductive polymer composition, comprising the electroconductive polymer and a compound having a carboxylic acid amide bond and a carboxylic acid ester bond which is formed from the first compound and the second compound by removing the dispersing medium from the electroconductive polymer solution according to claim 1 .
9. The electroconductive polymer composition according to claim 8 , obtained by heating the electroconductive polymer solution at 80° C. or higher and 300° C. or lower to remove the dispersing medium.
10. A solid electrolytic capacitor, having a solid electrolyte comprising the electroconductive polymer composition according to claim 8 .
11. A method for producing a solid electrolytic capacitor, comprising:
forming a dielectric layer on a surface of an anode conductor comprising a valve metal; and
carrying out an application or an impregnation of the electroconductive polymer solution according to claim 1 on the dielectric layer to form a solid electrolyte layer comprising an electroconductive polymer composition obtained by removing the dispersing medium from the electroconductive polymer solution.
12. A method for producing a solid electrolytic capacitor, comprising:
forming a dielectric layer on a surface of an anode conductor comprising a valve metal;
carrying out an oxidative polymerization of a monomer providing an electroconductive polymer on the dielectric layer to form a first solid electrolyte layer containing the electroconductive polymer; and
carrying out an application or an impregnation of the electroconductive polymer solution according to claim 1 on the first solid electrolyte layer to form a second solid electrolyte layer comprising an electroconductive polymer composition obtained by removing the dispersing medium from the electroconductive polymer solution.
13. An electroconductive polymer composition, obtained by forming a compound having a carboxylic acid amide bond and a carboxylic acid ester bond from a first compound having an amino group and a hydroxyl group and a second compound having a carboxylic acid group, wherein the compound having a carboxylic acid amide bond and a carboxylic acid ester bond is laid in an electroconductive polymer matrix or between electroconductive polymer dispersing particles,
wherein the first compound is at least one kind selected from 2-amino-2-hydroxymethyl-1,3-propanediol, 2-amino-2-hydroxyethyl-1,3-propanediol, 3-methylamino-1,2-propanediol and 1-(methylamino)propanediol.