Polyester composition
View Patent ↗Compositions comprising: (a) 30 to 65 weight percent of a polyester; (b) 7 to 25 weight percent of an ethylene copolymer toughener; (c) 5 to 25 weight percent of a copolyether ester elastomer having a shore D hardness of 20 to 50; optionally (d) 15 to 35 weight percent of a halogenated epoxy flame retardant; and (e) when (d) is present in the composition, optionally, 2 to 10 weight percent of a flame retardant synergist; wherein: the ratio of the combined weight of (b)+(c) relative to the weight of (a) ranges from 0.40 to 0.85; the ratio of the weight of (b) relative to that of (c) ranges from 0.3 to 2.5; and the Gardner impact of the composition, when molded, is at least 4.2 J, measured at −40° C. according to ASTM D5420. Methods of making articles by molding these melt-mixed compositions.
1. A composition comprising:
(a) 30 to 65 weight percent of a polyester;
(b) 7 to 25 weight percent of an ethylene copolymer toughener;
(c) 5 to 25 weight percent of a copolyether ester elastomer having a shore D hardness that ranges from 20 to 50;
(d) optionally, a flame retardant; and
(e) when (d) is present in the composition, optionally a flame retardant synergist,
wherein:
the ratio of the combined weight of (b)+(c) relative to the weight of (a) ranges from 0.40 to 0.85;
the ratio of the weight of (b) relative to that of (c) ranges from 0.3 to 2.5; and
the Gardner impact of the composition, when molded, is at least 4.2 J, measured at −40° C. according to ASTM D5420.
2. The composition of claim 1 , wherein the flame retardant, when present, is selected from halogenated polymers, halogenated epoxy flame retardants, and mixtures of these.
3. The composition of claim 2 , wherein:
when the flame retardant is a halogenated epoxy flame retardant, its concentration ranges from 15 to 35 weight percent of the total weight of the composition; and
the Gardner impact of the composition, when molded, is at least 7 J.
4. The composition of claim 2 , wherein the shore D hardness of the copolyether ester elastomer ranges from 25 to 45.
5. The composition of claim 2 , wherein the ratio of the combined weight of (b) plus (c) relative to the weight of (a) ranges from 0.45 to 0.85.
6. The composition of claim 2 , wherein the ethylene copolymer toughener comprises copolymerized monomers of ethylene and glycidyl methacrylate, and either n-butyl acrylate or ethyl acrylate.
7. The composition of claim 2 , wherein the polyester is selected from the group consisting of poly(ethylene terephthalate), poly(trimethylene terephthalate), poly(1,4-butylene terephthalate), and mixtures of these.
8. An article comprising the composition of claim 2 .
9. The article of claim 8 , in the form of a photovoltaic junction box or a photovoltaic connector.
10. A method of making an article comprising:
molding a melt-mixed composition comprising:
(a) 30 to 65 weight percent of a polyester;
(b) 7 to 25 weight percent of an ethylene copolymer toughener;
(c) 5 to 25 weight percent of a copolyether ester elastomer having a shore D hardness that ranges from 20 to 50;
(d) optionally, a flame retardant; and
(e) when (d) is present in the composition, optionally a flame retardant synergist, wherein:
the ratio of the combined weight of (b)+(c) relative to that of (a) ranges from 0.40 to 0.85;
the ratio of the weight of (b) to that of (c) ranges from 0.3 to 2.5; and
the Gardner impact of the article is at least 4.2 J, measured at −40° C. according to ASTM D5420.
11. The method of claim 10 , wherein the flame retardant, when present, is selected from halogenated polymers, halogenated epoxy flame retardants, and mixtures of these.
12. The method of claim 11 , wherein:
when the flame retardant is a halogenated epoxy flame retardant, its concentration ranges from 15 to 35 weight percent of the total weight of the composition and the Gardner impact of the article is at least 7 J.
13. The method of claim 11 , wherein the shore D hardness of the copolyether ester elastomer ranges from 25 to 45.
14. The method of claim 11 , wherein the ethylene copolymer toughener comprises copolymerized monomers of ethylene and glycidyl methacrylate, and either n-butyl acrylate or ethyl acrylate.