Ceramic body for light emitting devices
Some embodiments disclosed herein include a ceramic body including a first region and a second region. The first region may include a host material and first concentration of a dopant that is effective to produce luminescence. The second region may include the host material and second concentration of the dopant. In some embodiments, the first region has an average grain size that is larger than an average grain of the second region. The ceramic body may, in some embodiments, exhibit superior internal quantum efficiency (IQE). Some embodiments disclosed herein include methods for the making and using the ceramic bodies disclosed herein. Also, some embodiments disclosed herein lighting apparatuses including the ceramic bodies disclosed herein.
1. A ceramic body comprising:
a first region comprising a host material and a first concentration of a dopant, wherein the first concentration is effective to produce luminescence; and
a second region comprising the host material and a second concentration of the dopant, wherein the second concentration is less than the first concentration;
wherein the first region has an average grain size larger than an average grain size of the second region; and
the ceramic body exhibits an internal quantum efficiency (IQE) of at least about 0.80 when exposed to radiation having a wavelength of about 455 nm.
2. The ceramic body of claim 1 , wherein the host material is represented by the formula A 3 B 5 O 12 , wherein:
A is selected from the group consisting of Y, Lu, Ca, La, Tb, Gd and combinations thereof; and
B is selected from the group consisting of Al, Mg, Si, Ga, In, and combinations thereof.
3. The ceramic body of claim 1 , wherein the host material is selected from Y 3 Al 5 O 12 , (Y, Tb) 3 Al 5 O 12 , (Y, Gd) 3 Al 5 O 12 , (Y, Gd) 3 (Al, Ga) 5 O 12 , (Sr, Ca, Ba) 2 SiO 4 , Lu 3 Al 5 O 12 , Lu 2 CaMg 2 Si 3 O 12 , Lu 2 CaAl 4 SiO 12 , Ca 3 Sc 2 Si 3 O 12 , Ba 3 MgSi 2 O 8 , BaMgAl 10 O 17 , La 2 O 2 S, SrGa 2 S 4 , CaAlSiN 3 , Ca 2 Si 5 N 8 , and CaSiAlON.
4. The ceramic body of claim 1 , wherein the host material is Y 3 Al 5 O 12 .
5. The ceramic body of claim 1 , wherein the dopant is a rare earth metal.
6. The ceramic body of claim 1 , wherein the dopant is select from the group consisting of Ce, La, Tb, Pr, Eu, and combinations thereof.
7. The ceramic body of claim 1 , wherein the dopant is Ce.
8. The ceramic body of claim 1 , wherein the first region has an average grain size of about 5 μm to about 100 μm.
9. The ceramic body of claim 1 , wherein the second region has an average grain size of less than about 30 μm.
10. The ceramic body of claim 1 , wherein the second concentration of dopant is no more than about 0.2 at %.
11. The ceramic body of claim 1 , wherein a ratio of the first concentration of dopant to the second concentration of dopant is in the range of about 4:1 to about 1:1.
12. The ceramic body of claim 1 , wherein the first region comprises a central core of the ceramic body.
13. The ceramic body of claim 1 , where the second region comprises an outer peripheral of the ceramic body.
14. The ceramic body of claim 1 , wherein the first region adjoins the second region.
15. The ceramic body of claim 1 , the ceramic body further comprising a third region comprising the host material and a third concentration of the dopant, wherein the third concentration is less than the first concentration, the first region has an average grain size larger than an average grain size of the third region, and the first region is between the second and third regions.
16. The ceramic body of claim 15 , wherein:
the second region comprises a first surface of the ceramic body;
the third region comprises a second surface of the ceramic body; and
the first and second surface are on opposite sides of the ceramic body.
17. The ceramic body of claim 15 , wherein the first, second, and third regions are separate layers.
18. The ceramic body of claim 15 , wherein the third region has an average grain size less than about 30 μm.
19. The ceramic body of claim 15 , wherein the third concentration of dopant is no more than about 0.2 at %.
20. The ceramic body of claim 15 , wherein a ratio of the first concentration of dopant to the third concentration of dopant is in the range of about 4:1 to about 1:1.
21. A method of forming a ceramic body of claim 1 comprising:
forming an assembly, wherein forming the assembly comprises:
providing a first non-doped layer comprising a host material, a host material precursor, or combination thereof, wherein the first non-doped layer has a thickness in the range of about 40 μm to about 800 μm; and
disposing a doped layer on the first non-doped layer, wherein the doped layer has a thickness in the range of about 10 μm to about 400 μm, and comprises the host material, the host material precursor, or combination thereof, and a dopant; and
sintering the assembly to form the ceramic body comprising a first region and a second region, wherein an average grain size of the first region is larger than an average grain size of the second region;
wherein the first region comprises a first concentration of the dopant that is effective to produce luminescence, and the second region comprises a second concentration of the dopant that is less than the first concentration of the dopant.
22. A lighting apparatus comprising:
a light source configured to emit blue radiation; and
the ceramic body of claim 1 , wherein the ceramic body is configured to receive at least a portion of the blue radiation.