Copper CHA zeolite catalysts
View Patent ↗Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.
1. A SCR catalyst comprising an aluminosilicate zeolite having the CHA crystal structure and a mole ratio of silica to alumina from about 10 to about 150 and an atomic ratio of copper to aluminum from about 0.25 to about 1, the catalyst effective to promote the reaction of ammonia with nitrogen oxides to form nitrogen and H 2 O selectively, wherein the catalyst is in a form of a honeycomb monolith formed of the SCR catalyst.
2. The catalyst of claim 1 , wherein the mole ratio of silica to alumina is from about 15 to about 100.
3. The catalyst of claim 1 , wherein the mole ratio of silica to alumina is from about 15 to about 50 and the atomic ratio of copper to aluminum is from about 0.25 to about 0.5.
4. A staged catalyst comprising an aluminosilicate zeolite having the CHA crystal structure and a mole ratio of silica to alumina from about 10 to about 150 and an atomic ratio of copper to aluminum from about 0.25 to about 1, the catalyst having a first catalyst zone with copper loading on the zeolite tailored to promote an SCR reaction of ammonia with nitrogen oxides to form nitrogen and H 2 O selectively followed by a second catalyst zone comprising a zeolite having the CHA crystal structure and thereon a copper loading tailored to promote oxidation of ammonia.
5. The staged catalyst of claim 4 , wherein the second catalyst zone comprises a platinum group metal.
6. The staged catalyst of claim 4 , wherein the zones are on a single honeycomb substrate.
7. The staged catalyst of claim 4 , wherein the zones are on a separate honeycomb substrate.