Nonvolatile semiconductor storage device and fabrication method thereof
View Patent ↗A nonvolatile semiconductor storage device has a plurality of memory strings in which electrically rewritable memory cells are connected in series. The memory strings have word-line electroconductive layers laminated at a prescribed interval to sandwich an interlayer insulating film onto a semiconductor substrate and through holes that penetrate through the word-line electroconductive layers and the interlayer insulating films. The gate insulating film is formed along an inner wall of the through holes and includes a charge-accumulating film. The columnar semiconductor layer is formed inside the through holes to sandwich the gate insulating film along with the word-line electroconductive layer. The columnar semiconductor layer contains carbon, oxygen, or nitrogen.
1. A nonvolatile semiconductor storage device, comprising:
a memory string in which a plurality of electrically rewritable memory cells are connected in series in a first direction orthogonal to a plane of a substrate,
the memory string comprising:
word-line layers separated by interlayer insulating layers in the first direction,
a through hole that penetrates through the word-line layers and the interlayer insulating layers in the first direction,
an insulating film formed on an inner wall of the through hole, the insulating film having a charge accumulation layer, and
a columnar semiconductor layer formed on the insulating film in the through hole, the columnar semiconductor layer having a first semiconductor layer formed on the insulating film in the through hole and a second semiconductor layer formed on the first semiconductor layer in the through hole, the second semiconductor layer having at least one void therein.
2. The nonvolatile semiconductor storage device of claim 1 , wherein the first semiconductor layer is formed of silicon and the second semiconductor layer is formed of silicon with a dopant.
3. The nonvolatile semiconductor storage device of claim 1 , wherein the second semiconductor layer is formed of silicon doped with carbon.
4. The nonvolatile semiconductor storage device of claim 1 , wherein the second semiconductor layer is configured to prevent migration of the void therein.
5. The nonvolatile memory of claim 4 , wherein the insulating film is a gate insulator film.
6. The nonvolatile semiconductor storage device of claim 1 , wherein the void is formed as an unwanted consequence of the deposition process of the second semiconductor layer.
7. The nonvolatile semiconductor storage device of claim 1 , wherein the first and the second semiconductor layers are deposited by a chemical vapor deposition process.
8. The nonvolatile semiconductor storage device of claim 7 , wherein a dopant is introduced during the deposition process after the first semiconductor layer is deposited.
9. A nonvolatile semiconductor storage device, comprising:
a memory string in which electrically rewritable memory cells are connected in series in a first direction orthogonal to a plane of a substrate,
the memory string comprising:
a plurality of word-line layers separated by interlayer insulating layers in the first direction,
a through hole that penetrate through the word-line layers and the interlayer insulating layers in the first direction,
an insulating film formed on an inner wall of the through hole, the insulating film having a charge accumulation layer, and
a columnar semiconductor layer formed on the insulating film inside the through hole; wherein
the columnar semiconductor layer contains carbon or nitrogen.
10. The nonvolatile semiconductor storage device according to claim 9 , wherein
a concentration of carbon or nitrogen in a central portion of a cross section of the columnar semiconductor layer perpendicular to the first direction is higher than a concentration of carbon or nitrogen in a peripheral portion of the cross section of the columnar semiconductor layer perpendicular to the first direction.
11. The nonvolatile semiconductor storage device according to claim 9 , wherein
a concentration of carbon or nitrogen in a cross section of the columnar semiconductor layer perpendicular to the first direction has a gradient that increases from a peripheral portion of the cross section toward a central portion of the cross section.
12. The nonvolatile semiconductor storage device of claim 9 , wherein the columnar semiconductor layer has a first semiconductor layer formed on the insulating film and a second semiconductor layer formed on the first semiconductor layer, a concentration of carbon or nitrogen of the second semiconductor layer being higher than a concentration of carbon or nitrogen of the first semiconductor layer.
13. The nonvolatile semiconductor storage device of claim 12 , wherein the second semiconductor layer has at least one void therein.
14. The nonvolatile semiconductor storage device of claim 9 , wherein the columnar semiconductor layer has an outer layer and an inner layer, and the inner layer includes a dopant therein.