Blends of polysulfones and polyphenylene sulfide resins
View Patent ↗Compositions including a blend of a) a polysulfone (PSU); b) a polyphenylene sulfide (PPS); and, c) a polyetherimide and epoxy. The polyetherimide and epoxy can be present in an amount effective to act as a compatibilizer for the polysulfone (PSU) and polyphenylene sulfide (PPS). Various embodiments relate to a method of compatibilizing a blend of polysulfone (PSU) and polyphenylene sulfide (PPS). The method can include a) melt mixing a polysulfone (PSU) and a polyetherimide; and b) melt mixing a polyphenylene sulfide (PPS) and an epoxy. Step a) and b) can be carried out by one of sequential mixing and simultaneous mixing.
1. A composition comprising a blend of:
a) a polysulfone (PSU)
b) a polyphenylene sulfide (PPS); and,
c) a polyetherimide and epoxy, wherein the polyetherimide and epoxy are present in an amount effective to act as a compatibilizer for the polysulfone (PSU) and a polyphenylene sulfide (PPS), and the polyetherimide is present in the range of 2.5-30 wt % and the epoxy is in the range of 0.5-1.5 wt %, and wherein the composition possess a tensile strength greater than 70 Mpa, an impact strength of at least 35 J/m, and an elongation at break of at least 105%.
2. The composition of claim 1 , wherein the epoxy is an epoxy cresol novolac resin.
3. The composition of claim 1 , wherein the polyphenylene sulfide (PPS) is a linear poly(phenylene) sulfide.
4. The composition of claim 1 , wherein the morphology of the composition is fine, well-dispersed domains of polysulfone (PSU) and polyphenylene sulfide (PPS).
5. The composition of claim 1 , wherein the composition exhibits a heat distortion temperature (HDT) of at least 90° C.
6. The composition of claim 1 , wherein the polysulfone (PSU) is present in the range of 22.5-67.5 wt % and the polyphenylene sulfide (PPS) is present in the range of 25-75 wt %.
7. An extrudate comprising the composition of claim 1 .
8. A molded product comprising the composition of claim 1 .