IP Library Granted Patent US 9,764,279
Granted Patent B2
US 9,764,279 · App. 13/792,144 · Granted Sep 19, 2017

Biological reduction of carbon dioxide pollutants systems and methods

Inventors: Song Jin (Fort Collins, CO); Paul Fallgren (Westminster, CO); Jeffrey M. Morris (Arvada, CO); Alan E. Bland (Laramie, WY); Patrick Richards (Seattle, WA); Jesse D. Newcomer (Laramie, WY); Patricia Colberg (Laramie, CO)
Assignee: The University of Wyoming Research Corporation
B01D53/62B01D53/84C10L1/026C12N1/20C12P7/649F23J15/02B01D2251/95B01D2257/504C10G2300/1011C10G2300/405C10G2300/4043F23J2215/50Y02C10/02Y02C10/04Y02E20/326Y02E50/13Y02E50/17Y02E50/343Y02E50/346Y02P20/152Y02P20/59Y02P30/10Y02P30/20Y02P30/446
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Quick Facts
Patent No.
US 9,764,279
App. No.
13/792,144
Granted
Sep 19, 2017
Kind
B2
Abstract

Methods and systems to achieve clean fuel processing systems in which carbon dioxide emissions ( 1 ) from sources ( 2 ) may be processed in at least one processing reactor ( 4 ) containing a plurality of chemoautotrophic bacteria ( 5 ) which can convert the carbon dioxide emissions into biomass ( 6 ) which may then be used for various products ( 21 ) such as biofuels, fertilizer, feedstock, or the like. Sulfate reducing bacteria ( 13 ) may be used to supply sulfur containing compounds to the chemoautotrophic bacteria ( 5 ).

Claims (43)

1. A method of reducing carbon dioxide pollutants emitted from industrial plants comprising the steps of:

providing an industrial system which releases emissions into the atmosphere, said emissions having at least some carbon dioxide emissions;

providing a dual reactor emission reduction system comprising:

a first ex-situ processing reactor containing chemoautotrophic bacteria connected to a second ex-situ processing reactor containing sulfate reducing bacteria, whereby said chemoautotrophic bacteria are capable of digesting carbon dioxide fueled by reduced sulfur compounds to generate oxidized sulfur compounds, and whereby said sulfate reducing bacteria are capable of converting said oxidized sulfur compounds to generate said reduced sulfur compounds;

a sulfur shuttle between said first and second ex-situ processing reactors;

incorporating said dual reactor emission reduction system into said industrial system;

capturing substantially all of said emissions;

pretreating said emissions to provide separated carbon dioxide emissions;

containing said separated carbon dioxide emissions;

introducing said separated carbon dioxide emissions into said first ex-situ processing reactor of said dual reactor emission reduction system;

digesting said separated carbon dioxide emissions with said chemoautotrophic bacteria;

shuttling said oxidized sulfur compounds to said sulfate reducing bacteria in said second ex-situ processing reactor;

shuttling said reduced sulfur compounds to said chemoautotrophic bacteria in said first ex-situ processing reactor to create a continuous energy supply to said chemoautotrophic bacteria and said sulfate reducing bacteria;

regulating said first and second ex-situ processing reactors;

biologically producing biomass, lipids, and paraffin in said first and second ex-situ processing reactors;

extracting said biomass, lipids and paraffin from said reactors; and

reducing said carbon dioxide emissions into said atmosphere from said industrial system.

2. A method of reducing carbon dioxide pollutants according to claim 1 wherein said emissions further comprise a pollutant selected from a group consisting of nitrogen, nitrogen oxide, sulfur oxide, oxygen, and any combination thereof.

3. A method of reducing carbon dioxide pollutants according to claim 1 wherein said industrial system is selected from a group consisting of power generation sources, cement producing plants, coal refineries, oil refineries, refineries, lime producing plants, non-power generation sources, coal-fired power plants, natural gas-fired power plants, generation fuel cells, and combustion power plants.

4. A method of reducing carbon dioxide pollutants according to claim 1 wherein said chemoautotrophic bacteria are selected from a group consisting of Thiobacillus species, Paracoccus species, and combinations thereof.

5. A method of reducing carbon dioxide pollutants according to claim 1 and further comprising the step of providing waste organic carbon to said sulfate reducing bacteria in said second ex-situ processing reactor.

6. A method of reducing carbon dioxide pollutants according to claim 5 wherein said waste organic carbon is selected from a group consisting of waste dairy products, returned milk, waste dairy byproducts, cheese whey, straw, and woodchips.

7. A method of reducing carbon dioxide pollutants according to claim 1 wherein said sulfate reducing bacteria comprises Desulfovibrio desulfuricans and wherein said chemoautotrophic bacteria is selected from a group consisting of Thiobacillus ssp. genus, Paracoccus ssp genus, Thiovulum ssp. genus, Thiobacillus denitrificans, T. thioparus, T. caldus, T. hydrothermalis, Paracoccus genus, and Thiovulim genus.

8. A method of reducing carbon dioxide pollutants according to claim 1 and further comprising the step of providing recycled process biomass residue from said dual reactor emission reduction system as an electron donor supply to said sulfate reducing bacteria in said second ex-situ processing reactor.

9. A method of reducing carbon dioxide pollutants according to claim 1 and further comprising the step of processing said biomass into a fuel.

10. A method of reducing carbon dioxide pollutants according claim 1 and further comprising the step of drying said biomass.

11. A method of reducing carbon dioxide pollutants according to claim 1 wherein said step of regulating said first and second ex-situ processing reactors comprises a step selected from a group consisting of:

adjusting a pH of said first or second ex-situ processing reactors;

adding buffering solutions to said first or second ex-situ processing reactors;

adjusting a temperature of said first or second ex-situ processing reactors;

adding nutrients to said first or second ex-situ processing reactors;

adding inorganic ions to said first or second ex-situ processing reactors;

adjusting inorganic ions concentrations in said first or second ex-situ processing reactors;

adjusting bacterial cell densities in said first or second ex-situ processing reactors; and

adjusting nutrient concentrations added to said first or second ex-situ processing reactors.

12. A method of reducing carbon dioxide pollutants according to claim 1 wherein said step of regulating said first and second ex-situ processing reactors comprises a step selected from a group consisting of:

adjusting a concentration of said oxidized sulfur compounds entering said second ex-situ processing reactor;

adjusting a concentration of said reduced sulfur compounds entering said first ex-situ processing reactor; and

adjusting a concentration of separated carbon dioxide emissions entering said first ex-situ processing reactor.

13. A method of reducing carbon dioxide pollutants according to claim 1 wherein said oxidized sulfur compounds comprise sulfate.

14. A method of reducing carbon dioxide pollutants according to claim 1 wherein said reduced sulfur compounds comprise hydrogen sulfide.

15. A method of reducing carbon dioxide pollutants according to claim 1 wherein said step of extracting said biomass from said reactors comprises the step of extracting said biomass when a critical mass of biomass has been achieved.

16. A method of reducing carbon dioxide pollutants according to claim 1 wherein said step of incorporating said dual reactor emission reduction system into said industrial system comprises the step of retrofitting said dual reactor emission reduction system into said industrial system.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 24, 2022
From: THE UNIVERSITY OF WYOMING RESEARCH CORPORATION DBA WESTERN RESEARCH INSTITUTE
To: WESTERN RESEARCH INSTITUTE, INC.
Reel/Frame 060892/0182 →
CONFIRMATORY LICENSE Recorded Sep 29, 2014
From: UNIVERSITY OF WYOMING RESEARCH CORPORATION D/B/A WESTER RESEARCH INSTITUTE
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 033835/0239 →
NUNC PRO TUNC ASSIGNMENT Recorded Mar 29, 2013
From: JIN, SONG; FALLGREN, PAUL; MORRIS, JEFFREY M.; BLAND, ALAN E.; RICHARDS, PATRICK; NEWCOMER, JESSE D.; COLBERG, PATRICIA
To: THE UNIVERSITY OF WYOMING RESEARCH CORPORATION D/B/A WESTERN RESEARCH INSTITUTE
Reel/Frame 030115/0774 →
Continuity (4)
Continuation 13127697
Provisional Application 61228898 · Jul 27, 2009
Provisional Application 61358700 · Jun 25, 2010
Related Publication 20130189739A1 · Jul 25, 2013