Sensor interrogation
View Patent ↗A method of testing a system having at least one electrochemical sensor for detecting an analyte gas within a housing of the system, the housing having an inlet, the at least one electrochemical sensor including an electrically active working electrode in fluid connection with the inlet of the system, the method including biasing the electrically active working electrode at a first potential, to detect the analyte gas and biasing the electrically active working electrode at a second potential, different from the first potential, such that the at least one electrochemical sensor is sensitive to a driving force created in the vicinity of the inlet to test at least one transport path of the system. The method may further include creating the driving force in the vicinity of the inlet of the housing of the system and measuring a response of the electrically active working electrode to the driving force.
1. A method of testing a system having at least one electrochemical sensor for detecting a first gas that is an analyte gas within a housing of the system, the housing of the system having an inlet and a porous membrane through which gas can diffuse in fluid connection with the inlet, the at least one electrochemical sensor comprising an electrically active working electrode in fluid connection with the inlet of the system, comprising:
biasing the electrically active working electrode at a first potential, to detect the first gas;
biasing the electrically active working electrode at a second potential, different from the first potential, such that the at least one electrochemical sensor is sensitive to a change in a concentration of a second gas that is a gas other than the first gas or a simulant therefor;
creating a driving force in the vicinity of the inlet of the housing of the system which changes the concentration of the second gas other than by application of the first gas or a simulant therefore while the electrically active working electrode is biased at the second potential; and
measuring a non-analytical response of the electrically active working electrode to the driving force while the electrically active working electrode is biased at the second potential to test at least one transport path of the system including transport through the porous membrane.
2. The method of claim 1 wherein the driving force comprises (a) application of exhaled breath or (b) restricting entry of molecules into the inlet.
3. The method of claim 1 further comprising returning the electrically active working electrode to the first potential.
4. The method of claim 2 wherein the electrically active working electrode is responsive to carbon dioxide at the second potential.
5. The method of claim 1 wherein the electrically active working electrode is responsive to oxygen at the second potential.
6. The method of claim 1 further comprising electronically interrogating the at least one electrochemical sensor to test the functionality thereof to detect the analyte gas.
7. The method of claim 1 further comprising:
simulating the presence of the first gas electronically; and
measuring a response of the at least one electrochemical sensor to the electronic simulation.
8. The method of claim 7 wherein a constant current is caused to flow between the electrically active working electrode and a counter electrode of the at least one electrochemical sensor and the measured response is a potential difference.
9. The method of claim 7 wherein a constant potential difference is maintained between the electrically active working electrode and a counter electrode of the at least one electrochemical sensor and the measured response is a current.
10. The method of claim 7 wherein the at least one electrochemical sensor is an amperometric sensor.
11. The method of claim 1 wherein the at least one electrochemical sensor comprises a sensor housing comprising at least one inlet into an interior of the sensor housing, the electrically active working electrode being positioned within the sensor housing.
12. The method of claim 1 wherein the electrically active working electrode comprises an electrocatalytically active material deposited upon a porous membrane through which gas can diffuse.