Heat stable SnAl and SnMg based dielectrics
View Patent ↗A transparent dielectric composition comprising tin, oxygen and one of aluminum or magnesium with preferably higher than 15% by weight of aluminum or magnesium offers improved thermal stability over tin oxide with respect to appearance and optical properties under high temperature processes. For example, upon a heat treatment at temperatures higher than 500 C, changes in color and index of refraction of the present transparent dielectric composition are noticeably less than those of tin oxide films of comparable thickness. The transparent dielectric composition can be used in high transmittance, low emissivity coated panels, providing thermal stability so that there are no significant changes in the coating optical and structural properties, such as visible transmission, IR reflectance, microscopic morphological properties, color appearance, and haze characteristics, of the as-coated and heated treated products.
1. A composition comprising
tin oxide;
and
a third element,
wherein the tin oxide is doped with the third element,
wherein the third element is either aluminum or magnesium,
wherein the third element comprises more than 15% by weight of the total metal content of the composition,
wherein the composition is a transparent dielectric, and
wherein the composition has an appearance that remains the same, by visual inspection, after a heat treatment.
2. A composition as in claim 1 , wherein the third element comprises less than 70% by weight of the total metal content of the composition.
3. A composition as in claim 1 , wherein the third element comprises less than 35% by weight of the total metal content of the composition.
4. A composition as in claim 1 , wherein the composition has an amorphous structure.
5. A thin film coating comprising
tin oxide;
and
a third element,
wherein the tin oxide is doped with the third element,
wherein the third element is either aluminum or magnesium,
wherein the third element comprises more than 15% by weight of the total metal content of the composition, and
wherein the thin film coating is a transparent dielectric.
6. A thin film coating as in claim 5 , wherein the thin film coating comprises at least another thin film coating, wherein the another thin film coating is operable as an optical filler film.
7. A thin film coating as in claim 5 , wherein the third element comprises less than 70% by weight of the total metal content of the thin film coating.
8. A thin film coating as in claim 5 , wherein the third element comprises less than 35% by weight of the total metal content of the thin film coating.
9. A thin film coating as in claim 5 , wherein the thin film coating is amorphous.
10. A thin film coating as in claim 5 , wherein the thin film coating is disposed on a transparent substrate comprising glass or plastic.
11. A thin film coating as in claim 5 , wherein the article has an appearance that is unchanged by visual inspection after a heat treatment.
12. An article comprising:
a transparent substrate; and
a film disposed on the substrate, the film comprising tin oxide doped with a third element,
wherein the third element is either aluminum or magnesium,
wherein the third element comprises more than 15% by weight of the total metal content of the film, and
wherein the film is a transparent dielectric film.
13. An article as in claim 12 , wherein the third element comprises less than 70% by weight of the total metal content of the film.
14. An article as in claim 12 , wherein the third element comprises less than 35% by weight of the total metal content of the film.
15. An article as in claim 12 , wherein the transparent dielectric film has an amorphous structure.
16. An article as in claim 12 , further comprising at least one of
an antireflective film;
a metallic reflective film comprises one of silver, gold, or copper; or
a top protective film.
17. An article as in claim 12 , wherein the transparent substrate comprises glass or plastic.
18. An article as in claim 12 , wherein the article has an appearance that is unchanged by visual inspection after to a heat treatment.
19. An article as in claim 18 , wherein the heat treatment process comprises annealing at a temperature less than 1000 C for less than 10 minutes.
20. An article as in claim 18 , wherein the heat treatment process comprises annealing at a temperature higher than 500 C for less than 10 minutes.