Negative active material for rechargeable lithium battery, method of preparing the same, and rechargeable lithium battery including the same
View Patent ↗The invention relates to a negative active material for a rechargeable lithium battery, including an inner layer including a material being capable of doping and dedoping lithium, a carbon layer outside the inner layer, and an outer layer disposed on the carbon layer and including a material being capable of doping and dedoping lithium. The materials being capable of doping and dedoping lithium may be the same or different from each other. The invention further relates to a method of preparing the negative active material including: preparing a tube-shaped template with a hollow part; forming an outer layer including a material which can dope and dedope lithium inside the template; forming an inner precursor layer including a material which can dope and dedope lithium modified with an organic functional group inside the outer layer; annealing the template; and removing the template.
1. A method of preparing a negative active material for a rechargeable lithium battery, comprising:
preparing a tube-shaped template with a hollow part;
forming a first layer comprising a material being capable of doping and dedoping lithium inside the tube-shaped template;
forming an inner precursor layer comprising a material being capable of doping and dedoping lithium which includes an organic functional group inside the first layer;
forming a carbon layer and a second layer inside the first layer by annealing the tube-shaped template; and
removing the tube-shaped template from the first layer,
wherein each of the second layer, the carbon layer and the first layer has a tube shape, the carbon layer surrounds the second layer and the first layer surrounds the carbon layer.
2. The method of claim 1 , wherein the organic functional group is represented as CnHm, and wherein the n and m are integers of 1 or more.
3. The method of claim 2 , wherein the organic functional group is selected from the group consisting of a C1 to C30 aliphatic group, a C3 to C30 alicyclic group, a C6 to C30 aromatic group, and a combination thereof.
4. The method of claim 1 , wherein the annealing is performed at a temperature ranging from about 700° C. to about 1100° C.
5. The method of claim 1 , wherein the tube-shaped template is removed using a basic or acidic material.
6. The method of claim 5 , wherein the basic material or the acidic material has a concentration ranging from about 1M to about 6M.