2xxx series aluminum lithium alloys
View Patent ↗New 2xxx aluminum lithium alloys are disclosed. The aluminum alloys include 3.5-4.4 wt. % Cu, 0.45-0.75 wt. % Mg, 0.45-0.75 wt. % Zn, 0.65-1.15 wt. % Li, 0.1-1.0 wt. % Ag, 0.05-0.50 wt. % of at least one grain structure control element, up to 1.0 wt. % Mn, up to 0.15 wt. % Ti, up to 0.12 wt. % Si, up to 0.15 wt. % Fe, up to 0.10 wt. % of any other element, with the total of these other elements not exceeding 0.35 wt. %, the balance being aluminum.
1. A wrought aluminum alloy product consisting of:
3.5-4.4 wt. % Cu;
0.45-0.75 wt. % Mg;
0.45-0.75 wt. % Zn;
wherein (wt. % Zn)/(wt. % Mg) is 0.60-1.67;
0.65-0.950 wt. % Li;
0.1-1.0 wt. % Ag;
from 0.05 to 0.50 wt. % of at least one grain structure control element, wherein the at least one grain structure control element is selected from the group consisting of Zr, Sc, Cr, V, Hf, rare earth elements, and combinations thereof;
up to 1.0 wt. % Mn;
up to 0.15 wt. % Ti;
up to 0.12 wt. % Si;
up to 0.15 wt. % Fe; and
the balance being aluminum and incidental impurities;
wherein the wrought aluminum alloy product has a thickness of at least 12.7 mm; and
wherein the wrought aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 22 ksi√in.
2. The wrought aluminum alloy product of claim 1 , comprising at least 3.7 wt. % Cu.
3. The wrought aluminum alloy product of claim 1 , comprising not greater than 4.2 wt. % Cu.
4. The wrought aluminum alloy product of claim 1 , comprising at least 0.55 wt. % Mg.
5. The wrought aluminum alloy product of claim 1 , comprising not greater than 0.65 wt. % Mg.
6. The wrought aluminum alloy product of claim 1 , comprising at least 0.55 wt. % Zn.
7. The wrought aluminum alloy product of claim 1 , comprising not greater than 0.65 wt. % Zn.
8. The wrought aluminum alloy product of claim 1 , wherein (wt. % Zn)/(wt. % Mg) is 0.70-1.40.
9. The wrought aluminum alloy product of claim 1 , wherein (wt. % Zn)/(wt. % Mg) is 0.80-1.20.
10. The wrought aluminum alloy product of claim 1 , comprising at least 0.75 wt. % Li.
11. The wrought aluminum alloy product of claim 1 , comprising at least 0.825 wt. % Li.
12. The wrought aluminum alloy product of claim 1 , comprising at least 0.875 wt. % Li.
13. The wrought aluminum alloy product of claim 1 , comprising not greater than 0.5 wt. % Ag.
14. The wrought aluminum alloy product of claim 1 , comprising at least 0.05 wt. % Mn.
15. The wrought aluminum alloy product of claim 1 , comprising not greater than 0.5 wt. % Mn.
16. The wrought aluminum alloy product of claim 1 , wherein the wrought aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 23 ksi√in.
17. The wrought aluminum alloy product of claim 1 , wherein the wrought aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 24 ksi√in.
18. The wrought aluminum alloy product of claim 1 , wherein the wrought aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 25 ksi√in.
19. The wrought aluminum alloy product of claim 1 , wherein the wrought aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 26 ksi√in.
20. The wrought aluminum alloy product of claim 1 , wherein the wrought aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 27 ksi√in.
21. A rolled aluminum alloy product consisting of:
3.7-4.2 wt, % Cu;
0.55-0.65 wt. Mg;
0.55-0.65 wt. % Zn;
wherein (wt. % Zn)/(wt. % Mg) is 0.85-1.15;
0.75-0.950 wt. % Li;
0.10-0.50 wt. % Ag;
0.05-0.4 wt. % Mn,
0.07-0.14 wt. % Zr;
up to 0.15 wt, % Ti;
up to 0.12 wt. % Si;
up to 0.15 wt. % Fe; and
the balance being aluminum and incidental impurities;
wherein the rolled aluminum alloy product has a thickness of from 25.4 mm to 101.6 mm; and
wherein the rolled aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 22 ksi√in.
22. The rolled aluminum alloy product of claim 21 , comprising at least 0.825 wt. % Li.
23. The rolled aluminum alloy product of claim 21 , comprising at least 0.875 wt. % Li.
24. The rolled aluminum alloy product of claim 21 , wherein the rolled aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 23 ksi√in.
25. The rolled aluminum alloy product of claim 21 , wherein the rolled aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 24 ksi√in.
26. The rolled aluminum alloy product of claim 21 , wherein the rolled aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 25 ksi√in.
27. The rolled aluminum alloy product of claim 21 , wherein the roiled aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 26 ksi√in.
28. The rolled aluminum alloy product of claim 21 , wherein the rolled aluminum alloy product realizes a plane strain fracture toughness (K IC ) of at least 27 ksi√in.