IP Library Granted Patent US 9,103,654
Granted Patent B1
US 9,103,654 · App. 13/801,100 · Granted Aug 11, 2015

GMR nanowire sensors

Inventor: Bryan Cox (Marion, AR)
Assignee: Louisiana Tech University Research Foundation, a division of Louisiana Tech University Foundation, Inc.
G01B7/14G01D5/145G01R33/09
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Quick Facts
Patent No.
US 9,103,654
App. No.
13/801,100
Granted
Aug 11, 2015
Kind
B1
Abstract

A magnetic position sensor having at least one magnetic field sensor including a solidified layer of GMR nanowire carrier fluid formed on a substrate material. The solidified layer of carrier fluid has (i) discrete GMR nanowires each having a diameter of less than about 0.5 um and a length less than about 250 um; and (ii) a concentration of GMR nanowires in the dried layer between about 0.001 and about 10 percent by weight of the solution. The position sensor further includes a detection circuit capable of detecting a change in resistance of the magnetic field sensor.

Claims (39)

1. A magnetic position sensor comprising:

a. at least one magnetic field sensor comprising a solidified layer of GMR nanowire carrier fluid formed on a substrate material, wherein the solidified layer of carrier fluid comprises:

i. discrete GMR nanowires each having a diameter of less than about 0.5 μm and a length less than about 250 μm; and

ii. a concentration of GMR nanowires in the solidified layer being between about 0.001 and about 10 percent by weight of the carrier fluid;

b. a detection circuit capable of detecting a change in resistance of the magnetic field sensor; and

c. a magnet allowing relative movement closer to or further away from, the magnetic field sensor.

2. The magnetic position sensor of claim 1 , wherein the magnetic field sensor and the magnet are positioned in a housing and a biasing mechanism urges the magnet and magnetic field sensor apart.

3. The magnetic position sensor of claim 1 , further comprising a plurality of magnetic field sensors positioned on the substrate in a two dimensional configuration.

4. The magnetic position sensor of claim 3 , wherein a plurality of indicia are positioned over the substrate such that each indicia corresponds to at least one magnetic field sensor, thereby causing a change in resistance in the at least one magnetic field sensor as the magnet is moved over the indicia.

5. The magnetic position sensor of claim 1 , wherein the solidified layer of carrier fluid has at least about 100 nanowires per mm 2 .

6. The magnetic position sensor of claim 1 , wherein the GMR nanowires are positioned in a substantially random orientation when adhered to the substrate material.

7. The magnetic position sensor of claim 1 , further comprising a corrosion inhibitor which is at least one of a barrier-forming corrosion inhibitor or a scavenger corrosion inhibitor.

8. A GMR material carrying solution comprising:

a. a carrier fluid;

b. a concentration of discrete GMR nanowires contained in the carrier fluid, wherein:

i. the discrete GMR nanowires each having a diameter of less than about 0.5 μm and a length less than about 200 μm;

ii. the GMR nanowires have an aspect ratio of at least five;

iii. the concentration of GMR nanowires being between about 0.005 and about 10 percent by weight of the carrier fluid.

9. The GMR material carrying solution according to claim 8 , wherein the carrier fluid comprises

0.0001% to 0.5% of a surfactant;

0.01% to 15% of a viscosity modifier; and

80% to 99.0% of a solvent.

10. The GMR material carrying solution according to claim 8 , wherein the carrying solution comprises at least one solvent selected from group consisting of water, an alcohol, a ketone, an ether, a hydrocarbon or an aromatic solvent.

11. The GMR material carrying solution according to claim 8 , wherein the carrying solution comprises at least one of a dispersion agent, a viscosity control agent, a corrosion inhibitor, or an adhesion agent.

12. The GMR material carrying solution according to claim 8 , wherein the discrete nanowires each have a diameter of less than about 0.2 μm and a length less than about 100 μm.

13. The GMR material carrying solution according to claim 8 , wherein GMR nanowires comprise alternating ferromagnetic and non-magnetic conductive layers.

14. The GMR material carrying solution according to claim 8 , wherein the carrier fluid includes an ink, dye, or other pigment.

15. The GMR material carrying solution according to claim 8 , wherein the carrier fluid is substantially transparent.

16. The GMR material carrying solution according to claim 8 , further comprising a flux concentrator agent.

17. The GMR material carrying solution according to claim 8 , further comprising a corrosion inhibitor.

18. A method of forming a magnetic field sensor comprising the step of adhering a solidified layer of GMR nanowire carrier fluid to a substrate material, wherein the GMR nanowire carrier fluid comprises:

i. discrete GMR nanowires in the carrier fluid each having a diameter of less than about 0.5 μm and a length less than about 200 μm; and

ii. a concentration of GMR nanowires in the carrier fluid being between about 0.01 and about 10 percent by weight of the solution;

iii. wherein the GMR nanowires are positioned in a random orientation when adhered to the substrate material.

19. The method of forming a magnetic field sensor according to claim 18 , wherein the GMR nanowire carrier fluid is adhered to the substrate by drying the carrier fluid on the substrate.

20. The method of forming a magnetic field sensor according to claim 18 , wherein the substrate is a flexible sheet of polymer material.

21. The method of forming a magnetic field sensor according to claim 18 , wherein the carrier fluid is applied to the substrate using at least one sheet based or roll-to-roll based printing techniques.

22. The method of forming a magnetic field sensor according to claim 18 , wherein the sensor has a resistance change of about at least 0.01% per mT.

23. The method of forming a magnetic field sensor according to claim 18 , wherein the sensor is formed in a predefined shape on the substrate by applying the carrier fluid to a stamp having the predefined shape and then applying the stamp to the substrate in order transfer the carrier fluid to the substrate.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2016
From: LOUISIANA TECH UNIVERSITY RESEARCH FOUNDATION, A DIVISION OF LOUISIANA TECH UNIVERSITY FOUNDATION, INC.
To: LOUISIANA TECH RESEARCH CORPORATION
Reel/Frame 037653/0323 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 14, 2013
From: COX, BRYAN
To: LOUISIANA TECH UNIVERSITY RESEARCH FOUNDATION, A DIVISION OF LOUISIANA TECH UNIVERSITY FOUNDATION, INC.
Reel/Frame 029993/0564 →
Continuity (1)
Provisional Application 61622605 · Apr 11, 2012