Low-temperature fabrication of metal oxide thin films and nanomaterial-derived metal composite thin films
View Patent ↗Disclosed are new methods of fabricating metal oxide thin films and nanomaterial-derived metal composite thin films via solution processes at low temperatures (<400° C.). The present thin films are useful as thin film semiconductors, thin film dielectrics, or thin film conductors, and can be implemented into semiconductor devices such as thin film transistors and thin film photovoltaic devices.
1. A method of fabricating a transistor device comprising a thin film semiconductor component comprising indium gallium zinc oxide (In—Ga—Zn—O), the method comprising:
depositing a thin film from a precursor composition comprising an indium salt, a gallium salt, and a zinc salt in a solvent or solvent mixture, wherein the indium salt, the gallium salt, and the zinc salt independently comprise either an oxidizing anion or a fuel anion, provided that (a) if none of the indium salt, the gallium salt and the zinc salt comprises a fuel anion, then the precursor composition further comprises either a fuel or an ammonium salt comprising a fuel anion, and (b) if none of the indium salt, the gallium salt and the zinc salt comprises an oxidizing anion, then the precursor composition further comprises either an acid comprising an oxidizing anion or an inorganic salt comprising an oxidizing anion, wherein:
the fuel is selected from acetylacetone, CF 3 COCH 2 COCF 3 , CH 3 COCHFCOCH 3 , CH 3 COCH 2 C(═NH)CF 3 , CH 3 C(═NH)CHFC(═NH)CH 3 , CH 3 COCH 2 C(═NCH 3 )CF 3 , CH 3 C(═NCH 3 )CHFC(═NCH 3 )CH 3 , CH 3 C(═NH)CHFC(═NCH 3 )CH 3 , Ph 2 POCH 2 COCH 3 , urea, N-methylurea, citric acid, ascorbic acid, stearic acid, nitromethane, hydrazine, carbohydrazide, oxalyl dihydrazide, malonic acid dihydrazide, tetra formal tris azine, hexamethylenetetramine, and malonic anhydride,
the fuel anion is selected from acetylacetonate, a citrate, an oxalate, an ascorbate, and a stearate,
the oxidizing anion is selected from a nitrate, a perchlorate, a chlorate, a hypochlorite, an azide, a peroxide, a superoxide, a high-valent oxide, an N-oxide, a persulfate, a dinitramide, a nitrocyanamide, a nitroarylcarboxylate, a tetrazolate, and hydrates thereof, and
the oxidizing anions and the fuel and fuel anions in the precursor composition are present in amounts to allow metal oxide formation and complete combustion of the fuel and fuel anions; and
annealing the thin film at a temperature of less than or about 350° C. to initiate a combustion reaction between the oxidizing anions and the fuel and fuel anions, thereby forming a thin film semiconductor component comprising indium gallium zinc oxide (In—Ga—Zn—O) and converting the fuel and fuel anions into CO 2 , H 2 O, and optionally, N 2 ;
wherein the transistor device exhibits a charge mobility of about 3 cm 2 /Vs or higher.
2. The method of claim 1 comprising coupling the metal oxide thin film directly or indirectly to a flexible substrate.
3. The method of claim 1 , wherein the solvent or solvent mixture comprises an alkoxyalcohol.
4. The method of claim 1 , wherein the annealing step is performed at a temperature of less than or about 150° C.
5. The method of claim 1 , further comprising providing a metal oxide thin film dielectric, wherein providing the metal oxide thin film dielectric comprises:
depositing a thin film from a dielectric precursor composition comprising a fuel and one or more oxidizing agents in a solvent or solvent mixture, wherein the fuel and/or at least one of the oxidizing agent(s) comprise a metal salt comprising aluminum or cerium, and wherein the fuel and the one or more oxidizing agents are present in amounts to allow metal oxide formation and complete combustion of the fuel and fuel anions; and
annealing the thin film at a temperature less than or about 350° C. with or without exposure to a radiation source, thereby providing a metal oxide thin film dielectric and converting the fuel into CO 2 , H 2 O, and optionally, N 2 .
6. The method of claim 1 , further comprising providing a metal oxide thin film conductor, wherein providing the metal oxide thin film conductor comprises:
depositing a thin film from a conductor precursor composition comprising a fuel and one or more oxidizing agents in a solvent or solvent mixture, wherein the fuel and/or at least one of the oxidizing agent(s) comprise a metal salt, and wherein the fuel and the one or more oxidizing agents are present in amounts to allow metal oxide formation and complete combustion of the fuel and fuel anions; and
annealing the thin film at a temperature less than or about 350° C. with or without exposure to a radiation source, thereby providing a metal oxide thin film dielectric and converting the fuel into CO 2 , H 2 O, and optionally, N 2 .
7. The method of claim 1 further comprising coupling the metal oxide thin film directly to an organic layer.
8. The method of claim 1 , wherein the depositing step is carried out by spin-coating, slot-coating, drop-casting, zone casting, dip coating, blade coating, spray-coating, rod coating, or stamping.
9. The method of claim 1 , wherein each of the indium salt, the gallium salt, and the zinc salt comprises an oxidizing anion selected from a nitrate, a perchlorate, a chlorate, a hypochlorite, an azide, a peroxide, a superoxide, a high-valent oxide, an N-oxide, a persulfate, a dinitramide, a nitrocyanamide, a nitroarylcarboxylate, a tetrazolate, and hydrates thereof, and the precursor composition further comprises a fuel selected from acetylacetone, CF 3 COCH 2 COCF 3 , CH 3 COCHFCOCH 3 , CH 3 COCH 2 C(═NH)CF 3 , CH 3 C(═NH)CHFC(═NH)CH 3 , CH 3 COCH 2 C(═NCH 3 )CF 3 , CH 3 C(═NCH 3 )CHFC(═NCH 3 )CH 3 , CH 3 C(═NH)CHFC(═NCH 3 )CH 3 , Ph 2 POCH 2 COCH 3 , urea, N-methylurea, citric acid, ascorbic acid, stearic acid, nitromethane, hydrazine, carbohydrazide, oxalyl dihydrazide, malonic acid dihydrazide, tetra formal tris azine, hexamethylenetetramine, and malonic anhydride.
10. The method of claim 1 , wherein each of the indium salt, the gallium salt, and the zinc salt comprises nitrate or a hydrate thereof.
11. The method of claim 10 , wherein the precursor composition further comprises a fuel selected from acetylacetone, CF 3 COCH 2 COCF 3 , CH 3 COCHFCOCH 3 , CH 3 COCH 2 C(═NH)CF 3 , CH 3 C(═NH)CHFC(═NH)CH 3 , CH 3 COCH 2 C(═NCH 3 )CF 3 , CH 3 C(═NCH 3 )CHFC(═NCH 3 )CH 3 , CH 3 C(═NH)CHFC(═NCH 3 )CH 3 , Ph 2 POCH 2 COCH 3 , urea, N-methylurea, citric acid, ascorbic acid, stearic acid, nitromethane, hydrazine, carbohydrazide, oxalyl dihydrazide, malonic acid dihydrazide, tetra formal tris azine, hexamethylenetetramine, and malonic anhydride.
12. The method of claim 11 , wherein the precursor composition further comprises a base.
13. A method of fabricating a transistor device comprising a thin film semiconductor component comprising indium gallium zinc oxide (In—Ga—Zn—O), the method comprising:
depositing a thin film from a precursor composition comprising an indium salt, a gallium salt, and a zinc salt in a solvent or solvent mixture, wherein the indium salt, the gallium salt, and the zinc salt independently comprise either an oxidizing anion or a fuel anion, provided that (a) if none of the indium salt, the gallium salt and the zinc salt comprises a fuel anion, then the precursor composition further comprises either a fuel or an ammonium salt comprising a fuel anion, and (b) if none of the indium salt, the gallium salt and the zinc salt comprises an oxidizing anion, then the precursor composition further comprises either an acid comprising an oxidizing anion or an inorganic salt comprising an oxidizing anion, wherein:
the fuel is selected from acetylacetone, CF 3 COCH 2 COCF 3 , CH 3 COCHFCOCH 3 , CH 3 COCH 2 C(═NH)CF 3 , CH 3 C(═NH)CHFC(═NH)CH 3 , CH 3 COCH 2 C(═NCH 3 )CF 3 , CH 3 C(═NCH 3 )CHFC(═NCH 3 )CH 3 , CH 3 C(═NH)CHFC(═NCH 3 )CH 3 , Ph 2 POCH 2 COCH 3 , urea, N-methylurea, citric acid, ascorbic acid, stearic acid, nitromethane, hydrazine, carbohydrazide, oxalyl dihydrazide, malonic acid dihydrazide, tetra formal tris azine, hexamethylenetetramine, and malonic anhydride,
the fuel anion is selected from acetylacetonate, a citrate, an oxalate, an ascorbate, and a stearate,
the oxidizing anion is selected from a nitrate, a perchlorate, a chlorate, a hypochlorite, an azide, a peroxide, a superoxide, a high-valent oxide, an N-oxide, a persulfate, a dinitramide, a nitrocyanamide, a nitroarylcarboxylate, a tetrazolate, and hydrates thereof, and
the oxidizing anions and the fuel and fuel anions in the precursor composition are present in amounts to allow metal oxide formation and complete combustion of the fuel and fuel anions; and
annealing the thin film at a temperature of less than or about 250° C. to initiate a combustion reaction between the oxidizing anions and the fuel and fuel anions, thereby forming a thin film semiconductor component comprising indium gallium zinc oxide (In—Ga—Zn—O) and converting the fuel and fuel anions into CO 2 , H 2 O, and optionally, N 2 ;
wherein the transistor device exhibits a charge mobility of about 3 cm 2 /Vs or higher.
14. A method of fabricating a transistor device comprising a thin film semiconductor component comprising indium gallium zinc oxide (In—Ga—Zn—O), the method comprising:
depositing a thin film from a precursor composition comprising an indium salt, a gallium salt, and a zinc salt in a solvent or solvent mixture, wherein the indium salt, the gallium salt, and the zinc salt independently comprise either an oxidizing anion or a fuel anion, provided that (a) if none of the indium salt, the gallium salt and the zinc salt comprises a fuel anion, then the precursor composition further comprises either a fuel or an ammonium salt comprising a fuel anion, and (b) if none of the indium salt, the gallium salt and the zinc salt comprises an oxidizing anion, then the precursor composition further comprises either an acid comprising an oxidizing anion or an inorganic salt comprising an oxidizing anion, wherein:
the fuel is selected from acetylacetone, CF 3 COCH 2 COCF 3 , CH 3 COCHFCOCH 3 , CH 3 COCH 2 C(═NH)CF 3 , CH 3 C(═NH)CHFC(═NH)CH 3 , CH 3 COCH 2 C(═NCH 3 )CF 3 , CH 3 C(═NCH 3 )CHFC(═NCH 3 )CH 3 , CH 3 C(═NH)CHFC(═NCH 3 )CH 3 , Ph 2 POCH 2 COCH 3 , urea, N-methylurea, citric acid, ascorbic acid, stearic acid, nitromethane, hydrazine, carbohydrazide, oxalyl dihydrazide, malonic acid dihydrazide, tetra formal tris azine, hexamethylenetetramine, and malonic anhydride,
the fuel anion is selected from acetylacetonate, a citrate, an oxalate, an ascorbate, and a stearate,
the oxidizing anion is selected from a nitrate, a perchlorate, a chlorate, a hypochlorite, an azide, a peroxide, a superoxide, a high-valent oxide, an N-oxide, a persulfate, a dinitramide, a nitrocyanamide, a nitroarylcarboxylate, a tetrazolate, and hydrates thereof, and
the oxidizing anions and the fuel and fuel anions in the precursor composition are present in amounts to allow metal oxide formation and complete combustion of the fuel and fuel anions; and
annealing the thin film at a temperature of less than or about 350° C., wherein the annealing step consists of heat treatment without irradiation, to initiate a combustion reaction between the oxidizing anions and the fuel and fuel anions, thereby forming a thin film semiconductor component comprising indium gallium zinc oxide (In—Ga—Zn—O) and converting the fuel and fuel anions into CO 2 , H 2 O, and optionally, N 2 ;
wherein the transistor device exhibits a charge mobility of about 3 cm 2 /Vs or higher.