IP Library Granted Patent US 9,175,366
Granted Patent B2
US 9,175,366 · App. 13/804,053 · Granted Nov 3, 2015

Systems and methods for improved metal recovery using ammonia leaching

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Quick Facts
Patent No.
US 9,175,366
App. No.
13/804,053
Granted
Nov 3, 2015
Kind
B2
Abstract

Systems and methods for basic leaching are provided. In various embodiments, a method is provided comprising leaching a slurry comprising a copper bearing material and a leach medium comprising ammonia and ammonium carbonate, adding copper powder to the slurry, separating the slurry into a pregnant leach solution and solids, and performing a solvent extraction on the pregnant leach solution to produce an loaded aqueous stream.

Claims (18)

1. A method comprising:

leaching a slurry comprising a metal bearing material comprising one of copper and cobalt and copper and cobalt compounds, and a leach medium comprising ammonia and ammonium carbonate;

adding copper powder to the slurry;

separating the slurry into a pregnant leach solution and solids, the pregnant leach solution comprising copper and cobalt; and

performing a solvent extraction on the pregnant leach solution to produce a copper bearing loaded aqueous stream and a cobalt bearing raffinate.

2. The method of claim 1 , further comprising:

producing a cobalt precipitate from the raffinate; and

subjecting the cobalt precipitate to a metal recovery process.

3. The method of claim 1 , wherein the leach medium further comprises ammonium sulfate.

4. The method of claim 1 , further comprising:

producing a cobalt precipitate and a cobalt depleted liquid phase from the raffinate; and

adding a portion of the cobalt depleted liquid phase to the slurry during leaching.

5. The method of claim 1 , wherein the solvent extraction comprises at least one of an extraction phase, a scrub stage, a wash stage, and a solvent stripping phase.

6. The method of claim 5 , wherein the extraction phase yields a cobalt-bearing raffinate.

7. The method of claim 6 , further comprising precipitating cobalt from the cobalt-bearing raffinate.

8. The method of claim 7 , wherein the precipitating yields cobalt sulfide in a solid phase.

9. The method of claim 8 , wherein the cobalt sulfide is subjected to leaching.

10. The method of claim 5 , further comprising subjecting the loaded aqueous stream to electrowinning.

Assignments (3)
CHANGE OF NAME Recorded Jul 23, 2014
From: FREEPORT-MCMORAN CORPORATION
To: FREEPORT MINERALS CORPORATION
Reel/Frame 033389/0300 →
MERGER Recorded Jul 17, 2014
From: FREEPORT-MCMORAN CORPORATION
To: FREEPORT-MCMORAN CORPORATION
Reel/Frame 033357/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 17, 2013
From: ROBERTSON, JOANNA M; BOLLES, THOMAS R; GERTENBACH, DENNIS D
To: FREEPORT-MCMORAN CORPORATION
Reel/Frame 030625/0113 →