IP Library Granted Patent US 9,025,925
Granted Patent B2
US 9,025,925 · App. 13/806,160 · Granted May 5, 2015

Radiation-resistant rare-earth-doped optical fiber and method of radiation-hardening a rare-earth-doped optical fiber

Inventors: Benoôt Cadier (Perros Guirec, FR); Arnaud Laurent (Quemperven, FR); Thierry Robin (Camlez, FR); Sylvain Girard (Arpajon, FR); Claude Marcandella (Montlhery, FR)
Assignees: Ixblue; Commissariat a l'Energie Atomique et aux Energies Alternatives
C03B37/01838C03B2201/12C03B2201/28C03B2201/34G02B6/02295G02B6/024G02B6/03611H01S3/0672H01S3/06729H01S3/094007H01S3/09403H01S3/1608H01S3/1618G02B6/036
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Quick Facts
Patent No.
US 9,025,925
App. No.
13/806,160
Granted
May 5, 2015
Kind
B2
Abstract

A radiation-resistant optical fiber includes at least one core and at least one first cladding surrounding the core. The core includes a phosphosilicate matrix, the core being rare-earth doped, the rare earth being chosen from erbium, ytterbium, neodymium, thulium or erbium-ytterbium of thulium-holmium codoped and the core is cerium codoped. Also described is a method for radiation-hardening an optical fiber including the core having a phosphosilicate matrix, the core being rare-earth doped, the rare earth being chosen from erbium, ytterbium, neodymium and thulium, or erbium-ytterbium or thulium-holmium codoped, and including a step of cerium codoping the core of the fiber.

Claims (27)

1. A radiation-resistant optical fiber which is resistant to ionizing radiations, comprising:

at least one core ( 1 ); and

at least one first cladding ( 2 ) surrounding said core ( 1 ), wherein,

said core ( 1 ) comprises a phosphosilicate matrix,

said core ( 1 ) is doped with a rare earth element chosen from erbium, ytterbium, neodymium, thulium, or being erbium-ytterbium codoped or thulium-holmium codoped, and

said core ( 1 ) is codoped with cerium, and a phosphorus concentration is between 2 and 10 atomic %, and the cerium concentration is between 500 and 10000 ppm.

2. The optical fiber according to claim 1 , characterized in that the core is erbium doped or erbium-ytterbium codoped and in that the ratio between the erbium concentration and the cerium concentration (Er/Ce) in the fiber core is between 0.05 and 50.

3. The optical fiber according to claim 2 , characterized in that the core is erbium-ytterbium codoped and in that the ratio of the concentrations Yb/Er in the core of the fiber is between 5 and 50.

4. The optical fiber according to claim 3 , characterized in that the erbium concentration is between 100 and 1000 ppm, the ytterbium concentration is between 500 and 10000 ppm.

5. The optical fiber according to claim 1 , characterized in that the fiber comprises a second cladding surrounding the first cladding.

6. The optical fiber according to claim 1 , characterized in that the core further comprises hydrogen and/or fluorine.

7. The optical fiber according to claim 1 , characterized in that the fiber is a polarizing or polarization-maintaining fiber.

8. The optical fiber according to claim 1 , characterized in that the fiber is a micro-structured fiber or a photonic fiber comprising a cladding made of hollow capillaries or the fiber comprises a bandgap structure, or the fiber is a large-mode-area fiber.

9. A radiation-resistant optical-fiber amplifier comprising an optical fiber according to claim 1 .

10. A radiation-resistant fiber laser comprising an optical fiber according to claim 1 .

11. A method for radiation-hardening an optical fiber to ionizing radiations, comprising a phosphosilicate-matrix core, said core being doped with a rare earth chosen from erbium, ytterbium, neodymium, thulium, or being erbium-ytterbium codoped or thulium-holmium codoped; and a step of cerium codoping said core of the optical fiber so that a phosphorus concentration is between 2 and 10 atomic %, and the cerium concentration is between 500 and 10000 ppm.

12. The method according to claim 11 , characterized in that it comprises an additional step of fluorine codoping the core and/or the cladding of said fiber.

13. The method according to claim 11 , characterized in that it comprises an additional step of hydrogenating said optical fiber.

14. A method for manufacturing an active, radiation-resistant optical device using a rare-earth-doped optical fiber comprising a phosphosilicate-matrix core, said core being doped with a rare earth chosen from erbium, ytterbium, neodymium, thulium, or being erbium-ytterbium or thulium-holmium codoped, said core being cerium codoped so that said fiber has an increased radiation resistance, wherein a phosphorus concentration is between 2 and 10 atomic %, and the cerium concentration is between 500 and 10000 ppm.

15. The method according to claim 14 , characterized in that said optical device is chosen from: a rare-earth-doped optical-fiber amplifier, a fiber laser, a wideband source.

16. The optical fiber according to claim 2 , characterized in that the core is erbium-ytterbium codoped and in that the ratio of the concentrations Yb/Er in the core of the fiber is between 5 and 50.

17. The method according to claim 12 , characterized in that it comprises an additional step of hydrogenating said optical fiber.

18. The optical fiber according to claim 1 , wherein,

said core is erbium-ytterbium codoped, and

said at least one first cladding surrounding said core is a fluorinated-silica double-cladding having a numerical aperture (N.A.) higher than 0.40.

19. The optical fiber according to claim 18 , wherein the ratio of the concentrations Yb/Er in said core is between 12 and 25.

20. The optical fiber according to claim 18 , wherein the concentration ratio Yb/Ce is between 0.1 and 10 in said core.

Assignments (3)
CHANGE OF NAME AND ADDRESS Recorded Apr 3, 2023
From: IXBLUE
To: EXAIL
Reel/Frame 063237/0952 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 18, 2015
From: IXFIBER
To: IXBLUE
Reel/Frame 035190/0379 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 7, 2013
From: CADIER, BENOIT; LAURENT, ARNAUD; ROBIN, THIERRY; GIRARD, SYLVAIN; MARCANDELLA, CLAUDE
To: IXFIBER; COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
Reel/Frame 029772/0412 →
Priority Claims (1)
FR 10 55617 · Jul 9, 2010 · national
Continuity (1)
Related Publication 20130101261A1 · Apr 25, 2013