Method for producing surface-modified rare earth metal-based sintered magnet
View Patent ↗An object of the present invention is to provide a method for producing a surface-modified rare earth metal-based sintered magnet having extremely excellent corrosion resistance even in an environment with fluctuating temperature and humidity and also having excellent magnetic characteristics. The method for producing a surface-modified rare earth metal-based sintered magnet of the present invention as a means for achieving the object is characterized by comprising a step of subjecting a rare earth metal-based sintered magnet to a heat treatment at 200° C. to 600° C. in an atmosphere having an oxygen partial pressure of 1×10 3 Pa to 1×10 5 Pa and a water vapor partial pressure of 45 Pa or less with the ratio between the oxygen partial pressure and the water vapor partial pressure (oxygen partial pressure/water vapor partial pressure) being 450 to 20000.
1. A method for producing a surface-modified rare earth metal-based sintered magnet, consisting of:
a step of heating a rare earth metal-based sintered magnet from ordinary temperature to a heat treatment temperature of 200° C. to 600° C. in an atmosphere having an oxygen partial pressure of 1×10 3 Pa to 1×10 5 Pa and a water vapor partial pressure of 45 Pa or less with the ratio between the oxygen partial pressure and the water vapor partial pressure (oxygen partial pressure/water vapor partial pressure) being 600 to 20000,
a step of subjecting the rare earth metal-based sintered magnet to a heat treatment at the heat treatment temperature at the same oxygen partial pressure and water vapor partial pressure as in the step of heating from ordinary temperature, and then
a step of cooling the rare earth metal-based sintered magnet at the same oxygen partial pressure and water vapor partial pressure as in the step of heating from ordinary temperature and in the step of subjecting to the heat treatment.
2. The production method according to claim 1 , characterized in that the atmosphere has a total pressure of 9×10 4 Pa to 1.2×10 5 Pa.
3. The production method according to claim 1 , wherein:
the resulting surface-modified rare earth metal-based sintered magnet has a modification layer formed on the surface of the magnet;
the modification layer on the main phase of the surface of the magnet is constituted by an iron oxide made of 75 mass % or more hematite; and
the modification layer on the grain boundary triple point is constituted by an R oxide made of 75 mass % or more R 2 O 3 .