Process for the selective hydrogenation of multiply unsaturated hydrocarbons in olefin-containing hydrocarbon mixtures
View Patent ↗The present invention describes a process for the parallel selective hydrogenation of branched and unbranched multiply unsaturated C 4 -C 6 -hydrocarbons in olefin-containing hydrocarbon mixtures with minimization of hydrogenation and isomerization of the olefins present in the stream.
1. A process, comprising:
selectively hydrogenating an unbranched, multiply unsaturated C 4 -hydrocarbon and a branched, multiply unsaturated C 5 -hydrocarbon in a hydrocarbon mixture with addition of hydrogen and carbon monoxide in the presence of a heterogeneous hydrogenation catalyst in a hydrogenation reactor,
wherein a ratio of the volume of a feed stream comprising the hydrocarbon mixture, hydrogen, and carbon monoxide into the hydrogenation reactor to the volume of the hydrogenation catalyst per hour of residence time is from 10 to 25 l/h,
wherein a temperature at which the feed stream enters the hydrogenation reactor is from 30 to 60° C., and
wherein a content of carbon monoxide in the feed stream is from 0.5 to 5 ppm, based on the mass of the hydrocarbon mixture.
2. The process of claim 1 , wherein the heterogeneous hydrogenation catalyst is a palladium catalyst.
3. The process of claim 1 , being a liquid-phase process.
4. The process of claim 2 , wherein the palladium catalyst is a supported catalyst comprising palladium and a support material.
5. The process of claim 4 , wherein the support material is aluminum oxide, silica gel, or activated carbon.
6. The process of claim 5 , wherein a content of the palladium catalyst is from 0.01 to 3%, based on a mass of the support material.
7. The process of claim 5 , wherein a content of the palladium catalyst is from 0.1 to 1%, based on a mass of the support material.
8. The process of claim 5 , wherein a content of the palladium catalyst is from 0.3 to 0.5%, based on a mass of the support material.
9. The process of claim 2 , wherein the palladium catalyst has a BET surface area of from 50 to 400 m 2 /g, determined by gas adsorption in accordance with DIN ISO 9277.
10. The process of claim 2 , wherein the palladium catalyst has a BET surface area of from 100 to 300 m 2 /g, determined by gas adsorption in accordance with DIN ISO 9277.
11. The process of claim 2 , wherein the palladium catalyst has a BET surface area of from 200 to 300 m 2 /g, determined by gas adsorption in accordance with DIN ISO 9277.