Hermetically sealed electronic device using coated glass flakes

1. A method of forming a barrier, comprising:

a. providing a glass flake loaded curable organic material comprising

i. at least one curable organic material,

ii. 10-95 vol% glass flakes based on the volume of organic material,

b. applying the glass flake loaded curable organic material to at least one first substrate,

c. subjecting the glass flake loaded curable organic material to an ultrasonic horn in order to at least partially align the flakes generally parallel to the substrate, and

d. curing the curable organic material to form a barrier,

wherein the glass flakes have an aspect ratio of 2-100 and a length of 0.1-2000 microns.

2. The method of claim 1 , further comprising, prior to (d), contacting a second substrate with the at least one first substrate such that the glass flake loaded curable organic material lies therebetween.

3. The method of claim 2 , wherein the barrier forms a cavity.

4. The method of claim 3 , wherein an active layer is contained within the cavity.

5. The method of claim 4 , wherein the active layer is selected from the group consisting of solar cell, solar cell contact, organic PV device, plasma display device, nanocrystal display, electrochromic device, electrochromic material system, suspended particle device, micro-blind, liquid crystal device, smart window, switchable window, smart glass, eglass, LED, SED, FED, OLED, LCD, DLP, FLD, IMOD, TDEL, QDLED , TMOS, TPD, LCL, LPD, and OLET.

6. The method of claim 1 , wherein the glass flakes are present to an extent of 10-40 vol% and have a length of 0.5-100 microns.

7. The method of claim 1 , wherein the glass flakes are present to an extent of 40-70 vol% and have a length of 0.5-100 microns.

8. The method of claim 1 , wherein the average D 50 particle size of the glass flakes is 50 nanometers to 20 microns.

9. The method of claim 1 , wherein, prior to (a), the glass flakes are functionalized by the application to the glass flakes of at least one selected from the group consisting of adhesion promoting primers; coupling agents; organotitanate coupling agents; silane coupling agents selected from the group consisting of, vinyl, chloropropyl, epoxy, methacrylate, primary amine, diamine, mercapto, cationic styryl, cationic methacrylate, titanate, crosslinker, mixed silanes and melamine epoxy; rubber elastomers selected from the group consisting of natural rubber, butyl rubber, styrene-butadiene rubber, nitrile rubber, and neoprene rubber, and combinations of the foregoing.

10. The method of claim 1 , wherein, prior to (a), the glass flakes have been fabricated to contain at least one UV absorbing cation selected from the group consisting of titanium, cerium, transition metals and rare earth metals.

11. The method of claim 1 , wherein curing is achieved by application of a localized energy source selected from the group consisting of ultrasound, visible light, ultraviolet light, broadband infrared, laser, flame induction, and combinations thereof.

12. The method of claim 1 , wherein the curing is achieved by application of a dispersed energy source selected from the group consisting of thermal heating, ambient heat, ultrasound, natural gas burners, magnetic induction heating, convection furnace, and eddy currents.

13. A method of hermetically sealing an object, comprising:

a. providing a glass flake loaded curable organic material comprising

i. at least one curable organic material,

ii. 40-70 vol% glass flakes based on the volume of organic material,

b. applying the glass flake loaded curable organic material to the at least a portion of the surface of the object,

c. subjecting the glass flake loaded curable organic material to an ultrasonic horn in order to at least partially align the flakes generally parallel to the substrate, and

d. curing the curable organic material to form a film or sheet over at least a portion of the surface of the object,

wherein the glass flakes have an aspect ratio of 2-100 and a length of 0.1-2000 microns.

14. The method of claim 13 , wherein, prior to (a), at least one metal is coated onto the glass flakes.

15. The method of claim 14 , wherein the metal is coated onto the glass flakes by a procedure selected from the group consisting of spraying, electroplating, sputtering, CVD or in situ reduction of metal salts.