Lightly modified prepolymers and uses thereof
View Patent ↗An isocyanate-terminated prepolymer C having an NCO content of from ≧26% by mass to ≦31.0% by mass is obtainable from the reaction of an isocyanate composition A having a viscosity at 25° C. of from ≧60 mPas to ≦800 mPas, comprising from ≧25% by mass to ≦60% by mass MDI and from ≧40% by mass to ≦75% by mass pMDI, wherein the sum of the amounts of those components is ≦100% by mass, with a bifunctional polyester ether polyol B having an OH number of ≧200 mg(KOH)/g and ≦500 mg(KOH)/g, obtained from the reaction of a dicarboxylic acid/dicarboxylic acid derivative with at least one polyol and with an epoxide, wherein the polyester ether polyol B is used in amounts of from ≧1.5% by mass to ≦6.0% by mass, based on the sum of the masses of A and B. The invention further provides a PUR/PIR polymer produced from the prepolymer C, its use and composite elements based thereon.
1. An isocyanate-terminated prepolymer C having an NCO content of from ≧26.0% by mass to ≦31.0% by mass, based on the mass of the prepolymer C, obtained from the reaction of
(i) an isocyanate composition A having a viscosity at 25° C. of from ≧60 mPas to ≦800 mPas, comprising
from ≧25% by mass to ≦60% by mass monomeric diphenylmethane diisocyanate A1 and
from ≧40% by mass to ≦75% by mass polymeric diphenylmethane diisocyanate A2,
wherein the sum of the amounts of components A1 and A2 is ≦100% by mass, with
(ii) a polyester ether polyol B having an average functionality of from ≧1.9 to ≦2.1 and an OH number of from ≧200 mg(KOH)/g to ≦500 mg(KOH)/g, obtained from the reaction of a dicarboxylic acid and/or a dicarboxylic acid derivative B1 with at least one polyol B2 and with an epoxide B3,
wherein the polyester ether polyol B is used in amounts of from ≧1.5% by mass to ≦6.0% by mass, based on the sum of the masses of A and B.
2. The prepolymer according to claim 1 having a viscosity at 25° C. of from ≧300 mPas to ≦1600 mPas.
3. The prepolymer according to claim 1 , wherein the composition A has a viscosity at 25° C. of from ≧90 mPas to ≦300 mPas and an NCO content of from ≧30% by mass to ≦33% by mass.
4. The prepolymer according to claim 1 , wherein the polyester ether polyol B is obtained from the reaction of phthalic anhydride as component B1, diethylene glycol as component B2 and ethylene oxide as component B3.
5. The prepolymer according to claim 1 , wherein the NCO content is from ≧27.5% by mass to ≦29.5% by mass.
6. The prepolymer according to claim 2 , wherein the viscosity at 25° C. is from ≧500 mPas to ≦1000 mPas.
7. The prepolymer according to claim 1 , wherein the polyester ether polyol B having an OH number of from 275 mg(KOH)/g to 325 mg(KOH)/g and a viscosity of 6.5 +/− 1.3 Pa s at 25° C.
8. A polyurethane/polyisocyanurate polymer, obtained from a reaction of a prepolymer C according to claim 1 with an isocyanate-reactive component D.
9. The polyurethane/polyisocyanurate polymer according to claim 8 , wherein the molar ratio of isocyanate groups to hydroxyl groups in the reaction mixture of components C and D is from ≧1:1 to ≦5:1.
10. The polyurethane/polyisocyanurate polymer according to claim 8 , wherein the reaction of the prepolymer C with the isocyanate-reactive component D takes place in the presence of a foaming agent E.
11. The polyurethane/polyisocyanurate polymer according to claim 8 , wherein the isocyanate-reactive component D comprises from ≧50% by mass to ≦95% by mass of a polyester polyol D1 and from ≧5% by mass to ≦50% by mass of a polyether polyol D2, in each case based on the total mass of component D, and wherein further the sum of the amounts of components D1 and D2 is ≦100% by weight.
12. The polyurethane/polyisocyanurate polymer according to claim 11 , wherein the polyester polyol D1 has an average functionality of from ≧1.9 to ≦2.1 and an OH number of from ≧220 mg(KOH)/g to ≦270 mg(KOH)/g and further is obtained from the reaction of phthalic acid and/or phthalic anhydride as well as adipic acid, diethylene glycol and ethylene glycol.
13. The polyurethane/polyisocyanurate polymer according to claim 11 , wherein the polyether polyol D2 is a polyoxyethylene and/or polyoxypropylene polyol started on trimethylolpropane and having an OH number of from ≧200 mg(KOH)/g to ≦300 mg(KOH)/g.
14. A composite element that comprises a layer comprising a polyurethane/polyisocyanurate polymer according to claim 8 and a cover layer.
15. The composite element according to claim 14 , wherein the cover layer comprises a material that is is aluminium, steel, bitumen, paper, a mineral nonwoven, a nonwoven comprising organic fibres, a plastics sheet, a plastics film and/or a wooden panel.
16. The composite element according to claim 14 , wherein adhesion strength between the layer comprising a polyurethane/polyisocyanurate polymer and the cover layer is ≧0.20 N/mm 2 .
17. The composite element according to claim 15 , wherein the material of the cover layer is steel.
18. A method for foam-insulating and/or promoting adhesion in a composite element, comprising providing a layer comprising the polyurethane/polyisocyanurate polymer according to claim 8 on a cover layer of the composite element.
19. The method according to claim 18 , wherein the cover layer is a steel cover layer.